Disparities in exploitative and exploratory patenting performance across regions: Focusing on the roles of agglomeration externalities

We try to identify the determinants of regional variation in both exploitative and exploratory innovative competencies. Hereby, we focus on how a knowledge-creation mechanism with specialized externalities differs from one with diversified externalities. Innovative competence in the US is measured by local patenting performance; exploitative and exploratory patenting performances are distinguished by the degree of backward citation. Based on the extended knowledge-production function, including the two agglomeration externalities, our findings show that specialized externalities are associated with exploitation, while diversified externalities are positively related with both exploration and exploitation, regardless of industrial sectors.     

Measurement of zeta potential of macroscopic surfaces with Navier velocity slip exploiting electrokinetic flows in a microchannel

A method devised to measure the zeta potential of macroscopic surfaces with Navier velocity slip non-destructively exploiting electrokinetic flows in a microchannel. For an accurate as well as facile determination of zeta potential using this method, we need a simple relationship between zeta potential and streaming potential for electrokinetic flows in microchannels with consideration of the possibility of the Navier velocity slip. In the present investigation, we derive a semi-analytic formula for this relationship based on a one-dimensional modeling of electrokinetic flow in microchannels, which is as accurate as the numerical solution of the full governing partial differential equations. This formula is expected to allow accurate measurements of zeta potential of various macroscopic surfaces with Navier velocity slip.     

Conjoint analysis for luxury brand outlet malls in Korea with consideration of customer lifetime value

As Asian economies have grown rapidly, Asia has become a new leading market of the luxury goods industry. This paper used conjoint analysis (CA) for the optimal design of a luxury brand outlet mall to maximize the customer lifetime value (CLV). This approach complements a simple CA by considering CLV. The proposed approach is then applied to designing a suburban luxury brand outlet mall in Korea, a new concept to Korea. The results indicate that the optimal design for the outlet mall is the medieval European-style mall, with the linkage to Natural Tourism, which consists of the restaurants with delicious food and the stores with similar ratio between masstige and luxury brands.     

Intrinsic Kinetics of Chlorination of WO<Subscript>3</Subscript> Particles With Cl<Subscript>2</Subscript> Gas Between 973 K and 1223 K (700 °C and 950 °C)

Chlorination is one of the methods applied in extractive metallurgy for the treatment of minerals to obtain valuable metals, such as titanium and zirconium. The possibility of applying chlorination metallurgy to other metals such as tungsten was the major aim of this study. The kinetics of the chlorination of tungsten oxide (WO₃) particles has been investigated by thermogravimetry between 973 K and 1223 K (700 °C and 950 °C) and for partial pressures of chlorine ranging from 15 to 70 kPa. The starting temperature for the reaction of WO₃ with chlorine is determined to be about 920 K (647 °C). The influence of chlorine diffusion through the bulk gas phase and through the particle interstices in the overall rate was analyzed. In the absence of these two mass-transfer steps, a reaction order of 0.5 with respect to chlorine partial pressure, and an activation energy of 183 kJ/mol were determined. For tungsten oxide particles of less than 50-μm size, a complete rate expression has been obtained.     

Aircore mechanism during draining based on influence of pressure difference and drain port diameter

An understanding of the mechanism of aircore phenomenon during draining is very important. In this study, numerical simulations were conducted for different pressurized and suction pressure water tanks, as well as for different drain port diameters, to explain and validate the proposed aircore mechanism. It was found that increasing the pressure at the top surface of the tank results in suppression of the aircore, whereas an increase in the suction pressure at the drain port outlet enhances the development of the aircore. For different drain port diameters, it was observed that the duration of the aircore during draining decreases with a decrease in the drain port diameter, and that the aircore is suppressed for a very small drain port diameter.     

A study on the interfacial tension between solid iron and CaO–SiO<Subscript>2</Subscript>–MO system

Interfacial tension is an important property that plays an essential role in understanding wetting behavior between refractories–molten slag–steel in the steelmaking process. Most work on interfacial tensions of molten slag system have been done to clarify the effect of surface active elements in molten metal and slag composition, but there has been little work done with respect to the slags ionic structure. In this study, the interfacial tension between molten slag and solid Fe was investigated to understand the effect of the ionic structure of molten slag on interfacial tension by using solid Fe instead of molten steel. Interfacial tension measurements in CaO–SiO₂–FeO and CaO–SiO₂–MnO slags were carried out at 1,773 K on interstitial free (IF)-steel substrates using the sessile drop method. The composition of the slag was varied with amphoteric oxides of either FeO or MnO at unit basicity (C/S = 1.0). Results indicated a decrease in the interfacial tension with increased amphoteric oxide additions. The ionic species of molten slags were analyzed by FT-IR and the various types of oxygen ions (O²⁻, O⁻, O⁰⁾ in the slag was determined by X-ray photoelectron spectroscopy. The silicate bonding degree and the slags ionic behavior were semi-quantitatively analyzed with respect to the slag’s ionic structure model. By dissociating the slags networking structure with increased free oxygen ions, the interfacial tension decreased. Considering the ionic theory of molten slags, results indicate that the interfacial properties are directly affected by the ionic structure of the slag. This work hopes to clarify the relationship between the interfacial tension and the distribution of various oxygen ions.     

