A complete review based on various aspects of pulverized coal combustion

Coal is the most abundant energy source, and around 40% of the world's electricity is produced by coal combustion. The emission generated through it put a constraint on power production by coal combustion. There is a need to reduce the emissions generated through it to utilize the enormous energy of coal for power production. Detailed understanding of various aspects of coal combustion is required to reduce the emissions from coal‐fired furnaces. The aim of present paper is to review various aspects of pulverized coal combustion such as oxy‐fuel combustion, co‐combustion of coal and biomass, emissions from pulverized coal furnaces, ash formation and deposition, and carbon capture and sequestration (CCS) technologies to outline the progress made in these aspects. Both experimental and numerical aspects are included in this review. This review also discusses the thermodynamic aspects of the combustion process. Furthermore, the effect of various submodels such as devolatilization models, char combustion models, radiation models, and turbulent models on the process of pulverized coal combustion has been investigated in this paper.     

A study on remanufacturing possibility of a product

With the intensification of Globalization, customers’ environment-friendly attitude and stringent environmental regulations, the manufacturers have been orienting their manufacturing and other value additive processes towards the development of more environment-friendly products and use of relevant processes including taking back of used products after their end-of-use or end-of-life from the end users. Remanufacturing is one of the prominent and popular options. Remanufacturing perhaps has drawn maximum attention because of its economic viability and environmental cleanliness. The remanufacturing operation depends upon the quality and quantity of the used. Better the quality lesser the remanufacturing cost. A remanufacturer is unaware about the condition of used product before its acquisition. It may also be noted that the remanufactured product may be taken after a period of its use by users. So it is really difficult to judge how many cycles does the product go for remanufacturing. This has drawn the attention of the authors and the problem is studied with developing some mechanism on the possible frequency of the remanufacturing of a new product. This paper is a study report on this area of research which is expected to contribute immensely to the remanufacturing business.

     

Plasmon‐Induced Hot Carrier Separation across Dual Interface in Gold–Nickel Phosphide Heterojunction for Photocatalytic Water Splitting

Precise control of the topology of metal nanocrystals and appropriate modulation of the metal–semiconductor heterostructure is an important way to understand the relationship between structure and material properties for plasmon‐induced solar‐to‐chemical energy conversion. Here, a bottom‐up wet chemical approach to synthesize Au/Ni₂P heterostructures via Pt‐catalyzed quasi‐epitaxial overgrowth of Ni on Au nanorods (NR) is presented. The structural motif of the Ni₂P is controlled using the aspect ratio of the Au NR and the effective micelle concentration of the C₁₆TAB capping agent. Highly ordered Au/Pt/Ni₂P nanostructures are employed as the photoelectrocatalytic anode system for water splitting. Electrochemical and ultrafast absorption spectroscopy characterization indicates that the structural motif of the Ni₂P (controlled by the outer‐shell deposition of Ni) helps to manipulate hot electron transfer during surface plasmon decay. With optimized Ni₂P thickness, Pt‐tipped Au NR with an aspect ratio of 5.2 exhibits a geometric current density of 10 mA cm^?2 with an overpotential of 140 mV. The photoanode displays unprecedented long‐term stability with continuous chronoamperometric performance of 50 h at an input potential of 1.5 V with over 30 days. This work provides definitive guidance for designing plasmonic–catalytic nanomaterials for enhanced solar‐to‐chemical energy conversion.     

Transition‐Metal Dichalcogenide NiTe2: An Ambient‐Stable Material for Catalysis and Nanoelectronics

By means of theory and experiments, the application capability of nickel ditelluride (NiTe₂) transition‐metal dichalcogenide in catalysis and nanoelectronics is assessed. The Te surface termination forms a TeO₂ skin in an oxygen environment. In ambient atmosphere, passivation is achieved in less than 30 min with the TeO₂ skin having a thickness of about 7 Å. NiTe₂ shows outstanding tolerance to CO exposure and stability in water environment, with subsequent good performance in both hydrogen and oxygen evolution reactions. NiTe₂‐based devices consistently demonstrate superb ambient stability over a timescale as long as one month. Specifically, NiTe₂ has been implemented in a device that exhibits both superior performance and environmental stability at frequencies above 40 GHz, with possible applications as a receiver beyond the cutoff frequency of a nanotransistor.     

