Development of optimized triaxially electrospun titania nanofiber-in-nanotube core-shell structure

One dimensional (1D) nanostructures and its derivatives can be manipulated to serve special functions like hollow structure, and higher surface area. 1D TiO₂ nanotube-in-nanofibers (NF@NT) are developed through triaxial electrospinning followed by a calcination process. A blended solution of polyvinyl pyrrolidone and tetra-butyl titanate is used in outer and inner layers of nanofibers, respectively, while paraffin oil is used in the middle layer. The optimized triaxial nanofibers of 669.4 ± 52.43 nm are developed at 7.5 w/w% concentration, 28 kV applied voltage, and 24 cm spinning distance. TiO₂ NF@NT structure is obtained through calcination of optimized triaxial nanofibers at 550°C. Subsequently, the morphology of TiO₂ NF@NT and its uniform diameter distribution is confirmed through scanning electron microscopy. Fourier-transform infrared spectroscopy results indicates the formation of TiO₂ NF@NT. X-Rays diffraction pattern peaks also reveals the presence of both anatase and rutile crystalline phases. The presence of only titanium (Ti) and oxygen (O) elements in the TiO₂ NF@NT is confirmed through energy dispersive X-ray spectroscopy. Brunauer–Emmett–Teller analysis indicates that TiO₂ NF@NT has a higher specific surface area of ~141.68 m²/g compared with the solid TiO₂ nanofiber (~75.31 m²/g). This study can be adopted to develop TiO₂ NF@NT for wide range of application.     

Quality assurance and authentication of herbal drug (Argyrolobium roseum and Viola stocksii) through comparative light and scanning electron microscopy

The quality assurance and authentication of crude herbal drugs play important role in the effective therapeutic effect of herbal drug and their products. There are many reported problems in quality assurance of herbal crude drugs concerning to their correct identification. The present study was designed with the aim to document the authentication and quality assurance of the herbal crude drugs (Argyrolobium roseum and Viola stocksii) thorough light microscopy (LM) and scanning electron microscopy (SEM). The detailed foliar anatomical studies showed polygonal epidermal cells having anticlinal walls in Argyrolobium roseum while rounded epidermal cells were observed in Viola stocksii. The anomocytic stomata type was observed in Argrolobium roseum while actinocytic was noticed in Viola stocksii. The pollen of studied species appeared as tricolporate showing reticulate exine sculpturing in Argrolobium roseum while fine perforations were recorded in Viola stocksii. Furthermore, quantitative analysis of phenols, flavonoids, and antioxidant activity showed high flavonoid and phenol content in Argyrolobium roseum as compared with Viola stocksii. It was observed that Argyrolobium roseum was discriminated from the Viola stocksii based on the leaf and pollen micromorphological traits by using LM and SEM techniques. It was concluded that LM and SEM techniques were found useful for the quality assurance of botanicals and their authentication.     

Effect of polyphenol from apple peel extract on the survival of probiotics in yoghurt ice cream

The objective of this study was to evaluate the effect of apple peel polyphenol extract (APPE) on the microbiological and physicochemical properties of yoghurt ice cream stored at −20 °C for 90 days. Five level of APPE were added in yoghurt ice cream as: CTL (control without APPE); AE1 (1% APPE); AE2 (2% APPE); AE3 (3% APPE); AE4 (4% APPE); and AE5 (5% APPE). Samples with APPE had viable counts of Lactobacillus acidophilus and Bifidobacterium lactis of ≥8 log cfu g⁻¹ and >7 log cfu g⁻¹, respectively, during 90 days storage except the control sample. The highest viability of probiotics was obtained in the sample fortified with 5% APPE. The presence of APPE increased the acidity, decreased the melting rate and enhanced the overrun. Compared with the control sample, the hardness of the experimental samples increased with the fortification of APPE. The addition of APPE significantly increased sensory attributes.     

