Direct observation of the stacked structure in substituted copper phthalocyanine LB films with STM

The in-plane molecular structures of octa-alkyl substituted copper phthalocyanine LB films deposited on graphite have been resolved with a scanning tunnelling microscope (STM). The face-to-face stacking of Pc macrocycles has been observed in the topographies of R₈PcCu monolayers. The stacking period was found to be 3.8–4 Å and the molecular rows were separated by 19 Å and 16 A for (C₆H₁₃)PcCu and (C₅H₁₁)PcCu respectively.     

Superconducting microwave filter systems for cellular telephone base stations

In the second decade following the discovery of high-temperature superconductivity (HTS), wireless communications has emerged as the earliest large commercial market. The enormous growth of the wireless industry coupled with its increasing technology demands has created a significant opportunity for HTS technology in wireless base stations. These systems combine high-performance HTS RF filters with cryocooled semiconductor preamplifiers to offer enhanced sensitivity to improve signal reception and exceptional selectivity to reject interfering signals. There are now thousands of installed HTS systems and the prospects are good for widespread future deployment. This paper discusses the underlying technologies that support HTS wireless applications, based upon the characteristic microwave properties of HTS thin films and substrates. HTS filter design technology has been under development for a decade and has gained a fair measure of maturity in terms of design tools, simulation techniques, and available topologies. The need for extremely narrow-band filters, highly selective filters, frequency-agile filters, and very compact filter designs has led to many technology advances. On the system level, comparable advances in cryocooler technology and cryopackaging have enabled the development of a broadly deployable technology. We discuss industry trends and the methodologies and results of simulations and real-world measurements of HTS filter systems.     

Drawing of optical fiber with internal codrawn wire and conductive coating and electrooptic modulation demonstration

One hundred twenty meters of fiber with an internal codrawn wire and electrically conductive coating was successfully fabricated for the first time. The integration of the conductive coating and wire was all performed during the fiber draw stage, in a process that enabled arbitrarily long lengths of fiber to be made. The wire combined with the conductive coating enables a strong electric field to be formed across the optical core. Such a fiber is ideal for thermally poling long lengths and for nonlinear device applications such as optical switches and modulators.     

High‐efficiency microcrystalline silicon single‐junction solar cells

This short communication highlights our latest results towards high‐efficiency microcrystalline silicon single‐junction solar cells. By combining adequate cell design with high‐quality material, a new world record efficiency was achieved for single‐junction microcrystalline silicon solar cell, with a conversion efficiency of 10.69%, independently confirmed at ISE CalLab PV Cells. Such significant conversion efficiency could be achieved with only 1.8 µm of Si. Copyright © 2013 John Wiley & Sons, Ltd.     

1.4-/spl mu/m InGaAsP-InP strained multiple-quantum-well laser for broad-wavelength tunability

InGaAsP-InP strained multiple-quantum-well (MQW) lasers for extended wavelength tunability in external cavity operation were designed, fabricated, and tested. The active layer was a strain compensated structure consisting of three 3.2/spl plusmn/0.3 nm and three 6.4/spl plusmn/0.3 nm 1.0% compressive strained wells and five 10.3/spl plusmn/0.3 nm 0.45% tensile strained barrier layers. A 2-/spl mu/m-wide ridge waveguide laser of length 250 /spl mu/m, when used in a grating external cavity and with no coatings to alter the reflectivity of the facets, was observed to operate over a range >110 nm. The lasers were designed for applications in trace gas and liquid detection with the goal to maximize the tunable range when operated in external cavities and with no facet coatings.     

