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61.
S.?H.?Yu H.?S.?Ryoo S.?K.?HwangEmail author D.?H.?Shin 《Metals and Materials International》2003,9(2):107-114
Grain boundary character distribution in equal-channel-angular pressed Zr was studied. Using a die design of 90°/20° and an
operation temperature of 350°C. The initial grain size of 20 μm was reduced to about 270 nm with 4 passes via route Bc. The grain growth kinetics of the recrystallized state was obtained by experiment and Monte-Carlo computer simulation, respectively,
which showed good agreement. Based on kinetics and morphological characteristics, it was concluded that the grain coarsening
mechanism was governed by normal grain growth. No sign of abnormal grain growth was detected either in the experiment or in
simulation despite taking into consideration anisotropy in grain boundary energy as well as its mobility. This indicates that
grain boundaries produced by severely deformed Zr are stable against explosive coarsening. The evolution characteristics of
the microstructure in the present ECA pressed and recrystallized Zr differed from those of cold rolled Ti in that the grain
boundary misorientation distribution and texture were rather stable during grain growth.
Jointly Appointed by the Center for Advanced Aerospace Materials
This article is based on a presentation made in the 2002 Korea-US symposium on the “Phase Transformations of Nano-Materials,”
organized as a special program of the 2002 Annual Meeting of the Korean Institute of Metals and Materials, held at Yonsei
University, Seoul, Korea on October 25–26, 2002. 相似文献
62.
Koo Hyun Lee Ki Suk Nam Youl Min Park Pyung Woo Shin Deuk Yong Lee Yo-Seung Song 《Metals and Materials International》2002,8(4):381-385
Plasma nitrocarburized AISI 1020 steels were oxidized for 15, 30 and 60 min to evaluate their corrosion and microstructural properties. After plasma nitrocarburizing for 3 h at 570°C in a gas mixture comprising 85 vol.% N2, 12vol.% H2 and 3 vol.% CH4, the compound layer composed of ɛ-Fe2–3(N,C) and γ’-Fe4(N,C) phases and the diffusion layer above the matrix were observed. The top oxide layer, consisting mainly of magnetite (Fe2O4) and hematite (Fe2O3) phases, forms after post-oxidation treatment at 500°C. However, the oxide layer was severely degraded by spallation as a result of increases in post-oxidizing time. The difference in corrosion resistance should be attributed to the thickness of the top oxide layer, which was governed by post-oxidizing time. 相似文献
63.
Preparation of zeolitic adsorbents from waste coal fly ash 总被引:1,自引:0,他引:1
Power plants burning coal generate a large amount of fly ash as waste matter. The objective of this study is to produce zeolitic
adsorbents that possesses high adsorptive capacity for toxic cations. The sample was first pretreated with a High Intensity
Magnetic Separator for the removal of iron and magnetic materials (mainly Fe2O3 and TiO2). The zeolitic adsorbents were prepared under the various conditions of NaOH concentration (1–5 N), reaction time from 3
to 96 hours and at the various temperatures of 60, 80 and 100°C. The results of the experiment showed that the coal fly ash
should be synthesized with 4 N NaOH for 48 hours at 100°C in order to have good adsorptive capacity. The zeolitic adsorbents
showed higher cation exchange capacity values than the natural zeolite in removing NH
4
+
, Pb2+, Ca2+and Cd2+ions. 相似文献
64.
Zempachi Ogumi Hiroya Yamashita Koji Nishio Zen-Ichiro Takehara Shiro Yoshizawa 《Electrochimica acta》1983,28(11):1687-1693
The feasibility of a solid polymer electrolyte (SPE) method for Kolbe type reactions was investigated by using Pt-SPE composed with Nafion 415 and platinum. The Kolbe reaction of acetic acid proceeded effectively on one side and both sides Pt-SPE composites. The lower current efficiency was observed on the latter than on the former. Neat acetic acid could also be electrolysed on both sides SPE though the cell voltage was fairly high.A methanolic solution of monomethyl adipate was electrolysed to give dimethyl sebacate on both sides Pt-SPE according to the Brown-Walker reaction. The current efficiency and the terminal voltage increased with the concentration of monomethyl adipate. Pt-SPE behaved as an active electrode of a high roughness factor, eg about 6, for the Kolbe reaction of acetate. 相似文献
65.
Boo Young Shin Sang Hee Jang In Jae Chung Bong Shik Kim 《Polymer Engineering and Science》1992,32(1):73-79
Two thermotropic liquid crystalline polyesters (TLCPs) with long flexible spacer groups in the main chain were prepared by melt polymerization: one was a homopolymer with only decane groups (LCPHO) and the other was a copolymer with hexane or decane groups (LCPCO) between mesogen units. These polyesters were blended with a matrix polymer of poly(ethylene terephthalate) (PET). Scanning electron microscopy (SEM) revealed the excellent interfacial adhesion between polyester and PET, and the large aspect ratio of polyester microfibrils in the blend fiber made by extruding and drawing the blend through a die. The aspect ratio was estimated by using the modified Halpin-Tsai equation. The fiber with LCPHO showed more extensive fibril formation than that with LCPCO. 相似文献
66.