Analysis of organometallics dispersed polymer composite irradiated with oxygen ions

Thin films of polymethyl methacrylate (PMMA) were synthesized. Ferric oxalate was dispersed in PMMA films. These films were irradiated with 80 MeV O⁶⁺ ions at a fluence of 1×10¹¹ ions/cm². The radiation induced changes in electrical conductivity, Mössbauer parameter, microhardness and surface roughness were investigated. It is observed that hardness and electrical conductivity of the film increases with the concentration of dispersed ferric oxalate and also with the fluence. It indicates that ion beam irradiation promotes (i) the metal to polymer bonding and (ii) convert the polymeric structure into hydrogen depleted carbon network. Thus irradiation makes the polymer harder and more conductive. Before irradiation, no Mössbauer absorption was observed. The irradiated sample showed Mössbauer absorption, which seems to indicate that there is significant interaction between the metalion and polymer matrix. Atomic force microscopy shows that the average roughness (R _a) of the irradiated film is lower than the unirradiated one.     

An optimized hybrid algorithm in term of energy and performance for mapping real time workloads on 2d based on-chip networks

In this paper, we propose an optimized, search based near-optimal mapping heuristic, named as ONMAP for mapping real time embedded application workloads on 2D based on-chip interconnection network platforms. ONMAP exploits NMAP, a well-known and fast nearest neighbor heuristic algorithm by using the modular exact optimization method. The proposed hybrid algorithm minimizes the on-chip inter-processor communication energy consumption and optimizes the interconnection network performance parameters. The algorithm inherits the constructive search based heuristic nature of the NMAP algorithm, as well as the property of exact optimization for mapping embedded applications on the target communication architecture. To verify the efficiency and effectiveness of the algorithm, we have compared the proposed algorithm with NMAP and random mapping algorithm under similar simulation environments and traffic conditions. The mapping results of the exemplary real world applications such as VOPD, PIP, MPEG4, MWD, MMS and WiFi-80211arx indicate that ONMAP algorithm is more efficient than its competitors for most of the performance parameters of the on-chip network designs. The algorithm successfully optimized the energy consumption, up to 20 % and 26% in comparison to NMAP and random algorithms, respectively. Similarly, the cost is optimized up to 10% and 60% as compared to NMAP and random mapping algorithms, respectively.     

Role of Ni<Superscript>2+</Superscript> Ions in Magnetite Nano-particles Synthesized by Co-precipitation Method

In the present work, nickel-doped iron oxide (Ni_xFe_3?x O ₄) nanoparticles with different concentration of nickel (x = 0, 0.05, 0.1, and 0.15) have been prepared by co-precipitation method. These prepared nanoparticles have been characterized by using x-ray diffractometer, thermo gravimetric analysis and differential scanning calorimetry, Fourier transform infrared spectroscopy, scanning electron microscopy, vibrating sample magnetometer, and UV-Visible spectroscopy to study their structural, thermal, morphological, magnetic, and optical properties, respectively. The x-ray diffraction confirms the formation of single-phase inverse spinel cubic structure of NiFe₃ O ₄ nanoparticles. Crystallite size has been estimated by the full width at half maximum of the most intense x-ray diffraction peak where vibrational and stretching modes of metal-oxygen bonds in 872 cm are shown in Fourier transform infrared spectra which confirms the formation of nanoparticles. The thermal analysis revealed that the transition temperature and stability increases with increasing Ni concentration. The surface morphology indicated that the particles are spherical in shape with some agglomeration. The magnetic measurement revealed that the coercivity and anisotropy increases with nickel doping in magnetite nanoparticles. The optical analysis revealed that direct and indirect both types of band gap increases when the particle size decreases because the absorption spectra shift toward smaller wavelength. The blue shift confirms the formation of nanoparticles.     

Leaf Image-Based Plant Disease Identification Using Color and Texture Features

Wireless Personal Communications - Identification of plant disease is usually done through visual inspection or during laboratory examination which causes delays resulting in yield loss by the time...