Effects of a-Si:H resist vacuum-lithography processing on HgCdTe

A vacuum-compatible process for carrying out lithography on Hg_1−xCd_xTe and CdTe films was previously demonstrated. It was shown that hydrogenated amorphous silicon (a-Si:H) could be used as a dry resist by projecting a pattern onto its surface using excimer laser irradiation and then developing that pattern by hydrogen plasma etching. Pattern transfer to an underlying Hg_1−xCd_xTe film was then carried out via Ar/H₂ plasma etching in an electron cyclotron resonance (ECR) reactor. Despite the successful demonstration of pattern transfer, the possibility of inducing harmful effects in the Hg_1−xCd_xTe film due to this vacuum lithography procedure had not been explored. Here we present structural and surface compositional analyses of Hg_1−xCd_xTe films at key stages of the a-Si:H vacuum lithography procedure. X-ray diffraction double crystal rocking curves taken before and after a-Si:H deposition and after development etching were identical, indicating that bulk structural changes in the Hg_1−xCd_xTe film are not induced by these processes. Cross-section transmission electron microscopy studies show that laser-induced heating in the 350 nm thick a-Si:H overlayer is not sufficient to cause structural damage in the underlying Hg_1−xCd_xTe surface. In vacuo surface analysis via Auger electron spectroscopy and ion scattering spectroscopy suggest that the hydrogen plasma development process produces Hg-deficient surfaces but does not introduce C contamination. However, after ECR plasma etching into the Hg_1−xCd_xTe film, the measured x value is much closer to that of the bulk.     

Ionic Hydrogels with Biomimetic 4D‐Printed Mechanical Gradients: Models for Soft‐Bodied Aquatic Organisms

Direct‐ink writing (DIW), a rapidly growing and advancing form of additive manufacturing, provides capacities for on‐demand tailoring of materials to meet specific requirements for final designs. The penultimate challenge faced with the increasing demand of customization is to extend beyond modification of shape to create 4D structures, dynamic 3D structures that can respond to stimuli in the local environment. Patterning material gradients is foundational for assembly of 4D structures, however, there remains a general need for useful materials chemistries to generate gray scale gradients via DIW. Here, presented is a simple materials assembly paradigm using DIW to pattern ionotropic gradients in hydrogels. Using structures that architecturally mimic sea‐jelly organisms, the capabilities of spatial patterning are highlighted as exemplified by selectively programming the valency of the ion‐binding agents. Spatial gradients, when combined with geometry, allow for programming the flexibility and movement of iron oxide nanoparticle–loaded ionotropic hydrogels to generate 4D‐printed structures that actuate in the presence of local magnetic fields. This work highlights approaches to 4D design complexity that exploits 3D‐printed gray‐scale/gradient mechanics.     

Cyclic code weight spectra and BIST aliasing

In built-in self-test for logic circuits, test data reduction can be achieved using a linear feedback shift register. The probability that this data reduction will allow a faulty circuit to be declared good is the probability of aliasing. Based on the independent bit-error model, we show that the code spectra for the cyclic code generated by the feedback polynomial can be used to obtain an exact expression for the aliasing probability of a multiple input signature register when the test length is a multiple of the cycle length. Several cases are examined and, as expected, primitive feedback polynomials provide the best performance. Some suggestions to avoid peaks in the aliasing probability are given.     

Design and calibration of a high-frequency oscillatory ventilator

High-frequency ventilation (HFV) is a modality of mechanical ventilation which presents difficult technical demands to the clinical or laboratory investigator. The essential features of an ideal HFV system are described, including wide frequency range, control of tidal volume and mean airway pressure, minimal dead space, and high effective internal impedance. The design and performance of a high-frequency oscillatory ventilation system is described which approaches these requirements. The ventilator utilizes a linear motor regulated by a closed loop controller and driving a novel frictionless double-diaphragm piston pump. Finally, the ventilator performance is tested using the impedance model of Venegas [1].     

Chemical Amplification of a Triphenylene Molecular Electron Beam Resist

Molecular resists, such as triphenylene derivatives, are small carbon rich molecules, and thus give the potential for higher lithographic resolution and etch durability, and lower line width roughness than traditional polymeric compounds. Their main limitation to date has been poor sensitivity. A new triphenylene derivative molecular resist, with pendant epoxy groups to aid chemically amplified crosslinking, was synthesized and characterized. The sensitivity of the negative tone, pure triphenylene derivative when exposed to an electron beam with energy 20 keV was ～ 6 × 10^–4 C cm^–2, which increased substantially to ～ 1.5 × 10^–5 C cm^–2 after chemical amplification (CA) using a cationic photoinitiator. This was further improved, by the addition of a second triphenylene derivative, to ～ 7 × 10^–6 C cm^–2. The chemically amplified resist demonstrated a high etch durability comparable with the novolac resist SAL 601. Patterns with a minimum feature size of ～ 40 nm were realized in the resist with a 30 keV electron beam.