Individual Particle Morphology and Acidity

The morphological characterization of particles during the Pittsburgh Air Quality Study (PAQS) suggests that particle shape and physical state depends on their acidity. The aerosol shape parameters measured by Computer-Controlled Scanning Electron Microscopy (CCSEM) are statistically different in periods when atmospheric particles are neutral and when they are acidic. High concentrations of particles smaller than 500 nm with high sulfur content and liquid appearance or signs of a previous liquid state before partial or total recrystallization are present on filters collected in days with high aerosol acidity. By contrast, in winter and summer periods in which the aerosol was neutral, the shape parameter values are similar and suggest that the particles have been dried out. These direct observations support the hypothesis that during summer acidic periods in the Eastern United States the particles may contain some water even at low relative humidity both in the atmosphere and on filters.     

Human-and-Humanoid Postures Under External Disturbances: Modeling,Simulation, and Robustness. Part 2: Simulation and Robustness

The sophisticated method for mathematical modeling of humanoid robots formulated in Part 1 of this paper is applied here to the dynamic task of keeping a posture under disturbance, which is equally important to humans and humanoid robots. The idea of this work is to develop and realize a simulator tool for dynamic analysis of human-or-humanoid behavior under disturbances. To show the potentials and verify this tool, we comparatively analyze the robustness of some postures to external disturbance. At this stage of research we do not conduct real experiments with humans/humanoids but try to verify our simulation tool by relying on available experience. Therefore, the postures for comparison are taken from everyday life and from sports: upright standing, squat posture, and three karate postures. As the external disturbance we choose an impulse and a permanent force, both with variable direction and magnitude.     

Neural Structures Using the Eigenstates of a Quantum Harmonic Oscillator

The main result of the paper is the use of orthogonal Hermite polynomials as the basis functions of feedforward neural networks. The proposed neural networks have some interesting properties: (i) the basis functions are invariant under the Fourier transform, subject only to a change of scale, (ii) the basis functions are the eigenstates of the quantum harmonic oscillator, and stem from the solution of Schrödinger's diffusion equation. The proposed feed-forward neural networks demonstrate the particle-wave nature of information and can be used in nonparametric estimation. Possible applications of the proposed neural networks include function approximation, image processing and system modelling.     

Occlusion Culling Algorithms: A Comprehensive Survey

In this paper, occlusion culling techniques that appeared in the last decade are reviewed. Occlusion culling techniques are responsible for reducing the polygons rendered by the graphics hardware with the target of achieving real-time rendering. The various techniques are discussed in detail and a synopsis table with their main characteristics is given.     

Nitrate reduction in a simulated free-water surface wetland system

The feasibility of using a constructed wetland for treatment of nitrate-contaminated groundwater resulting from the land application of biosolids was investigated for a site in the southeastern United States. Biosolids degradation led to the release of ammonia, which upon oxidation resulted in nitrate concentrations in the upper aquifer in the range of 65-400 mg N/L. A laboratory-scale system was constructed in support of a pilot-scale project to investigate the effect of temperature, hydraulic retention time (HRT) and nitrate and carbon loading on denitrification using soil and groundwater from the biosolids application site. The maximum specific reduction rates (MSRR), measured in batch assays conducted with an open to the atmosphere reactor at four initial nitrate concentrations from 70 to 400 mg N/L, showed that the nitrate reduction rate was not affected by the initial nitrate concentration. The MSRR values at 22 °C for nitrate and nitrite were 1.2 ± 0.2 and 0.7 ± 0.1 mg N/mg VSS_COD-day, respectively. MSRR values were also measured at 5, 10, 15 and 22 °C and the temperature coefficient for nitrate reduction was estimated at 1.13. Based on the performance of laboratory-scale continuous-flow reactors and model simulations, wetland performance can be maintained at high nitrogen removal efficiency (>90%) with an HRT of 3 days or higher and at temperature values as low as 5 °C, as long as there is sufficient biodegradable carbon available to achieve complete denitrification. The results of this study show that based on the climate in the southeastern United States, a constructed wetland can be used for the treatment of nitrate-contaminated groundwater to low, acceptable nitrate levels.     

