Redox‐Active Polymers Connecting Living Microbial Cells to an Extracellular Electrical Circuit

Microbial electrochemical systems in which metabolic electrons in living microbes have been extracted to or injected from an extracellular electrical circuit have attracted considerable attention as environmentally‐friendly energy conversion systems. Since general microbes cannot exchange electrons with extracellular solids, electron mediators are needed to connect living cells to an extracellular electrode. Although hydrophobic small molecules that can penetrate cell membranes are commonly used as electron mediators, they cannot be dissolved at high concentrations in aqueous media. The use of hydrophobic mediators in combination with small hydrophilic redox molecules can substantially increase the efficiency of the extracellular electron transfer process, but this method has side effects, in some cases, such as cytotoxicity and environmental pollution. In this Review, recently‐developed redox‐active polymers are highlighted as a new type of electron mediator that has less cytotoxicity than many conventional electron mediators. Owing to the design flexibility of polymer structures, important parameters that affect electron transport properties, such as redox potential, the balance of hydrophobicity and hydrophilicity, and electron conductivity, can be systematically regulated.     

Zero-Sequence Voltage-based Method for Determination and Classification of Unloaded Overhead Line Operating Conditions at the Moment of Energization

Overhead line energization can be performed under normal or faulty conditions. The latter indicates an occurrence of a fault along the line that exists at the moment of energization. This can lead to significant over-voltages that could endanger proper line operation. The issue gets more complex to protective devices when it comes to high-resistance faults, which impair the ability of relays to react promptly and accurately. Consequently, installation of additional detection devices becomes necessary. This paper proposes a novel method that properly detects and classifies line operating conditions at the moment of energization. The method is designed to be useful for utilities and it can be considered as a low-cost, fast, and accurate detection and classification approach, suitable for dealing with both low-resistance and high-resistance faults. Through comprehensive mathematical modeling it was found that both normal and faulty conditions during line energization are accompanied by the zero-sequence voltages of specific characteristics. The differences between zero voltage sequences are reflected in harmonic content, magnitudes of dominant frequencies, and their phase angles in regard to supply voltage. These findings are taken as the method's detection and classification criteria. The validity of the proposed model is verified by simulations and by field measurements.     

圆弧“U”形结构安装座铸造工艺改进

安装座为精铸件,其结构总体呈半圆弧形,一端为“U”形结构,该产品主要工艺难点为圆弧径向及“U”形结构开口端易变形,圆弧径向两端加工后易出现“黑皮”。通过工艺改进运用反变形工艺、工艺拉筋等工艺措施有效解决铸件变形问题,提高产品铸造工艺出品率。     

Laterally vibrating MEMS resonant vacuum sensor based on cavity-SOI process for evaluation of wide range of sealed cavity pressure

Microsystem Technologies - This paper reports a laterally vibrating MEMS resonant vacuum sensor which senses ambient pressure based on the squeeze-film damping effect. The single-anchored...     

Analysis of constant-volume shear tests based on precise measurement of stresses in powder beds

This study demonstrates a new constant-volume shear test configuration to analyze the stresses in powder beds and evaluate powder flowability. A novel cylindrical shear cell geometry and load cell arrangement allowed precise measurement of the normal stress acting on the shear planes of the powder beds. The stress transmission ratio between the top and shear planes decreased with increasing ratio of the powder bed height in the upper section of the shear cell to the shear cell diameter. This was due to friction between the powder bed and the side wall of the upper section of the shear cell. Using the measured values of the normal stress on the shear planes, the effects of the powder bed height and shear cell diameter were eliminated from the data. In addition, to evaluate the shear properties of the powder beds, the powder yield locus, consolidation yield locus, critical state line, shear cohesion, and void fraction were obtained from a single shear test. The powder yield locus data were used to obtain flow functions.     

