Isolation of Solid Solution Phases in Size‐Controlled LixFePO4 at Room Temperature

State‐of‐the‐art LiFePO₄ technology has now opened the door for lithium ion batteries to take their place in large‐scale applications such as plug‐in hybrid vehicles. A high level of safety, significant cost reduction, and huge power generation are on the verge of being guaranteed for the most advanced energy storage system. The room‐temperature phase diagram is essential to understand the facile electrode reaction of Li_xFePO₄ (0 < x < 1), but it has not been fully understood. Here, intermediate solid solution phases close to x = 0 and x = 1 have been isolated at room temperature. Size‐dependent modification of the phase diagram, as well as the systematic variation of lattice parameters inside the solid‐solution compositional domain closely related to the electrochemical redox potential, are demonstrated. These experimental results reveal that the excess capacity that has been observed above and below the two‐phase equilibrium potential is largely due to the bulk solid solution, and thus support the size‐dependent miscibility gap model.     

A fabrication technique for a UO2 pellet consisting of UO2 grains and a continuous W channel on the grain boundary

A new fabrication process of UO₂-W composite fuel has been studied in order to improve the thermal conductivity of the UO₂ pellet by the addition of a small amount of W. A fabrication process was designed from the phase equilibria among tungsten, tungsten oxides and UO₂. The conventionally sintered UO₂ pellet which contains W particles is heat-treated in an oxidizing gas and then in a reducing gas. In the oxidizing heat-treatment W particles are oxidized and liquid tungsten oxide penetrates within the UO₂ grain boundary, and in the reducing heat-treatment liquid oxide is transformed to solid tungsten which forms a continuous channel along the UO₂ grain boundary. This developed technique can provide a continuous W channel covering UO₂ grains for a UO₂-W composite fuel even with a small amount of a metal phase - below 6 vol.%. The thermal diffusivity of the UO₂-6 vol.%W cermet composite increases by about 80% when compared with that of a pure UO₂ pellet.     

Address pulses during sustain period for increasing luminous efficiency

Abstract— A new driving method using a short pulse applied to the address electrode (i.e., address pulse) during a sustain period is proposed to improve the luminous efficiency. In this method, short pulses are additionally applied to the address electrode during the rising or falling edge of the sustain pulses. In the case of a small sustain gap, address pulses synchronized with a rising edge of the sustain pulse can help the expansion of the discharge volume toward the address electrode, whereas address pulses synchronized with a falling edge of the sustain pulse produce a self‐erasing discharge, which improves the luminous efficiency. In the case of a large sustain gap, the application of the address pulse can produce a stable sustain discharge at a low sustain voltage level, generating an efficient discharge even in the case of the long discharge path.     

Molecular dynamics study on external field induced crystallization of amorphous argon structure

A molecular dynamics study has been conducted on an external-force-field-induced isothermal crystallization process of amorphous structures as a new low-temperature athermal crystallization process. An external cyclic-force field with a dc bias is imposed on molecules selected randomly in an amorphous-phase of argon. Multiple peaks smoothed out in the radial distribution functions for amorphous states appear very clearly during the crystallization process that cannot be achieved otherwise. When the amorphous material is locally exposed to an external force field, crystallization starts and propagates from the interfacial region and crystallization growth rates can be estimated.     

Oral absorption and pharmacokinetics of rebamipide and rebamipide lysinate in rats

Rebamipide is an anti-ulcer agent exhibiting a low aqueous solubility and a poor oral bioavailability. This study was conducted to examine if the rebamipide lysinate salt form would exhibit improved solubility profiles and higher oral bioavailability compared with rebamipide free acid. Both compounds showed pH-dependent solubility profiles, with the solubility of rebamipide lysinate dramatically improved at a median pH of 5.1 (17-fold increases) over free acid, but the improvement in the solubility was not as pronounced in artificial gastric and intestinal fluids (1.4- and 1.9-fold increases, respectively). The Cl, V_ss and t_1/2 in rats after i.v. injection of rebamipide (0.5 mg/kg) averaged 21.0 ± 3.2 ml/min/kg, 0.3 ± 0.0 L/kg, and 0.4 ± 0.1 hr, respectively. No significant difference was observed in these parameters between rebamipide and rebamipide lysinate. Despite improved solubility profiles, the absolute oral bioavailability of rebamipide lysinate was not increased (5.1 vs. 4.8%) nor did AUC (407.8 vs. 383.6 ng^.hr/ml) and C_max (87.4 vs.77.0 ng/ml) compared with rebamipide free acid. Rebamipide lysinate, however, showed a more rapid absorption, and initial serum drug concentrations were higher than those found for rebamipide free acid.     