Decolorization and toxicity of reactive anthraquinone textile dyes under methanogenic conditions

Reductive decolorization of two anthraquinone reactive dyes (Reactive Blue 4, RB4; Reactive Blue 19, RB19) under methanogenic conditions was performed using a mixed, methanogenic culture. Decolorization of the two anthraquinone dyes was investigated to evaluate the rate and extent of color removal as well as to assess possible toxic effects of the dyes and their decolorization product(s) on the methanogenic culture as a function of initial dye concentration ranging from 50 to 300 mg x L(-1). A dextrin/peptone mixture was used as the carbon and electron source. A high rate and extent of color removal was achieved ranging from 4.3 to 29.9 mg x L(-1)h(-1) and 73-91% for RB4, and 13.0-74.4 mg x L(-1)h(-1) and 90-95% for RB19. Initial RB4 concentrations up to 100 mg x L(-1) did not result in any significant inhibition. Both the 200 and 300 mg x L(-1) RB4-amended cultures, and all RB19-amended cultures resulted in severe inhibition of both acidogenesis and methanogenesis. Sequential dye addition at 300 mg x L(-1) for both RB4 and RB19 resulted in accumulation of volatile fatty acids (VFAs) and a very low methane production at the end of the first dye addition after 44 days of incubation. However, at the end of the second dye addition, after a relatively long incubation (384 days), recovery of methanogens in the RB4-amended culture was observed in contrast to the complete inhibition of methanogenesis in the RB19-amended culture. Therefore, RB19 resulted in a higher degree of inhibition of both acidogenesis and methanogenesis than RB4. Addition of dextrin/peptone to dye-inhibited cultures resulted in acidogenesis and a gradual recovery of methanogenesis (mainly aceticlastic methanogenesis) in the RB4-inhibited culture, and a slow recovery of acidogenesis but no recovery of methanogenesis in the RB19-inhibited culture. In contrast, addition of 80% H(2)-20% CO(2) gas to dye-inhibited cultures resulted in recovery of hydrogenotrophic methanogenesis in both the RB4- and RB19-inhibited cultures. In spite of the relatively severe inhibition of the two anthraquinone dyes on the mixed, methanogenic culture, a high extent of color removal was achieved.     

Estimation of daily traffic emissions in a South-European urban agglomeration during a workday. Evaluation of several "what if" scenarios

Detailed traffic data collected from seven major roads in the city of Athens, Greece are presented and analysed in this study. Vehicles are split into seven categories while vehicle speed is also recorded. Based on these data the emissions of five major pollutants (CO, Benzene, NO(X), PM(10) and VOCs) were calculated with the aid of the COPERT methodology and, based on these results, an Artificial Neural Network was also developed. The results of the two methodologies were compared and it was found that the differences were very small. The ANN model seems to be a reliable alternative to calculate road traffic emissions in a busy road environment. The results reflect the spatial and temporal distribution of the concentrations of the pollutants examined. Alternative "what if" scenarios of the fleet distribution were also applied by means of environmental policy. Since Athens experiences low air quality conditions the correct estimation of traffic emissions is crucial since they play a significant role in the design of an environmental abatement strategy.     

Mechanical behaviour and microstructure of heat-treated Cu–Ni–Si alloy

ABSTRACT

Cu–Ni–Si alloys exhibit a good combination of strength and electrical conductivity and may be a potential candidate for utilisation in electrotechnical applications. In this work, the mechanical behaviour and its relation to the microstructure of a Cu–Ni–Si alloy, subjected to different solution heat treatment cycles, were investigated. Tensile, bend and hardness testing, in addition to Optical and Scanning Electron Microscopy, were employed, as the main analytical techniques, in the context of the present investigation.

This paper is part of a Thematic Issue on Copper and its Alloys.