Development of a thin film technique for an amorphous metallic ribbon/thermoplastic matrix composite system

A thin film method is developed for the fabrication of an amorphous metallic ribbon/PP (polypropylene) matrix composite system. The interfacial shear strength of composites fabricated with thin film is 0.52 ± 0.09 MPa (process B), which is comparable to that of the sandwich method of composite fabrication reported recently. The optical micrographs of the interfacial zone appear to be defect free and there are no visible voids, cracks, or air entrapment during fabrication. This qualitative analysis of the ribbon/matrix interface suggests that thin film can provide a better interfacial bond, a result which is supported by the results of pullouts tests. The composite fabrication time using the thin film method is short, and this method therefore has the potential to produce composites at a high volume fraction of ribbon reinforcements as compared to the sandwich method.     

Gelatinization of Starch During Preparation of Indian Unleaved Flat Breads

The comparison of starch granule deformation and extent of starch gelatinization in a few common Indian unleavened flat breads (Chapati, Parontha and Poorie) was made. The starch granule swelling was evaluated by scanning electron as well as polarized light microscopy. The peak viscosity in Haake rotary viscosimeter and hydration capacity were used for comparing the extent of starch gelatinization in crust and crumb of these baked products. Although a few of the starch granules on the outside of crust, maintained a weak outline those in the crumb area gave only a matrix of gelatinized starch. The extent of starch gelatinization was reflected by the related increase in hydration capacity of these products. However, the peak viscosity values were found to be inversely related to the extent of starch gelatinization. As compared to crumb, a higher extent of browning was observed in the crust. Water absorption, type of cereal, mode and efficiency of heat transfer were found to control the extent of starch gelatinization in these baked products.     

Metabolic profile biomarkers of metal contamination in a sentinel terrestrial species are applicable across multiple sites

In this study, we addressed the question of whether an omic approach could genuinely be useful for biomarker profile analysis across different field sites with different physicochemical characteristics. We collected earthworms (Lumbricus rubellus) from seven sites with very different levels of metal contamination and prevailing soil type and analyzed tissue extracts by 1H nuclear magnetic resonance spectroscopy. Pattern recognition analysis of the data showed that both site- and contaminant-specific effects on the metabolic profiles could be discerned. Zinc was identified as the probable major contaminant causing a metabolic change in the earthworms. Individual sites could be resolved on the basis of NMR spectral profiles by principal component analysis; these site differences may also have been caused by additional abiotic factors such as soil pH. Despite an inevitable degree of confounding between site and contaminant concentrations, it was possible to identify metabolites which were correlated with zinc across all different sites. This study therefore acts as a proof of principle for the use of NMR-based metabolic profiling as a diagnostic tool for ecotoxicological research in polluted field soils.     

Volatile aldehyde emissions from heated cooking oils

Low molecular weight aldehydes (LMWAs) formed during the heating of frying media (triglycerides) were adsorbed onto tenax and analyzed by GC‐MS after thermal desorption. Six alkanals (C₅ to C₁₀), seven 2‐alkenals (C₅ to C₁₁) and 3 alkadienals (C₇, C₉ and C₁₀) were found in the fumes of canola oil (control), extra virgin olive oil, and refined olive oil, heated at 180 and 240 °C. The emission rates of these aldehydes depended on the heating temperature. Frying in any type of olive oil, independently of its commercial category, will effectively decrease the emission of volatile aldehydes at temperatures below the smoking point. Thus, using the cheaper olive oil for deep‐frying purposes will not affect aldehyde emissions. This is important since olive oil is usually used for deep‐frying operations while extra virgin olive oil is used as salad dressing in Spain. The mixture of refined olive oil with some virgin olive oil is the most acceptable type of olive oil in non‐Mediterranean countries due to its milder flavor. However, if higher temperatures are needed the use of canola oil is more advisable due to its higher smoke point. Copyright © 2004 Society of Chemical Industry     

Amylograph Pasting Behaviour of Cereal and Tuber Starches

The pasting characteristics in terms of peak viscosity (P), hot paste viscosity (H), cold paste viscosity (C) and at the selected fixed peak viscosities, the various ratios i.e., breakdown (H/P), setback (C/P), total setback (C/H) and relative breakdown, BD_r, (P-H)/(C-H) to distinguish the starches from different species, are reported. Important differences in these characteristics among various starches have been observed. The amount of soluble amylose present in a starch, significantly affected its tendency for retrogradation. The breakdown (H/P), setback (C/P), total setback (C/H) ratios and especially the relative breakdown (BD_r) can be made use of in distinguishing the starches from different species of wheat.     

