Dynamic behavior analysis of reciprocating compressor with subsidence fault considering flexible piston rod

Subsidence wear is inevitable in a reciprocating compressor system, but how to induce body vibration is not clear. We investigated the dynamic behavior of a reciprocating compressor system with subsidence fault considering a flexible piston rod. The flexible piston rod was modeled as a cantilever beam. The dynamic model, in which the influence of the subsidence size, variational cylinder pressure, impact effects and piston rod flexibility are taken into account, was established. Influences of the four parameters including subsidence size, vertical force of flexible piston rod, cylinder pressure and crankshaft speed were analyzed in the dynamic response. Numerical results reveal that with the change of the four parameters, the existence of subsidence fault has a significant effect on the displacement, velocity and acceleration of the crosshead in the transverse direction, but only conspicuously affects the acceleration in the longitudinal direction. In addition to cylinder pressure, the larger the values of the other three parameters, the greater the influences. The cylinder pressure is a time-varying working load. Not only the cylinder pressure but also the open/close time of the valves and change rate of the pressure all affect the dynamic behavior of the system with subsidence. Meanwhile, the change in the vertical force of the flexible piston rod has a remarkable effect on the jump position of the crosshead, but the effect of other parameters is not obvious. In addition, the changes of parameters produce obvious influences on the impact force and the impact range of the crosshead. The stability of the reciprocating compressor system was studied using Poincaré portraits method. The result shows that the system with subsidence fault has chaotic behavior.     

振动磨碎机动力学分析及仿真试验

通过建立介质层的运动方程和仿真试验,研究振动磨碎机磨腔内介质群的运动规律.考虑弹性力和阻尼力的影响,建立振动磨碎机的微分方程,描述机体的动态特性.分析系统在简谐激励力作用下,机体结构产生的应力和变形.研究结果表明,在适当的振动强度下,介质群以一定的频率做相对于筒体中心的回转运动,介质在一定的区域形成稳定的圆弧状运动轨迹,在其他区域形成一种级联式的抛射运动,物料流动方向和离心力方向一致,从而减小传统振动磨磨腔心部乏能区的范围.机体在持续的激励力作用下产生圆周运动轨迹,改善介质群的运动状态,获得高效的研磨效果和狭窄的粒度分布.当激振频率与系统的固有频率接近时,受迫振动的动荷系数骤然增加,系统的振幅将达到最大值,结构设计时应予以注意.     

基于正交匹配追踪的周期非均匀采样研究

结合正交匹配追踪算法,提出了一种针对稀疏信号的周期非均匀采样与重构方法。根据周期非均匀采样的系统模型,基于联合子空间理论将采样与重构过程转换为矩阵向量运算;再借助正交匹配追踪算法确定采样数据矩阵中非零元素的位置,并分析了该算法在周期非均匀采样系统中的完整重构条件,通过插值器实现信号完整重构。最后,以多带正弦信号为例验证了可完整重构概率,系统实验证明:对于稀疏信号的采样与重构,该方法满足完整重构条件。     

浅谈DMAIC阶段质量工具在过程改进中的应用

运用DMAIC各个阶段使用的质量工具,在过程改进中,对改进项目采用DMAIC部分工具测量系统分析、正态性检验、过程能力分析、鱼果图、因果矩阵分析,回归分析、方差分析、DOE,结合MINITABLE统计软件的应用,较快地找到改进的最佳运行参数并实施控制,最终达到了降低产品成本、使顾客满意的目的。该项目的成功推广,提高了公司技术人员运用先进质量工具分析问题、解决问题的能力。     

As-cast microstructure and solidification behavior of a high Al- and Nb-containing superalloy

This study investigated the as-cast microstructure and solidification behavior of a high Al- and Nb-containing low thermal expansion IN783 alloy. By analyzing the as-cast microstructure, the quenched microstructure after soaking at high temperature and differential scanning calorimeter (DSC) results, the solidification sequence of IN783 alloy was determined as follows: L → L + γ → L + γ + β → γ + β + Laves. Segregation of Al and Nb promoted the formation of Al-enriched β phase and Nb-enriched Laves phase, respectively. Several types of β and Laves phase were observed, which were believed to form by different mechanisms and at different stages during solidification.     