Optimal design for concrete pavement situated above box culvert: experimental and numerical study

This study examined the pavement distress data obtained from the field as well as the effects of the soil cover depth, joint position and reinforced slab length on the behaviour of concrete pavement using the finite element method. An ultimate strength model with a similarity of 1/2 was designed and constructed. Finite element analysis incorporating an implicit direct numerical integration scheme was conducted to obtain an optimal design for the pavement structure above a box culvert. An accelerated pavement test was conducted for validation, in which a realistic traffic load was imposed on the pavement model constructed in the laboratory. The strain histories were measured at each section and compared with those of numerical analysis. The optimal joint position and reinforced slab length that can minimise the damage to the pavement structure above a box culvert were also determined.     

Evaluation of lead exposure in workers at secondary lead smelters in South Korea: with focus on activity of erythrocyte pyrimidine 5'-nucleotidase (P5N)

To evaluate lead exposure among secondary lead-smelting workers with a focus on erythrocyte pyrimidine 5'-nucleotidase (P5N) activity, blood lead concentration (PbB), activity of P5N and other biological variables were examined in 88 exposed workers in five secondary lead smelters and in 24 non-exposed workers in Korea. All of the mean values of air lead concentration (PbA) in the three processes, scrap pretreatment, blast furnace smelting, and refining and casting of the secondary lead smelters, markedly exceeded 0.05 mg/m3. In this survey, 29 (97%) of 30 air samples for lead exceeded 0.05 mg/m3. The highest mean PbA and PbB values were found in the section of blast furnace smelting. All of the mean PbB values in all the sections were higher than 30 microg/dl. PbB of 71 (81%) of the 88 exposed workers exceeded 30 microg/dl. In 31 (35%) of the exposed workers, PbB was above 60 microg/dl. Compared with the non-exposed group, zinc protoporphyrin (ZPP) in the exposed group was significantly increased, whereas erythrocyte P5N activity and activity of erythrocyte delta-aminolevulinic acid dehydratase (ALAD) were significantly inhibited. Erythrocyte P5N activity had valid biological correlation with PbB and with other biological variables, such as ALAD activity or ZPP. Lead exposure affected hemoglobin levels via inhibition of P5N activity, as well as the heme biosynthetic pathway, in the high-exposure state.     

Diffusion studies in the β (B2), β′ (bcc), and γ (fcc) Fe-Ni-Al alloys at 1000 °C

Diffusion studies were carried out in the Fe-Ni-Al system at 1000 °C with solid-solid diffusion couples assembled with β (B₂), β′ (bcc), and γ (fcc) single-phase alloys for the development of diffusion structures, diffusion paths, and for the determination of interdiffusion and intrinsic diffusion coefficients. The diffusion structures were examined by optical and scanning electron microscopy, and the concentration profiles were determined by electron microprobe analysis. Diffusion couples included several series of β vs γ and β′ vs γ diffusion couples characterized by a common terminal alloy bonded to several terminal alloys with varying compositions. The development of planar and nonplanar interfaces, as well as two-phase layers, as observed in various couples, were related to the diffusion paths. The interdiffusion fluxes of individual components were calculated directly from the experimental concentration profiles, and the diffusional interactions among components were examined in the light of zero-flux planes (ZFPs) and flux reversals, which were identified in several couples. Ternary interdiffusion coefficients ( (i, j = Al, Ni)), with Fe considered as the dependent concentration variable, were evaluated at composition points of the intersection of diffusion paths of single-phase couples and of multiphase couples that developed planar interfaces. The interdiffusion coefficients were the largest in magnitude for the β′ alloys, especially near the β/β′ miscibility gap, and decreased for the β and γ alloys. In the β and γ phases, the main interdiffusion coefficient for Al was larger than those for Ni and Fe. Also, Fe interdiffused faster than Ni in the Fe-rich β and β′ phases. The cross-interdiffusion coefficients ( and ) were negative in all three phases. In general, the coefficients were larger in magnitude than the coefficients; however, the magnitude of was greater than that of near the β/(β + γ) phase boundary on the ternary isotherm. In the β phase, the magnitude of (i, j=Al, Ni) coefficients increased over 1 to 2 orders of magnitude with a decrease in the Al concentration and increase in the Fe/Ni concentration ratio. Interdiffusion coefficients, extrapolated from the ternary coefficients for binary alloys, were consistent with those in literature. Intrinsic diffusion coefficients were also determined at selected compositions. In addition, tracer diffusion coefficients were estimated for the binary Fe-Al and Ni-Al alloys at selected compositions, from an extrapolation of ternary interdiffusion coefficients.