The performance of SAS-super-180 air sampler and settle plates for assessing viable fungal particles in the air of dry-cured meat production facility

Performances of SAS-super-180 air sampler and settle plates were investigated for the assessment of airborne fungal food contamination. Air samples were taken from processing rooms of a dry-cured production facility and outdoors. Fungal colonies and numbers of species were counted and compared. Quantitatively, the air sampler showed higher numbers of species and mean CFU/plate compared to settle plates. Qualitatively, the two methods showed similar dominating fungal genera and species associated with dry-cured meat products. The study showed settle plates could provide important qualitative information for food processing plants where airborne fungi associated with food products are the targets.     

Determination of volume fraction of bainite in low carbon steels using artificial neural networks

Artificial neural networks have been used to estimate the volume fraction of bainite in low carbon steels containing various alloying elements. The network predicts the volume fraction for a given composition, isothermal transformation temperature and isothermal transformation time. Additionally, the maximum transformation temperature at which bainite formation takes place is also provided as an input to the neural network. The network was trained using the experimental data from three low carbon steels and it was found to perform quite well in predicting the volume fraction of bainite. The impact of the composition of alloying elements on the volume fraction of bainite was also studied and the results were in agreement with the known metallurgical theory.     

Evaluation of the behavior of shrouded plasma spray coatings in the platen superheater of coal-fired boilers

Nickel- and cobalt-based coatings were formulated by a shrouded plasma spray process on boiler tube steels, namely, ASTM-SA210-grade A1 (GrA1), ASTM-SA213-T-11 (T11), and ASTM-SA213-T-22 (T22). The Ni-22Cr-10Al-1Y alloy powder was sprayed as a bond in each case before the final coating. The degradation behavior of the bared and coated steels was studied in the platen superheater of the coal-fired boiler. The samples were inserted through the soot blower dummy points with the help of stainless steel wires. The coatings were found to be effective in increasing resistance to degradation in the given boiler environment. The maximum protection was observed in the case of Stellite-6 (St-6) coating.     

GaAsSb: a novel material for near infrared photodetectors on GaAs substrates

We have studied the molecular beam epitaxy (MBE) growth of GaAsSb on GaAs substrates. The optical properties and composition of GaAsSb layer strongly depend on the growth temperature, the Ga growth rate, and the As and Sb fluxes and their ratios. We also report on two GaAsSb-GaAs photodiode structures operating at 1.3 /spl mu/m. The peak quantum efficiency was 54% for the GaAsSb resonant-cavity-enhanced (RCE) p-i-n photodiode and 36% for the RCE GaAsSb avalanche photodiode (APD) with separate absorption, charge, and multiplication regions (SACM). At 90% of the breakdown, the dark current of the SACM APD was 5 nA. The GaAsSb SACM APD also exhibited very low multiplication noise and k/sub eff/ was approximately 0.1, which is the lowest ever reported for APDs operating at 1.3 /spl mu/m.     

Study of Molten Salt Corrosion of High Velocity Oxy-Fuel Sprayed Cermet and Nickel-Based Coatings at 900 °C

Absract Samples of Cr₃C₂-NiCr cermet and NiCrBSi coatings formed by the high velocity oxy-fuel (HVOF) process on Superni 718 superalloy have been corroded in the Na₂SO₄-V₂O₅ molten salt environment at 900 °C under cyclic conditions. The hot corrosion behavior of the coatings has been investigated by means of thermogravimetric analysis, X-ray diffraction, scanning electron microscopy/energy dispersive spectroscopy, and electron probe microanalyzer techniques. Efforts have been made to formulate the mode of corrosion attack. Both the coatings protected the substrate superalloy Superni 718 completely. While protecting the superalloy, the Cr₃C₂-NiCr cermet coating partially oxidized along the splat boundaries up to the coating substrate interface, whereas only the upper part of the coating, to about 100 μm from the surface, oxidized in the case of the NiCrBSi coating. The hot corrosion resistance of both the coatings has been attributed to the formation of protective oxides of chromium/silicon at the surface and at the splat boundaries of the coatings.