Study on heat conduction and adsorption/desorption characteristic of MIL-101/few layer graphene composite

Journal of Porous Materials - Aiming at the poor heat conduction performance of porous MIL-101 applied in adsorption cooling process, few layer graphene (FLG) was selected as a promising thermal...     

焊接热源有效利用率的测试计算法

给出实际热输入值是正确求解焊接热弹塑性问题和焊接残余应力与变形问题的前提;因而,准确地确定热源有效利用率η,在焊接力学的发展中是一个急待解决的命题。本文推荐采用的“测试计算法”提供了一个能够准确、简捷地求得η值的新途径。引入被焊材料的熔化潜热系数后,给出了线热源加热焊缝金属至熔化温度(处于液态)时的实际热有效利用率ηt 的表达式。在四种不同类型的薄板材料上进行了钨极氩弧焊试验,测试计算结果与理论值相符合。理论推导与试验结果均证明,形成焊缝所需要的线能量的无量纲数值等于焊缝金属熔化热有效利用率ηt 的倒数。文中给出的焊接规范参数选择原则也适用于符合线热源条件的其它熔焊热源。η值不但与焊接工艺方法、规范参数有关,而且也随被焊材料的热物理特性不同而异。     

挤压变形对Mg95Zn4.3Y0.7合金组织和性能的影响

研究了在250℃、不同挤压比下挤压变形对Mg95 Zn4.3 Y0.7合金组织及性能的影响。结果表明，Mg95 Zn4.3 Y0.7经过挤压变形后，合金中晶界处的共晶相破碎，弥散分布至晶粒内部，并且晶粒显著细化。同时，随着挤压比的增大，晶粒细化程度增加，合金的力学性能单调增加。当挤压比为16时，合金晶粒尺寸为5-8μm，抗拉强度为288.9MPa，显微硬度HV值为117.8。     

长轴表面激光淬火变形与控制

应用激光淬火强化技术控制长轴的淬火变形，分析了激光淬火变形的原因和影响因素。研究结果表明，激光淬火不仅可使长轴振摆变形量控制在很小的范围内，而且可将已变形的长轴校直到很高的精度。     

Ensemble deep transfer learning driven by multisensor signals for the fault diagnosis of bevel-gear cross-operation conditions

The existing intelligent fault diagnosis techniques of bevel gear focus on single-sensor signal analysis under the steady operation condition. In this study, a new method is proposed based on ensemble deep transfer learning and multisensor signals to enhance the fault diagnosis adaptability and reliability of bevel gear under various operation conditions. First, a novel stacked autoencoder(NSAE) is constructed using a denoising autoencoder, batch normalization, and the Swish activation function. Second, a series of source-domain NSAEs with multisensor vibration signals is pretrained. Third, the good model parameters provided by the source-domain NSAEs are transferred to initialize the corresponding target-domain NSAEs. Finally, a modified voting fusion strategy is designed to obtain a comprehensive result. The multisensor signals collected under the different operation conditions of bevel gear are used to verify the proposed method. The comparison results show that the proposed method can diagnose different faults in an accurate and stable manner using only one target-domain sample, thereby outperforming the existing methods.     

PAN/FPU Composite Nanofiber Membrane with Superhydrophobic and Superoleophobic Surface as a Filter Element for High-Efficiency Protective Masks

Recently, because of the outbreak of COVID-19, the demand for various types of filter elements in protective materials has increased globally. Furthermore, new requirements for the filtration performance of PM2.5 liquid (oil) particles have been put forward. In this work, Superhydrophobic and superoleophobic composite nanofibers with excellent filtration capacity for oil and salt particles are developed through the modification of polyacrylonitrile (PAN) by fluoro-polyurethane (FPU) doping. The results show that the PAN/FPU composite nanofibers doped with 9 wt% FPU has a uniform fiber morphology with a diameter of 240 ± 30 nm. Compared to the pure PAN nanofibers, the water-based contact angle of PAN/FPU increases from 90 ± 5° to 151 ± 5°, and the oil-based contact angle increases from 58 ± 2° to 152 ± 3°. Importantly, at a high flow rate of 95 L min⁻¹, the filtration efficiency of the PAN/FPU nanofiber membrane for 0.3 µm oil particles increases from 92 ± 1% to 99.2 ± 0.1%. After cyclic loading, the filtration efficiency of 0.3 µm oil particles remains above 98%. Meanwhile, the filtration efficiency for 0.3 µm salt particles remains at 98.23 ± 0.1%. The PAN/FPU nanofiber membrane developed in this work is effective in applications and has good market prospects as a protective filtration material.     

