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91.
Appropriate financial incentives within construction project coalitions can contribute to effective project governance. However, the dearth of primary research material is partly attributed to the lack of a suitable methodology with which to study projects. Social network analysis (SNA) is proposed as an analytical tool to explore coalition governance. Primary data are presented for three European case studies employing quite different approaches to the use of financial incentives in project governance. The case studies investigate pain share/gain share arrangements implemented under a prime contracting procurement approach; an unusual use of activity-related penalties in the French system of procurement; and the use of guaranteed maximum price supplements within a UK standard form of (without contractor's design) building contract. The use of SNA enables the observation of a number of transaction sets and the formulation of a framework for the quantification of construction project governance. The first case study demonstrates the decentralization of client-orientated financial management, from consultant quantity surveyor to a number of multidisciplinary cluster leaders. The second case study illustrates the importance of incentive contiguity in effective project governance. The third case study uses SNA to demonstrate the way in which financial governance could be transformed through the transference of client-orientated financial management from the client and their professional adviser to the main contractor.

Les incitations financières appropriées, dans le cadre d'un fonds commun relatif à un projet de construction, peuvent contribuer à une gestion efficace du projet. Or, la pénurie de matériel de recherche primaire est attribuée, en partie, à l'absence d'une méthodologie appropriée permettant d'étudier de tels projets. Dans cet article, l'auteur propose l'analyse du réseau social (SNA) comme outil analytique permettant d'explorer la gouvernance collective. L'article présente des données primaires concernant trois études de cas européennes employant des méthodologies tout à fait différentes d'utilisation des incitations financières dans la gouvernance du projet. Ces études de cas portent sur les mécanismes de partage des difficultés/partage des gains mis en ?uvre au titre des approvisionnements par un maître d'?uvre, sur l'usage inhabituel de pénalités liées à l'activité dans le système français des approvisionnements et sur l'usage de suppléments de prix garantis et maximaux dans une forme standard du SNA, au Royaume-Uni, permettant l'observation d'un certain nombre d'ensembles de transactions et la formulation d'un cadre pour la quantification de la gouvernance du projet de construction. La première étude de cas démontre la décentralisation de la gestion financière orientée ‘client’, du consultant métreur-vérificateur vers un certain nombre de responsables de groupes pluridisciplinaires. La deuxième étude de cas illustre l'importance de la contiguïté incitative dans une gouvernance de projet efficace. La troisième étude de cas utilise la SNA pour démontrer comment pourrait être transformée la gouvernance financière en passant d'une gestion financière orientée ‘client’, du client et de son conseiller professionnel, vers le maître d'?uvre.

Mots-clés: modèles de développement, collaboration, gouvernance, incitations, contrats de maître d'oeuvre, approvisionnement, dynamique du projet, organisation du projet, analyse du réseau social, intégration des équipes.  相似文献   
92.
The purpose of this project was to compare the ability of chlorine (HOCl/OCl) and monochloramine (NH2Cl) to mobilize mercury from dental amalgam. Two types of amalgam were used in this investigation: laboratory-prepared amalgam and samples obtained from dental-unit wastewater. For disinfectant exposure simulations, 0.5 g of either the laboratory-generated or clinically obtained amalgam waste was added to 250 mL amber bottles. The amalgam samples were agitated by end-over-end rotation at 30 rpm in the presence of 1 mg/L chlorine, 10 mg/L chlorine, 1 mg/L monochloramine, 10 mg/L monochloramine, or deionized water for intervals of 0 h, 2 h, 4 h, 8 h, and 24 h for the clinically obtained amalgam waste samples and 4 h and 24 h for the laboratory-prepared samples. Chlorine and monochloramine concentrations were measured with a spectrophotometer. Samples were filtered through a 0.45 µm membrane filter and analyzed for mercury with USEPA standard method 245.7. When the two sample types were combined, the mean mercury level in the 1 mg/L chlorine group was 0.020 mg/L (n = 25, SD = 0.008). The 10 mg/L chlorine group had a mean mercury concentration of 0.59 mg/L (n = 25, SD = 1.06). The 1 mg/L chloramine group had a mean mercury level of 0.023 mg/L (n = 25, SD = 0.010). The 10 mg/L chloramine group had a mean mercury level of 0.024 mg/L (n = 25, SD = 0.011). Independent samples t-tests showed that there was a significant difference between the natural log mercury measurements of 10 mg/L chlorine compared to those of 1 mg/L and 10 mg/L chloramine. Changing from chlorine to chloramine disinfection at water treatment plants would not be expected to produce substantial increases in dissolved mercury levels in dental-unit wastewater.  相似文献   
93.
The action spectra of Bacillus subtilis spores (ATCC6633) and Salmonella typhimurium LT2 were characterized using physical radiometry for irradiance measurements and a multiple target model to interpret the inactivation kinetics. The observed action spectrum of B. subtilis spores deviated significantly from the relative absorbance spectrum of the DNA purified from the spores, but matched quite well with the relative absorbance spectrum of decoated spores. The action spectrum of B. subtilis spores determined in this study was statistically different from those reported in previous studies. On the other hand, the action spectrum of S. typhimurium bacteria matched quite well with the relative absorbance spectrum of DNA extracted from vegetative cells, except in the region below 240 nm. It is concluded that the common use of the relative DNA absorbance spectrum as a surrogate for the germicidal action spectrum can result in systematic errors when evaluating the performance of a polychromatic UV light reactors using bioassays. For example, if the weighted germicidal fluence (UV dose) calculated using the relative DNA absorbance spectrum as the germicidal weighting factor is found to be 40 mJ cm−2 for a medium pressure lamp UV reactor, that calculated using the relative action spectrum of B. subtilis spores, as determined in this study, would be 66 mJ cm−2.  相似文献   
94.
Tool wear is an important machinability criterion. To reduce total machining costs, this study demonstrates the wear and tribological performance of four ceramic tools in dry high-speed turning of Ni-Co-Cr precipitation hardenable superalloy (Inconel 100). Wear of the tool materials and the structural and phase transformations at the tool–chip interface were investigated. Results obtained reveal that SiAlON ceramic outperformed other ceramic tool materials at different cutting speeds due to the formation of a large amount of mullite tribofilms on the tool face, which serve as a thermal barrier layer. Alumina ceramic with the addition of ZrO2 can be recommended for machining Inconel 100 at speeds above 150 m/min due to its ability to form thermal barrier ZrO2 tribofilms, which decrease the coefficient of friction at the tool–chip interface. Mixed alumina and an alumina matrix reinforced with SiCw were found to be unsuitable for machining age-hardened Inconel 100 superalloy.  相似文献   
95.
Many of today's spaceraft have long mission lifetimes. Whatever the lubrication method selected, the initial lubricant charge is required to last the entire mission. Fluid lubricant losses are mainly due to evaporation, tribo-degradation, and oil creep out of the tribological regions.