Masuhiro Tsukada Hiroshi Katoh Donna Wilson Bong‐Seob Shin Takayuki Arai Ritsuko Murakami Giuliano Freddi 《应用聚合物科学杂志》2002,86(5):1181-1188
The work presented here discusses a new technique for preparing silk fibers and films with persistent antimicrobial activity through use of metallic dyestuffs during the fiber dyeing process. The length of the silk fibers investigated contracted when the fibers were immersed in concentrated neutral salt solutions, such as calcium or potassium nitrate, at elevated temperature levels. The birefringence and molecular orientation of the silk fibroin molecules became less ordered by the action of the neutral salt solutions, resulting in increased dyestuff absorption. Subsequently, contracted silk fibers were dyed with metallic dyestuffs containing Cr or Cu for the purpose of obtaining silk fibers with antimicrobial activity. Silk fibers dyed with metallic dyestuffs showed significant antimicrobial activity against the plant pathogen Cornebacterium and the human pathogen Coli bacillus. Tensile strength of the silk fibers after the salt shrinking and dyeing processes did not show a significant change, whereas the elongation at break was increased slightly. The techniques described here for preparing significantly active antimicrobial silk fibers are effective and economic ways of providing new materials for industrial and biomedical applications. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1181–1188, 2002 相似文献
67.
T. J. Shin H. K. Park S. W. Lee B. Lee W. Oh J.‐S. Kim S. Baek Y.‐T. Hwang H.‐C. Kim M. Ree 《Polymer Engineering and Science》2003,43(6):1232-1240
A series of aromatic polyimides composed of well‐defined conjugation units were synthesized form 5,5′‐bis(4‐aminophenyl)‐2,2′‐bifuryl (PFDA) and 2,2′‐bis(furyl) benzidine (FurylBZ) with various dianhydrides. The synthesized polyimides emit blue to green light with a quantum yield of 7.3–14.9%, depending on the polymer backbone. In particular, PFDA‐based polymers exhibit extremely narrow photo‐luminescence. The structure, thermal stability, refractive index and dielectric properties of the polymer films were also determined. 相似文献
68.
Seong‐Ho Choi Min‐Seok Kim Jae Jeong Ryoo Kwang‐Pill Lee Hyun‐Dong Shin Sun‐Hwa Kim Yong‐Hyun Lee 《应用聚合物科学杂志》2002,85(11):2451-2457
Carboxylic acid groups were introduced onto polyethylene (PE) film by radiation‐induced graft copolymerization. Subsequently, the clodextrin glucanotransferase (CGTase) was immobilized on the PE film with a carboxylic acid group. The activity of the immobilized CGTase on PE film was in the range of 0.40–1.04 U/cm2 per min. The production of cyclodextrins (CDs) from corn starch was examined using the CGTase‐immobilized PE film. The production ratios of CDs using CGTase‐immobilized PE film was in the following order: α–CD > β–CD > γ–CD. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2451–2457, 2002 相似文献
69.
Do‐Hung Han Jae‐Hyuk Jang Hye‐Young Kim Byung‐Nam Kim Boo‐Young Shin 《Polymer Engineering and Science》2006,46(4):431-437
The high melt viscosity of polypropylene was studied by grafting bifunctional monomers, 1,6‐hexanediol diacrylate (HDDA) and tripropylene glycol diacrylate (TPGDA), onto homopolypropylene (HPP) and random ter‐polypropylene (RTPP) under electron‐beam irradiation. Creation of the high‐melt‐viscosity polypropylene was possible at low radiation dosage and low monomer content, under a prohibition of both radiation degradation and homopolymerization. TPGDA monomer was more effective in increasing the melt viscosity of HPP compared with RTPP, whereas HDDA monomer was more effective for enhancing the melt viscosity of RTPP. Such different effects of monomers on melt viscosity may arise from different monomer structures, namely, TPGDA has additional three methyl groups, but HDDA has no methyl groups. Electron‐beam radiation technology, on an increase of the melt viscosity, was much more effective in HPP than RTPP, when compared with virgin polymers. Modified RTPP and HPP with high melt viscosity were capable of foaming with numerous fine cells, of which the modified HPP with 1.5 mmol TPGDA and 0.5 kGy could create more spherical foam cells and its bending strength was 1.5 times more than that of the foamed RTPP. POLYM. ENG. SCI., 46:431–437, 2006. © 2006 Society of Plastics Engineers. 相似文献
70.
Sang-Gon Kim Jong-Sung Park Jae-Sul An Kug Sun Hong Hyunho Shin Hyungsun Kim 《Journal of the American Ceramic Society》2006,89(3):902-907
Various types of crystalline ceramic fillers (TiO2 , ZrO2 , Al2 O3 , MgO, and cordierite) were added to BaO–ZnO–B2 O3 –SiO2 (BZBS) glass (5–20 wt%), and the resultant dielectric constant, coefficient of thermal expansion (CTE), and optical reflectance were investigated for the application of the composites to the barrier ribs in plasma display panels. All the investigated fillers were partially dissolved into the glass at the fabrication temperature (575°C), and the residual fillers were aligned along the boundaries of sintered glass frits. By considering all aspects of the properties, the addition of TiO2 fillers of about 10 wt% to BZBS glass was the most desirable of the types of fillers investigated. The addition of TiO2 filler (10 wt%) yielded 61% in optical reflectance, 8.3 × 10−6 K–1 in coefficient of thermal expansion, and 15.5 in dielectric constant, which were properties comparable with the currently used Pb-based barrier ribs. 相似文献