Crystal structure of (Ba1−x Lax) [Mg(1 + x)/3Nb(2−x)/3]O3 ceramics

The crystal structure of (Ba_1–x La _x )[Mg_{(1 + x)/3}Nb_(2–x)/3]O₃ (BLMN) ceramics with 0 x 1 was investigated using X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). When the La content, x, was above 0.1, the 1:2 ordered hexagonal structure found in Ba(Mg_1/3Nb_2/3)O₃ (BMN) was transformed into the 1:1 ordered cubic structure. The 1:1 ordered cubic structure was maintained up to x = 0.7. When x exceeded 0.7, however, BLMN exhibited a 1:1 ordered monoclinic structure, rather than a 1:1 ordered cubic structure. La(Mg_2/3Nb_1/3)O₃ (LMN) has a 1:1 ordered monoclinic P2₁/n structure with a = 5.6004 Å, b = 5.6414 Å, c = 7.9346 Å, and = 89.9819°. The monoclinic LMN has the in-phase and the anti-phase tilt of oxygen octahedra. The anti-parallel shift of A-site cations was also found in LMN.     

On pseudo-fuzzy linear mappings

In this paper we study a more general class of linear maps on fuzzy subsets of vector spaces than those on fuzzy subspaces. We obtain a version of the fundamental theorem of homomorphisms which applies to these pseudo-fuzzy linear maps. In the case of fuzzy subspaces, the results become those for fuzzy linear maps. We introduce the notion of magnification of pseudo-fuzzy linear mappings. It is shown that this notion behaves well with respect to the fundamental theorem and with respect to the composition of mapping. We note that the class of distribution functions of random variables naturally produces pseudo-fuzzy linear mappings, which are not fuzzy linear mappings. We observe that pseudo-fuzzy linear mappings are examples of gain relations. We consider general properties of these relations as well as many other examples. From these results additional properties of pseudo-fuzzy linear mappings are obtained.     

A Temperature‐Controllable Microelectrode and Its Application to Protein Immobilization

This letter presents a smart integrated microfluidic device which can be applied to actively immobilize proteins on demand. The active component in the device is a temperature‐controllable microelectrode array with a smart polymer film, poly(N‐isopropylacrylamide) (PNIPAAm) which can be thermally switched between hydrophilic and hydrophobic states. It is integrated into a micro hot diaphragm having an integrated micro heater and temperature sensors on a 2‐micrometer‐thick silicon oxide/silicon nitride/silicon oxide (O/N/O) template. Only 36 mW is required to heat the large template area of 2 mm×16 mm to 40°C within 1 second. To relay the stimulus‐response activity to the microelectrode surface, the interface is modified with a smart polymer. For a model biomolecular affinity test, an anti‐6‐(2, 4‐dinitrophenyl) aminohexanoic acid (DNP) antibody protein immobilization on the microelectrodes is demonstrated by fluorescence patterns.     

Design of a Haptic Interface for a Gastrointestinal Endoscopy Simulation

This paper presents a new design and analysis of a haptic interface for a gastrointestinal endoscopy simulation. The gastrointestinal endoscopy is a procedure in which the digestive tract and organs of a patient are diagnosed and treated using a long and flexible endoscope. The developed haptic interface incorporates two degrees of freedom (DOF), each of which is necessary to describe the movements of an endoscope during the actual endoscopy procedures. The haptic interface has a translational motion mechanism to implement the insertion movement of the endoscope, and a rotational motion mechanism to implement the rotational movement of the endoscope. The endoscope included in the haptic interface is supported by a folding guide to prevent the endoscope from buckling. Force feedback in each direction is provided by wire-driven mechanisms. The developed haptic interface has a workspace, sensitivity, and maximum attainable force and torque enough to simulate the endoscopy procedures such as colonoscopy, upper GI (gastrointestinal) endoscopy, and endoscopic retrograde cholangiopancreatography (ERCP). The developed haptic interface is applied to implementation of a colonoscopy simulation. Performance including force bandwidth is evaluated through experiments and simulation.     

Design of an auto-focusing actuator with a flexure-based compliant mechanism for mobile imaging devices

There is increasing consumer’s demand for high-quality and high-performance mobile imaging devices. In this paper, an auto-focusing (AF) actuator with a flexure hinge that uses the electromagnetic (EM) circuit of a voice coil motor was designed and evaluated. The flexure hinge was designed by using finite element analysis. The EM circuit was designed based on the structural stiffness of the device. The EM circuit was analyzed using the design of experiments procedure. Based on the results, the effective design parameters were selected, and improvements were made to the design. Finally, a prototype of the AF actuator was manufactured, and the feasibility and performance of the actuator with the flexure hinge were verified experimentally. The experimental results indicated that the proposed actuator performed adequately and satisfied the design requirements.