Preparation and Bioactivity of Iridium(III) Phenanthroline Complexes with Halide Ions and Pyridine Leaving Groups

A series of half-sandwich structural iridium(III) phenanthroline (Phen) complexes with halide ions (Cl⁻, Br⁻, I⁻) and pyridine leaving groups ([(η⁵-Cp^X)Ir(Phen)Z](PF₆)_n, Cp^x: electron-rich cyclopentadienyl group, Z: leaving group) have been prepared. Target complexes, especially the Cp^xbiph (biphenyl-substituted cyclopentadienyl)-based one, showed favourable anticancer activity against human lung cancer (A549) cells; the best one ( Ir8 ) was almost five times that of cisplatin under the same conditions. Compared with complexes involving halide ion leaving groups, the pyridine-based one did not display hydrolysis but effectively caused lysosomal damage, leading to accumulation in the cytosol, inducing an increase in the level of intracellular reactive oxygen species and apoptosis; this indicated an anticancer mechanism of oxidation. Additionally, these complexes could bind to serum albumin through a static quenching mechanism. The data highlight the potential value of half-sandwich iridium(III) phenanthroline complexes as anticancer drugs.     

粉煤灰高附加值利用研究进展

粉煤灰是火电厂燃煤过程中产生的固体残渣, 其成分复杂, 具有毒性, 若处理不当会对环境造成危害。因此, 粉煤灰的高附加值利用迫在眉睫。然而, 粉煤灰的品质是制约其高附加值利用的主要因素。目前, 中国粉煤灰品质参差不齐, 缺少完善的品质评价体系, 由此造成粉煤灰利用领域的局限性。针对上述问题, 首先分析了中国粉煤灰的资源化特性, 总结了粉煤灰的品质评价方法, 并重点阐述了适用于粉煤灰高附加值利用的品质评价方法;其次, 详细介绍了粉煤灰高附加值利用技术（高附加值提取技术、高附加值材料制备技术）;最后, 对粉煤灰高附加值利用的发展趋势做出了展望。     

DMFC阳极催化剂用GRQD-NiCo2O4复合物的制备与电催化活性分析

采用水热法制备GRQD-NiCo₂O₄复合物,利用XRD、SEM及TEM分析其微结构,并探讨其作为DMFC阳极催化剂使用时的电化学性能。微结构分析表明所得GRQD-NiCo₂O₄复合物皆为具NiCo₂O₄单一相的尖晶石结构,且GRQD质量浓度高于0.25 g/mL后表面形貌将转变GRQD与NiCo₂O₄相互结合的状态。电化学分析表明添加GRQD可有效增强NiCo₂O₄的导电性并提升其电化学稳定性,其中GRQD质量浓度为0.25 g/mL时所得样品经500次循环测试后电流密度约为77.5 A/g,与循环5次后相比其电流密度剩余量最大（约为69.7%）,该样品作为DMFC阳极催化剂使用时性价比最佳。     

Zr替代Ti对Ti19．5V40Mn16．2Cr9．8Ni14．5合金的影响Ⅱ：电化学性能

在对合金微观结构和储氢性能研究的基础上，详细考察了少量Zr取代Ti对Ti19．5V40Mn16．2Cr9．8Ni14．5合金电化学性能的影响。通过观察电极的充放电行为，并结合EIS及多种极化曲线的分析结果，发现少量Zr对Ti的取代能够显著提高合金电极的实际电化学容量和循环稳定性，而且还能在一定程度上改善合金的电极动力学性能。对于这些性能的改善，从合金微观结构方面进行了解释。