Vortex Matter in Highly Strained Nb$$_{}$$Zr$$_{25}$$25: Analogy with Viscous Flow of Disordered Solids

We present the results of magnetization and magneto-transport measurements in the superconducting state of an as-cast Nb\(_{75}\)Zr\(_{25}\) alloy. We also report the microstructure of our sample at various length scales by using optical, scanning electron and transmission electron microscopies. The information of microstructure is used to understand the flux pinning properties in the superconducting state within the framework of collective pinning. The magneto-transport measurements show a non-Arrhenius behaviour of the temperature- and field-dependent resistivity across the resistive transition and is understood in terms of a model for viscous flow of disordered solids which is popularly known as the ‘shoving model’. The activation energy for flux flow is assumed to be mainly the elastic energy stored in the flux-line lattice. The scaling of pinning force density indicates the presence of two pinning mechanisms of different origins. The elastic constants of the flux-line lattice are used to estimate the length scale of vortex lattice movement, or the volume displaced by the flux-line lattice. It appears that the vortex lattice displacement estimated from elastic energy considerations is of the same order of magnitude as that of the flux bundle hopping length during flux flow. Our results could provide possible directions for establishing a framework where vortex matter and glass-forming liquids or amorphous solids can be treated in a similar manner for understanding the phenomenon of viscous flow in disordered solids or more generally the pinning and depinning properties of elastic manifolds in random media. It is likely that the vortex molasses scenario is more suited to explain the vortex dynamics in conventional low-T\(_C\) superconductors.     

Experimental investigation of spray characteristics of kerosene and ethanol-blended kerosene using a gas turbine hybrid atomizer

Gas turbines have wide application as prime movers in transportation and power generating sectors, most of which are driven by fossil fuels like kerosene. The conventional fuels are associated with problems of air pollution, and the fuel reserves are getting depleted gradually. Addition of ethanol in kerosene leads to better spraying characteristics. The present work deals with the spray characteristics of pure kerosene and 10%-ethanol-blended (by volume) kerosene using a novel gas-turbine hybrid atomizer. Here the inner air and outer air enter in the same and opposite directions, respectively, with respect to the fuel flow direction into the atomizer and a high swirling effect occurs outside the nozzle. The fuel stream is sandwiched between two annular air streams and the flow rate of inner and outer air is varied continuously. Various spray stages like distorted pencil, onion, tulip and fully developed spray regimes have been observed. The breakup length, cone angle and sheet width of the fuel stream are analysed directly from backlit imaging for different fuel and air flow rates. From the image processing, it is observed that breakup occurs at an early stage for 10%-ethanol-blended kerosene due to low viscosity of ethanol. It is also observed that at higher air flow rate, breakup occurs at an early stage due to turbulent nature of the fuel stream.     

Injectable Bone Cement Reinforced with Gold Nanodots Decorated rGO-Hydroxyapatite Nanocomposites,Augment Bone Regeneration

Interest in the development of new generation injectable bone cements having appropriate mechanical properties, biodegradability, and bioactivity has been rekindled with the advent of nanoscience. Injectable bone cements made with calcium sulfate (CS) are of significant interest, owing to its compatibility and optimal self-setting property. Its rapid resorption rate, lack of bioactivity, and poor mechanical strength serve as a deterrent for its wide application. Herein, a significantly improved CS-based injectable bone cement (modified calcium sulfate termed as CS_mod), reinforced with various concentrations (0–15%) of a conductive nanocomposite containing gold nanodots and nanohydroxyapatite decorated reduced graphene oxide (rGO) sheets (AuHp@rGO), and functionalized with vancomycin, is presented. The piezo-responsive cement exhibits favorable injectability and setting times, along with improved mechanical properties. The antimicrobial, osteoinductive, and osteoconductive properties of the CS_mod cement are confirmed using appropriate in vitro studies. There is an upregulation of the paracrine signaling mediated crosstalk between mesenchymal stem cells and human umbilical vein endothelial cells seeded on these cements. The ability of CS_mod to induce endothelial cell recruitment and augment bone regeneration is evidenced in relevant rat models. The results imply that the multipronged activity exhibited by the novel-CS_mod cement would be beneficial for bone repair.     

