A Systematic Approach to Achieving High Performance Hybrid Lighting Phosphors with Excellent Thermal‐ and Photostability

The authors have designed and synthesized a family of high‐performance inorganic–organic hybrid phosphor materials composed of extended and robust networks of one, two, and three dimensions. Following a bottom‐up solution‐based synthetic approach, these structures are constructed by connecting highly emissive Cu₄I₄ cubic clusters via carefully selected ligands that form strong Cu? N bonds. They emit intensive yellow‐orange light with high luminescence quantum efficiency, coupled with large Stokes shift, which greatly reduces self‐absorption. They also demonstrate exceptionally high framework‐ and photostability, comparable to those of commercial phosphors. The high stabilities are the result of significantly enhanced Cu? N bonds, as confirmed by the density functional theory (DFT) binding energy and electron density calculations. Possible emission mechanisms are analyzed based on the results of theoretical calculations and optical experiments. Two‐component white phosphors obtained by blending blue and yellow emitters reach an internal quantum yield as high as 82% and correlated color temperature as low as 2534 K. The performance level of this subfamily exceeds all other types of Cu–I based hybrid systems. The combined advantages make them excellent candidates as alternative rare‐earth element‐free phosphors for possible use in energy‐efficient lighting devices.     

On the optimum design of unitary cyclic group space-time codes

In this letter, based on the exact pairwise-error probability, we derive the union bound on the symbol-error probability (SEP) of the differential unitary space-time (DUST) modulation employing group codes. Instead of using the rank-and-determinant or Euclidean distance criteria, we optimize the cyclic group codes such that the union bound on the SEP is minimized for a predetermined scenario, taking into account the number of transmit and receive antennas and the operating signal-to-noise ratio (SNR). Our simulation results show that for a wide range of SNRs, the codes with the minimum union bound for a particular SNR outperform the codes designed based on rank-and-determinant or Euclidean distance criteria.     

Microwave active resonator band-pass filters in various mmic technologies

In this article, two topologies of L-C parallel active resonators are presented. These circuits are realized in MMIC technology, using three transistors which could be MESFET, hemt or HBT. The survey of these resonators shows the possibility, by controling the values of a resistor and/or a capacitor, on the one hand, to tune the resonance frequency of these circuits, and on the other hand, to cancel out their losses so as to obtain negative conductance. Compact, lossless and narrow-band filters are then implemented using previous active resonators. To date, the use of mesfet technology has reduced the synthesis of such active filters in S-band and at X-band low frequencies. Now, however, hemt and HBT technologies allow the extension of their implementation to the whole X-band. This survey is illustrated by the simulated response of a 10 GHz filter with a 500 MHz 3 dB bandwidth. The mmic technology is a 0.2 μm hemt one. The simulated performances of this filter achieve a mean transmission gain of 0. 5 dB, with a reflection loss higher than 10 dB at 10 GHz,     

Ligand‐Free Synthesis of Aluminum‐Doped Zinc Oxide Nanocrystals and their Use as Optical Spacers in Color‐Tuned Highly Efficient Organic Solar Cells

The color of polymer solar cells using an opaque electrode is given by the reflected light, which depends on the composition and thickness of each layer of the device. Metal‐oxide‐based optical spacers are intensively studied in polymer solar cells aiming to optimize the light absorption. However, the low conductivity of materials such as ZnO and TiO₂ limits the thickness of such optical spacers to tenths of nanometers. A novel synthesis route of cluster‐free Al‐doped ZnO (AZO) nanocrystals (NCs) is presented for solution processing of highly conductive layers without the need of temperature annealing, including thick optical spacers on top of polymer blends. The processing of 80 nm thick optical spacers based on AZO nanocrystal solutions on top of 200 nm thick polymer blend layer is demonstrated leading to improved photocurrent density of 17% compared to solar cells using standard active layers of 90 nm in combination with thin ZnO‐based optical spacers. These AZO NCs also open new opportunities for the processing of high‐efficiency color tuned solar cells. For the first time, it is shown that applying solution‐processed thick optical spacer with polymer blends of different thicknesses can process solar cells of similar efficiency over 7% but of different colors.     

Reduced Surfactant Uptake in Three Dimensional Assemblies of VOx Nanotubes Improves Reversible Li+ Intercalation and Charge Capacity

The relationship between the nanoscale structure of vanadium pentoxide nanotubes and their ability to accommodate Li⁺ during intercalation/deintercalation is explored. The nanotubes are synthesized using two different precursors through a surfactant‐assisted templating method, resulting in standalone VO _x (vanadium oxide) nanotubes and also “nano‐urchin”. Under highly reducing conditions, where the interlaminar uptake of primary alkylamines is maximized, standalone nanotubes exhibit near‐perfect scrolled layers and long‐range structural order even at the molecular level. Under less reducing conditions, the degree of amine uptake is reduced due to a lower density of V⁴⁺ sites and less V₂O₅ is functionalized with adsorbed alkylammonium cations. This is typical of the nano‐urchin structure. High‐resolution TEM studies revealed the unique observation of nanometer‐scale nanocrystals of pristine unreacted V₂O₅ throughout the length of the nanotubes in the nano‐urchin. Electrochemical intercalation studies revealed that the very well ordered xerogel‐based nanotubes exhibit similar specific capacities (235 mA h g^?1) to Na⁺‐exchange nanorolls of VO_x (200 mA h g^?1). By comparison, the theoretical maximum value is reported to be 240 mA h g^?1. The VOTPP‐based nanotubes of the nano‐urchin 3D assemblies, however, exhibit useful charge capacities exceeding 437 mA h g^?1, which is a considerable advance for VO_x based nanomaterials and one of the highest known capacities for Li⁺ intercalated laminar vanadates.     