Characterization of mixing performance in a microreactor and its application to the synthesis of porous coordination polymer particles

Here we quantitatively evaluated the mixing performance of a tailor-made microreactor with central-collision type through the iodide/iodate chemical test reaction, and applied the microreactor to the synthesis of zeolitic imidazolate framework-8 (ZIF-8), which is a subclass of porous coordination polymers (PCPs) or metal organic frameworks (MOFs). The chemical test reaction demonstrated excellent mixing performance of the microreactor with a characteristic mixing time shorter than 1 ms, which is approximately 100 times faster than those of a batch reactor and a millimeter-sized Y-shaped mixer. Taking advantage of the rapid and uniform mixing, the microreactor successfully produced ZIF-8 particles with high reproducibility by simply mixing aqueous solutions of zinc nitrate and 2-methylimidazole. The synthesis at room temperature resulted in ZIF-8 particles with chamfered cube shape, while a lower temperature of 5 °C produced raspberry-type spherical particles. We confirmed that prepared ZIF-8 particles have BET surface area of ～1500 m²/g and exhibit the gate adsorption behavior caused by the structural transition of the ZIF-8 framework.     

Quantitative analysis of agglomerates levitated from particle layers in a strong electric field

The electrification, agglomeration, and levitation of particles in a strong electric field were analyzed experimentally and theoretically. Particle layers of glass, alumina, and ferrite were formed on a plate electrode and an external voltage was applied. Microscopic observations of the agglomerates levitated from the particle layers revealed that the number of primary particles constituting an agglomerate is affected by particle diameter and electrical resistance, but not by the applied electric field. The electric field distributions in the system were calculated by considering the charges and geometries of the agglomerates formed on the particle layers. The charges of the agglomerates were obtained experimentally. All forces acting on the agglomerates (i.e., gravitational forces, Coulomb forces, interaction forces between polarized particles, image forces, and gradient forces) were analyzed under different conditions, including various electric field distributions and charges of agglomerates. Furthermore, the critical conditions for the levitation of the agglomerates were evaluated using a force balance.     

Optimization of Digital Growth of Thick N-Polar InGaN by MOCVD

Smooth 200 nm thick N-polar InGaN films were grown by metal–organic chemical vapor deposition (MOCVD) on sapphire using a digital approach consisting of a constant In, Ga, and N precursor flow with pulsed injection of H2 into the N2 carrier gas. Using this growth scheme, the H2 injection time was altered and the effect on the morphology and indium incorporation in the films observed. The effect of periodic insertion of additional GaN inter-layers on the surface morphology of the InGaN layers was also studied.     

Properties of syndiotactic-rich poly(vinyl alcohol) thin film in water. V. Effect of initial temperature of heating on elongation

The effect of the initial temperature of heating on the elongation of syndiotactic-rich poly(vinyl alcohol) thin films was investigated in water under a load. The elongation ratios E_i after 4 h at fixed temperatures increased roughly with an increase in the initial temperature T_i and a decrease in the annealing temperature. E_i after 4 h was the smallest at T_i = 45°C for the films annealed at temperatures below 100°C. E_i was 6.8 at T_i = 60°C for the unannealed film and 1.12 at T_i = 70°C for the film annealed at 200°C. The elongation at break decreased and the temperature at break increased with an increase in annealing temperature, but those at the annealing temperature of 100°C were the smallest. The films annealed at 200°C did not break even at 98°C (boiling temperature) in water and the elongation ratio was 1.42–1.97 in the initial temperature range of 10–70°C. From these results, the relation between the elongation in water and the state of polymer chains in film was discussed.     

Porous cellulose acetate membrane prepared by thermally induced phase separation

Microporous cellulose acetate membranes were prepared by a thermally induced phase separation (TIPS) process. Two kinds of cellulose acetate with acetyl content of 51 and 55 mol % and two kinds of diluents, such as 2‐methyl‐2,4‐pentandiol and 2‐ethyl‐1,3‐hexanediol, were used. In all polymer‐diluent systems, cloud points were observed, which indicated that liquid–liquid phase separation occurred during the TIPS process. The growth of droplets formed after the phase separation was followed using three cooling conditions. The obtained pore structure was isotropic, that is, the pore size did not vary across the membrane. In addition, no macrovoids were formed. These pore structures were in contrast with those usually obtained by the immersion precipitation method. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3951–3955, 2003