Observation of iron silicide formation by plan-view transmission electron microscopy

The formation and the phase transitions of iron silicide by solid-phase epitaxy have been investigated by means of plan-view transmission electron microscopy, which enables us to observe a clean interface between Fe and Si. Layers of Fe were deposited on Si (100) at room temperature in an ultrahigh vacuum chamber. The sample was annealed in the electron microscope at a temperature between 673 and 1073 K. After annealing at 673 K, FeSi crystallites were formed with various orientations. When the annealing temperature was increased to 973 K, we found that the crystallites suddenly started to coalesce into grains of several hundreds of nanometers in size and polycrystalline beta-FeSi2 was formed. These phase transitions were also confirmed with electron energy-loss spectroscopy.     

Application of the double slip plane crack model to temperature and strain rate sensitive BCC metals

The double slip plane crack model proposed by Weertman, Lin and Thomson (1982) has been applied to model the effect of temperature and strain rate on the stress intensity factor at a crack tip in temperature and strain rate sensitive materials. Increase in temperature or decrease in strain rate (as well as a decrease in slip plane spacing) are shown to increase the shielding of the crack tip by dislocation distributions on the slip planes. Furthermore, the effect of temperature on the fracture toughness, K_llc, at various strain rates was shown to exhibit the same sigmoidal shaped curve seen for K_lc data in typical alloy steels.     

The calculation of particle deposition efficiency due to inertia,diffusion and interception in a plane stagnation flow

The particle deposition mechanism in a plane stagnation flow is investigated analytically and numerically. Particle deposition efficiency η_TID is obtained theoretically by taking into account particle inertia, diffusion and interception. It is compared with various calculated deposition efficiencies, i.e. η_T (due to inertia) + η_I (due to interception) + η_D (due to diffusion), η_TI, (due to inertia and interception) + η_D, etc. In the region where all of the three deposition mechanisms, i.e. inertia, interception and diffusion, act at the same time, real deposition efficiency η_TID is not accurately expressed by η_T + η_I + η_D. However, η_TID is nearly equal to η_TI + η_D unless the interception parameter is zero.The calculated results of particle concentration indicate that a high concentration region is formed near the deposition plate, and that the concentration becomes higher as particle inertia increases.     

Asymmetric aldol polymerization of bis(triethylsilyl enol ether) and dialdehyde

Summary Mukaiyama aldol reaction smoothly occurred between bis(triethylsilyl enol ether) and dialdehyde in the presence of Lewis acid catalyst to yield polymers that consist of -hydroxy carbonyl repeating units. When chirally modified Lewis acid catalyst was used, the optically active poly(-hydroxy ketone)s were obtained by means of the asymmetric aldol polymerization.     

Effects of low-dose cadmium exposure on biological examinations

We conducted an epidemiological study to investigate the effects of low-dose cadmium (Cd) exposure on human health in a specific area of a town in Japan where low Cd concentration was detected in rice. We compared clinical findings, urinary and whole blood Cd concentrations, and indicators of renal dysfunction between the polluted area and the control area. The study employed 44 men and 54 women from the polluted area and 21 men and 29 women from the control area. In urine analysis, as indicators of Cd exposure and possible related renal dysfunction, Cd, beta(2)-microglobulin (beta(2)-MG), alpha(1)-microglobulin (alpha(1)-MG), N-acetyl-beta-D-glucosaminidase (NAG), total protein, inorganic phosphorus, lysozyme and creatinine were quantitatively measured. In blood analysis, serum IP and creatinine and whole blood Cd were measured. No case of renal dysfunction due to Cd exposure was confirmed. However, both the urinary and whole blood Cd of the polluted area were significantly higher than those of the control area for both sexes. Urinary beta(2)-MG did not differ between the two areas. For women, urinary alpha(1)-MG was significantly higher in the polluted area than in the control area. In correlation analysis, beta(2)-MG, alpha(1)-MG and NAG, were positively correlated with both of urinary and whole blood Cd for men and women in the polluted area except for between urinary beta(2)-MG and urinary Cd for men. In the control area, the sole positive correlation observed was between urinary beta(2)-MG and whole blood Cd for men. We then examined the determinants of variations of parameters in urinary and blood tests. Potential determinants were age, sex, body mass index, an indicator of smoking habits (cigarette index) and the index of estimated Cd intake from rice (Cd-rice-index). Cd-rice-index was expressed as the product of Cd concentrations in homegrown rice multiplied by daily frequency multiplied by duration (years) of residence in the polluted area. In multiple regression analysis, whole blood Cd was independently associated with Cd-rice-index, age and gender. Variations in whole blood Cd accounted for a substantial portion of the variations in urinary Cd, although they were less influential in older individuals. Whole blood Cd was the sole independent variable related to variations in urinary beta(2)-MG. Cd-rice-index accounted for a portion of the variance in urinary NAG, while age was a more powerful determinant. It was thus revealed that the consumption of homegrown rice polluted with Cd in low concentration resulted in an elevation of whole blood Cd level and consequent increase in urinary Cd level. However, it was not clearly elucidated that the excretion of urinary low-molecular microglobulins could increase significantly in response to slight elevation of Cd body load.     