Suppression of buried oxide induced variability on digital performance of GeOI pMOSFETs using substrate bias scheme

Random variation in buried oxide thickness strongly affects the digital performance of ultra-thin body germanium-on-insulator MOSFETs. Dependencies of threshold voltage, ON-current, OFF-current and subthreshold slope of ultra-thin body germanium-on-insulator MOSFETs on three different BOX dielectrics are examined by employing well-calibrated Synopsys TCAD. The variation of threshold voltage and ON-current becomes less sensitive with high-k BOX dielectrics whereas smaller variation of OFF-current is observed for the device with low-k BOX dielectrics. The subthreshold slope remains almost unaltered for all BOX dielectrics. Furthermore, a positive substrate bias is found to suppress variability of digital performance parameters of GeOI p-MOSFETs.

     

Is cloned code really stable?

Clone has emerged as a controversial term in software engineering research and practice. The impact of clones is of great importance from software maintenance perspectives. Stability is a well investigated term in assessing the impacts of clones on software maintenance. If code clones appear to exhibit a higher instability (i.e., higher change-proneness) than non-cloned code, then we can expect that code clones require higher maintenance effort and cost than non-cloned code. A number of studies have been done on the comparative stability of cloned and non-cloned code. However, these studies could not come to a consensus. While some studies show that code clones are more stable than non-cloned code, the other studies provide empirical evidence of higher instability of code clones. The possible reasons behind these contradictory findings are that different studies investigated different aspects of stability using different clone detection tools on different subject systems using different experimental setups. Also, the subject systems were not of wide varieties. Emphasizing these issues (with several others mentioned in the motivation) we have conducted a comprehensive empirical study where we have - (i) implemented and investigated seven existing methodologies that explored different aspects of stability, (ii) used two clone detection tools (NiCad and CCFinderX) to implement each of these seven methodologies, and (iii) investigated the stability of three types (Type-1, Type-2, Type-3) of clones. Our investigation on 12 diverse subject systems covering three programming languages (Java, C, C#) with a list of 8 stability assessment metrics suggest that (i) cloned code is often more unstable (change-prone) than non-cloned code in the maintenance phase, (ii) both Type 1 and Type 3 clones appear to exhibit higher instability than Type 2 clones, (iii) clones in Java and C programming languages are more change-prone than the clones in C#, and (iv) changes to the clones in procedural programming languages seem to be more dispersed than the changes to the clones in object oriented languages. We also systematically replicated the original studies with their original settings and found mostly equivalent results as of the original studies. We believe that our findings are important for prioritizing code clones from management perspectives.     

Kitkaite NiTeSe,an Ambient-Stable Layered Dirac Semimetal with Low-Energy Type-II Fermions with Application Capabilities in Spintronics and Optoelectronics

The emergence of Dirac semimetals has stimulated growing attention, owing to the considerable technological potential arising from their peculiar exotic quantum transport related to their nontrivial topological states. Especially, materials showing type-II Dirac fermions afford novel device functionalities enabled by anisotropic optical and magnetotransport properties. Nevertheless, real technological implementation has remained elusive so far. Definitely, in most Dirac semimetals, the Dirac point lies deep below the Fermi level, limiting technological exploitation. Here, it is shown that kitkaite (NiTeSe) represents an ideal platform for type-II Dirac fermiology based on spin-resolved angle-resolved photoemission spectroscopy and density functional theory. Precisely, the existence of type-II bulk Dirac fermions is discovered in NiTeSe around the Fermi level and the presence of topological surface states with strong (≈50%) spin polarization. By means of surface-science experiments in near-ambient pressure conditions, chemical inertness towards ambient gases (oxygen and water) is also demonstrated. Correspondingly, NiTeSe-based devices without encapsulation afford long-term efficiency, as demonstrated by the direct implementation of a NiTeSe-based microwave receiver with a room-temperature photocurrent of 2.8 µA at 28 GHz and more than two orders of magnitude linear dynamic range. The findings are essential to bringing to fruition type-II Dirac fermions in photonics, spintronics, and optoelectronics.