MIMO Channel Capacity and Configuration Selection for Switched Parasitic Antennas

Multiple-input multiple-output (MIMO) systems offer significant enhancements in terms of their data rate and channel capacity compared to traditional systems. However, correlation degrades the system performance and imposes practical limits on the number of antennas that can be incorporated into portable wireless devices. The use of switched parasitic antennas (SPAs) is a possible solution, especially where it is difficult to obtain sufficient signal decorrelation by conventional means. The covariance matrix represents the correlation present in the propagation channel, and has significant impact on the MIMO channel capacity. The results of this work demonstrate a significant improvement in the MIMO channel capacity by using SPA with the knowledge of the covariance matrix for all pattern configurations. By employing the “water-pouring algorithm” to modify the covariance matrix, the channel capacity is significantly improved compared to traditional systems, which spread transmit power uniformly across all the antennas. A condition number is also proposed as a selection metric to select the optimal pattern configuration for MIMO-SPAs.     

当道路难行时,尽快转向无带方向——Sony XDCAM HD高清系统全程支持2006陆虎G4越野挑战赛

陆虎（Land Rover）G4越野挑战赛．是各大汽车公司彼此互相交流的重大活动。经过三年多的精心准备．2006年G4挑战赛正式拉开了帷幕——一个月时间，18组挑战者．4000公里行程．跨越泰国、老挝、巴西和波利维亚。本届赛事是2003年G4挑战赛的延续．它的前身就是2000年结束的“骆驼杯”越野挑战赛。     

Reconstruction and quantification of the carotid artery bifurcation from 3-D ultrasound images

Three-dimensional (3-D) ultrasound is a relatively new technique, which is well suited to imaging superficial blood vessels, and potentially provides a useful, noninvasive method for generating anatomically realistic 3-D models of the peripheral vasculature. Such models are essential for accurate simulation of blood flow using computational fluid dynamics (CFD), but may also be used to quantify atherosclerotic plaque more comprehensively than routine clinical methods. In this paper, we present a spline-based method for reconstructing the normal and diseased carotid artery bifurcation from images acquired using a freehand 3-D ultrasound system. The vessel wall (intima-media interface) and lumen surfaces are represented by a geometric model defined using smoothing splines. Using this coupled wall-lumen model, we demonstrate how plaque may be analyzed automatically to provide a comprehensive set of quantitative measures of size and shape, including established clinical measures, such as degree of (diameter) stenosis. The geometric accuracy of 3-D ultrasound reconstruction is assessed using pulsatile phantoms of the carotid bifurcation, and we conclude by demonstrating the in vivo application of the algorithms outlined to 3-D ultrasound scans from a series of patient carotid arteries.     

Fabrication of gold micro-spine structures for improvement of cell/device adhesion

Improvement of the interface contact between biological objects and electronic devices can significantly enhance the quality of electronic signal transfer. The surface of biosensor can be artificially modified in order to strengthen the adhesion of biological cells. We report on results of fabrication of micron and submicron golden spines by means of e-beam lithography and electroplating. The fabrication technique allows easy modification of the size and shape of golden spines by variation of processing parameters. The structures with different spine profiles and spacing have been fabricated for optimization of cell growth conditions. We present the results of growth of rat cortical neurons on the surface of spine modified samples. Well-defined cell guidance was established at the spine arrays. Furthermore, the results of transmission electron microscope and focused ion beam technique confirm the good adhesion between the spines and cell structures.     

Operator dependence of 3-D ultrasound-based computational fluid dynamics for the carotid bifurcation

The association between vascular wall shear stress (WSS) and the local development of atherosclerotic plaque makes estimation of in vivo WSS of considerable interest. Three-dimensional ultrasound (3DUS) combined with computational fluid dynamics (CFD) provides a potentially valuable tool for acquiring subject-specific WSS, but the interoperator and intraoperator variability associated with WSS calculations using this method is not known. Here, the accuracy, reproducibility and operator dependence of 3DUS-based computational fluid dynamics were examined through a phantom and in vivo studies. A carotid phantom was scanned and reconstructed by two operators. In the in vivo study, four operators scanned a healthy subject a total of 11 times, and their scan data were processed by three individuals. The study showed that with some basic training, operators could acquire accurate carotid geometry for flow reconstructions. The variability of measured cross-sectional area and predicted shear stress was 8.17% and 0.193 N/m/sup 2/ respectively for the in vivo study. It was shown that the variability of the examined parameters was more dependent on the scan operators than the image processing operator. The range of variability of geometrical and flow parameters reported here can be used as a reference for future in vivo studies using the 3DUS-based CFD approach.