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The Sn3.0Ag0.5Cu (wt.%) lead-free solder alloy is considered to be one of the most promising candidates to replace the traditionally used Sn–Pb solder. However, this alloy composition has some weaknesses, mainly as a result of its higher melting temperature compared to the eutectic Sn–Pb solder. In this paper, lead-free solder alloy nanoparticles of Sn3.0Ag0.5Cu were synthesized by chemical reduction with NaBH4 as reducing agent. The experimental results indicated that the major particle size of Sn3.0Ag0.5Cu nanoparticles was smaller than 100 nm. The melting and solidification properties of the Sn3.0Ag0.5Cu nanoparticles were studied by differential scanning calorimetry at different scanning rates. It was evidenced by the differential scanning calorimetry curves that the melting temperature of Sn3.0Ag0.5Cu nanoparticles was lower than that of the bulk alloy. In addition, the undercooling of the Sn3.0Ag0.5Cu nanoparticles was in the range of 82.0–88.5 °C at different cooling rates, which was much larger than that of the Sn3.0Ag0.5Cu micro-sized particles, showing stronger cooling rate dependence. 相似文献
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The orientation-dependent out-of-plane dielectric properties of barium stannate titanate (Ba(Sn0.15Ti0.85)O3 (BTS)) thin films prepared by sol–gel method were investigated. Films with (1 0 0), (1 1 0), and (1 1 1) orientation were grown on LaNiO3-buffered (1 0 0), (1 1 0), and (1 1 1) LaAlO3 (LAO) single-crystal substrates, respectively. The different temperature of the dielectric constant maximum (Tm) of the BTS thin films with different orientation was believed to be attributing to stress inside the films. Films with the (1 1 1) orientation had higher relative dielectric constant and tunability than (1 0 0)- and (1 1 0)-oriented films. This difference in dielectric properties in these three kinds of oriented BTS films may be attributed to change in the direction and magnitude of electric polarization in orientation engineered BTS films and stress in the films. 相似文献
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Zhai Wangyi Cao Yuanming Li Yifei Zheng Min Wang Zuoshan 《Journal of Materials Science》2022,57(4):2597-2609
Journal of Materials Science - The exploration of novel and multifunctional coatings through composite nanomaterials design is crucial for developing next-generation polyester fabrics. Herein, we... 相似文献
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普通六倍体小麦中存在为数不多的自然突变的Waxy蛋白亚基缺失小麦材料。选用自然突变形成的4种缺失1个或2个Waxy蛋白亚基的部分糯小麦材料,2种Waxy蛋白亚基全缺失的糯小麦品系,以普通中筋小麦济麦19作为对照,研究其籽粒性状和面团的粉质特性、揉混特性、拉伸和黏度特性。结果表明,糯小麦的籽粒硬度、直链淀粉含量与其他小麦相比明显偏低;部分糯小麦的直链淀粉含量比对照有不同程度的降低。面团的粉质特性、揉混特性和拉伸特性测定表明,糯小麦面团的吸水率极显著高于其他小麦,其稳定时间、断裂时间,揉混特性的中线峰值时间、峰值面积、8min尾高,拉伸特性的最大拉伸阻力、拉伸曲线面积、最大拉伸比显著低于对照,而部分糯小麦(江苏白火麦除外)的粉质参数(吸水率除外)、揉混参数、最大拉伸阻力、最大拉伸比均高于对照,达显著或极显著水平。黏度特性上,糯小麦的面团黏度、附着功、黏聚性较大,部分糯小麦(江苏白火麦除外)的面团黏度较小,均呈显著或极显著性差异。综合面团的流变学特性测定表明,糯小麦面粉的吸水率高,但面团的结构差,筋力弱;Sturdy、Satanata和IKE3个部分糯小麦的面团的耐揉性、耐搅性、面团筋力优于济麦19,也优于糯小麦;缺失Wx—D1亚基的江苏白火麦的大多数面团流变学参数与糯小麦无显著性或极显著性差异。 相似文献
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采用原子吸收分光光度法和高效液相色谱法等技术,检测了甜高粱茎杆汁的主要成分质量浓度,包括蔗糖、果糖和葡萄糖、总氮量以及若干金属元素质量浓度;采取响应面法建立尿素、MgSO4、KH2PO4、CaCl2等的加入量最优组合的二次回归数学模型。结果表明,当尿素、MgSO4、KH2PO4和CaCl2的添加量分别为8.4228、1.0938、4.1702和4.0422g/L时,乙醇发酵得率达93.18%,比优化前乙醇质量浓度提高了9.56g/L。 相似文献
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Zhennai Yang Shengyu Li Xue Zhang Xianpeng Zeng Da Li Yujuan Zhao Jian Zhang 《Journal of Bioscience and Bioengineering》2010,110(1):53-57
Exopolysaccharides (EPSs) produced by lactic acid bacteria (LAB) play an important role in the improvement of the physical properties of fermented dairy products. To find EPS-producing LAB strains with potential industrial applications, a Lactobacillus rhamnosus strain, L. rhamnosus JAAS8, that is capable of producing two forms of EPS when grown in MRS broth or semi-defined medium with glucose as a carbon source was isolated and identified from Chinese sauerkraut. The capsular-polysaccharide (CPS) present surrounding the bacterial surface of L. rhamnosus JAAS8 was observed by both optical microscopy and transmission electron microscopy. The slime-polysaccharide (SPS) present in the growth medium was produced mainly during the exponential growth phase, while the CPS was produced only in fermentation. Monosaccharide analysis of the purified polysaccharide samples showed that the CPS was composed of galactose and N-acetylglucosamine in a molar ratio of 5:1, and the SPS was composed of galactose, glucose and N-acetylglucosamine in a molar ratio of 4:1:1. The use of L. rhamnosus JAAS8 could be considered for potential applications in the dairy industry to improve the rheological properties of fermented milk products by increasing their water-holding capacity and viscosity. 相似文献