Discrimination of psychoactive fungi (commonly called "magic mushrooms") based on the DNA sequence of the internal transcribed spacer region

'Magic mushrooms' (MMs) are psychoactive fungi containing the hallucinogenic compounds, psilocin (1) and psilocybin (2). Since June 6, 2002, these fungi have been regulated by the Narcotics and Psychotropics Control Law in Japan. Because there are many kinds of MMs and they are sold even as dry powders in local markets, it is very difficult to identify the original species of the MMs by morphological observation. Therefore, we investigated the internal transcribed spacer (ITS) region in the ribosomal RNA gene of MMs obtained in Japanese markets to classify them by a genetic approach. Based on the size and nucleotide sequence of the ITS region amplified by PCR, tested MMs were classified into 6 groups. Furthermore, a comparison of the DNA sequences of the MMs with those of authentic samples or with those found in the databases (GenBank, EMBL and DDBJ) made it possible to identify the species of tested MMs. Analysis by LC revealed that psilocin (1) was contained at the highest level in Panaeolus cyanescens among the MMs, but was absent in the Amanita species.     

Polygon visibility ordering via Voronoi diagrams

Visibility determination is one of the oldest problems in computer graphics. The visibility, in terms of back-to-front polygon visibility ordering, is determined by updating a priority list as the viewpoint moves. A new list-priority algorithm, utilizing a property of Voronoi diagrams, is proposed in this paper. The operation is in two phases. First, in a pre-processing phase the scene is divided into Voronoi cells. A sub-list associated with each cell contains references to those polygons that intersect with it. The polygons are assigned a fixed set of view-independent priority orders within the cluster. Last, an interactive phase sorts the clusters according to the depth value of each Voronoi site. The most time-consuming work is performed during the pre-processing phase that only has to be executed once for the scene. Since all the polygons in a cell are pre-computed to obtain the fixed priority order within the cluster, a relatively simple task is left in the interactive phase, which is only to sort the clusters repeatedly when the viewpoint is changed. This method contains performance benefits that make it better shaped than previous BSP based methods.     

Bond-order potential for transition metal carbide cluster for the growth simulation of a single-walled carbon nanotube

A classical many-body potential for transition metal carbide cluster is developed in the form of the bond-order type potential function. The parameter sets between carbon atoms and several transition metal atoms (Fe, Co and Ni) are constructed by fitting binding energies from Density Functional Theory (DFT) calculations. Using the potential function, clustering process of carbon atoms to a small metal cluster is studied by classical molecular dynamics (MD) simulation. The number of hexagonal rings in the Co cluster increases about twice as fast as in the Fe cluster. This implies that the graphitic lattice interacts more strongly with Co atoms than with Fe atoms. A Co cluster has a crystal structure where metal atoms are regularly allocated and embedded in the hexagonal carbon network in the simulation. In contrast, carbon atoms cover the entire surface in case of the Fe cluster. Additionally, the potential energy surface that a carbon atom feels from a 2D closed-packed facet is examined using a hypothetical FCC(1 1 1) facet of several transition metals. The potential energy minima are distributed on the hexagonal network showing the 2D closed-packed facet can be a template where a graphene is formed.     

Advanced CD Control Technology for 65-nm Node Dual Damascene Process

This paper describes an advanced critical dimension (CD) control technology for a 65-nm node dual damascene process and beyond. A newly developed deposition enhanced shrink etching (DESE) process was introduced into both via and trench etching. This technology realizes not only dynamic via shrink ranging 40 nm but also accurate trench CD control by feedforward technology. Etching performance was investigated by electrical results of 65-nm Cu/low-k interconnects using porous chemical-vapor deposition SiOC. The 100% yields of 60-M via chains verified the DESE process robustness.