高分子量二元丙烯腈聚合物的合成及性能

设计合成了双功能共聚单体3-酰胺基-3-丁烯酸甲酯(MMPA),以二元共聚合代替传统的三元共聚合,采用水相悬浮聚合的方法制备超高分子量丙烯腈二元共聚物作为碳纤维前驱体。采用傅里叶红外变换光谱仪、差示扫描量热分析仪和热失重分析仪详细研究了单体配比对聚合物相对分子质量、结构及预氧化性能的影响,结果表明,共聚单体MMPA的加入使预氧化温度由240℃降低至213℃,且投料中随着MMPA含量的增加预氧化温度降低,预氧化程度加深,合成的共聚单体MMPA能够有效改善丙烯腈聚合物的预氧化性能,宽化放热峰,避免放热集中;水相悬浮制备得到的丙烯腈聚合物相对分子质量高达106.7×10~4,有利于提高碳纤维的力学性能。     

In situ Raman spectroscopy of topological insulator Bi2Te3 films with varying thickness

Topological insulators （TIs） are a new state of quantum matter with a band gap in bulk and conducting surface states. In this work, the Raman spectra of topological insulator Bi2Te3 films prepared by molecular beam epitaxy （MBE） have been measured by an in situ ultrahigh vacuum （UHV）-MBE-Raman spectroscopy system. When the thickness of Bi2Te3 films decreases from 40 quintuple-layers （QL） to 1 QL, the spectral characteristics of some Raman modes appearing in bulk Bi2Te3 vary and a new vibrational mode appears, which has not been reported in previous studies and might be related to quantum size effects and symmetry breaking. In addition, an obvious change was observed at 3 QL when a Dirac cone formed. These results offer some new information about the novel quantum states of TIs.     

Joule Heating Activation of Template-Mediated Carbon Fibers with Significantly Enhanced Capacitive Performance

Carbon fibers (CFs) have been innovated in the application of fiber-shaped and wearable energy storage devices recently. However, time- and energy-consuming activation process under harsh conditions is generally required to modify the surface structure of the CF. Herein, a fast and effective Joule heating activation method is proposed with the nickel–cobalt layered double hydroxide-derived nanometal particles as the template. The resultant Joule heating-activated CF (JACF) demonstrates excellent capacitive performance with an electrode capacitance of 268 F g⁻¹. After assembling into a solid-state fiber-shaped supercapacitor (FSC), the device shows both enhanced specific capacitance and energy/power densities, as well as the long cycling stability of over 5000 cycles. The Joule heating method reported in this work is time and energy saving for CF activation compared with the traditional chemical etching or high-temperature annealing processes, and it is promising for the large-scale production of high-performance fiber-shaped and wearable energy devices.     

可见光诱导TiO2光催化及其机理研究进展

简述了二氧化钛的光催化机理。针对其禁带宽度较大,只能被小于387nm的紫外光所激发的缺点,综述了近年来国内外针对纳米TiO2可见光催化的改性方法和改性机理研究进展,包括离子掺杂、半导体复合、表面光敏化等方法。最后展望了提高纳米TiO2可见光光催化活性研究的前景。     

Intermolecular and intramolecular quencher based quantum dot nanoprobes for multiplexed detection of endonuclease activity and inhibition

DNA cleavage by endonucleases plays an important role in many biological events such as DNA replication, recombination, and repair and is used as a powerful tool in medicinal chemistry. However, conventional methods for assaying endonuclease activity and inhibition by gel electrophoresis and chromatography techniques are time-consuming, laborious, not sensitive, or costly. Herein, we combine the high specificity of DNA cleavage reactions with the benefits of quantum dots (QDs) and ultrahigh quenching abilities of inter- and intramolecular quenchers to develop highly sensitive and specific nanoprobes for multiplexed detection of endonucleases. The nanoprobe was prepared by conjugating two sets of DNA substrates carrying quenchers onto the surface of aminated QDs through direct assembly and DNA hybridization. With this new design, the background fluorescence was significantly suppressed by introducing inter- and intramolecular quenchers. When these nanoprobes are exposed to the targeted endonucleases, specific DNA cleavages occur and pieces of DNA fragments are released from the QD surface along with the quenchers, resulting in fluorescence recovery. The endonuclease activity was quantified by monitoring the change in the fluorescence intensity. The detection was accomplished with a single excitation light. Multiplexed detection was demonstrated by simultaneously assaying EcoRI and BamHI (as model analytes) using two different emissions of QDs. The limits of detection were 4.0 × 10(-4) U/mL for EcoRI and 8.0 × 10(-4) U/mL for BamHI, which were at least 100 times more sensitive than traditional gel electrophoresis and chromatography assays. Moreover, the potential application of the proposed method for screening endonuclease inhibitors has also been demonstrated. The assay protocol presented here proved to be simple, sensitive, effective, and easy to carry out.