In the past, several techniques were developed to maintain the appropriate amount of oil in the system. They were based on oil reservoirs (cartridges, impregnated porous parts), barrier films, and labyrinth seals. Nevertheless, all these systems have had limited success or have not established a proven record for space missions.

The system reported here provides to the ball-race contact fresh lubricant in-situ and on demand when the ball bearing is close to failure. The lubricant is stored in a porous cartridge attached to the inner or the outer ring of a ball bearing. The oil is released by heating the cartridge to eject oil, taking advantage of the greater thermal expansion of the oil compared to the porous network. The heating may be activated by torque increases that signal the depletion of oil in the contact. The low surface tension of the oil compared to the ball bearing material is utilized and the close proximity of the cartridge to the moving balls allows the lubricant to reach the ball-race contacts. This oil re-supply system avoided a mechanism failure, reduced torque to an acceptable level, and extended the life of the component.  相似文献   
96.
Municipal wastewater treatment plants in the USA produce over 6.2 × 106 t of dried sewage sludge every year. This microorganism-rich sludge is often landfilled or used as fertilizer. Recent restrictions on the use of sewage sludge, however, have resulted in increased disposal problems. Extraction of lipids from sludge yields an untapped source of cheap feedstock for biodiesel production. Solvents used for extraction in this study include n-hexane, methanol, acetone, and supercritical CO2. The gravimetric yield of oil was low for nonpolar solvents, but use of polar solvents gave a considerably increased yield; however, the percentage of saponifiable material was less. Extraction of lipids with a mixture of n-hexane, methanol, and acetone gave the largest conversion to biodiesel compared with other solvent systems, 4.41% based on total dry weight of sludge. In situ transesterification of dried sludge resulted in a yield of 6.23%. If a 10% dry weight yield of fatty acid methyl esters is assumed, the amount of biodiesel available for production in the USA is 1.4 × 106 m3/year. Outfitting 50% of municipal wastewater plants for lipid extraction and transesterification could result in enough biodiesel production to replace 0.5% of the national petroleum diesel demand (0.7 × 106 m3).  相似文献   
97.
The permeability of green ceramic tapes was determined as a function of binder content for binder removed by air oxidation. The tapes were comprised of barium titanate as the dielectric, and polyvinyl butyral and dioctyl phthalate were the main components of the binder mixture. The flow in porous media through the tapes was analyzed in terms of models for describing Knudsen, slip, and Poiseuille flow mechanisms. The characteristic pore size was determined to be 1–2 μm, and thus Poiseuille flow was the dominant transport mechanism contributing to the flux. The permeability was then determined from Darcy's law for flow in porous media. The permeability was also determined from microstructural attributes in terms of the specific surface, the pore fraction, and a term to account for tortuosity and constrictions.  相似文献   
98.
Steroid derivatives bearing fluorescent groups such as anthracene, dansyl, deazaflavin, and pyrene attached to C6 were synthesized. These compounds are unique inhibitors of cytochrome P450 3A4 (CYP3A4) and display similar IC(50) values in the microM range for the CYP3A4 substrates midazolam, testosterone, and nifedipine. On binding to CYP3A4, the fluorescence of the dansyl, deazaflavin, and pyrene probes is quenched by photophysical interaction of the fluorophore with the heme. The addition of drug candidates with binding constants in the nM-microM range causes displacement of the probes from the active site, and hence leads to restoration of fluorescence. Accordingly, relative affinities of drug candidates to CYP3A4 can be easily and accurately determined by fluorescence measurements.  相似文献   
99.
The effect of microfillers on the thermal stability of natural rubber (NR), carboxylated styrene butadiene rubber (XSBR) latices, and their 70/30 NR/XSBR blend were studied using thermogravimetric method. Microcomposites of XSBR and their blend were found to be thermally more stable than unfilled samples. The activation energy needed for the degradation of polymer chain was calculated from Coats‐Redfern plot. Activation energy needed for the thermal degradation of filled samples was higher than unfilled system. It indicated the improved thermal stability of the filled samples. The ageing resistance of the micro‐filled samples was evaluated from the mechanical properties of aged samples. The thermal ageing was carried out by keeping the samples in hot air oven for 7 days at 70°C. The mechanical properties such as tensile strength, modulus at 300% elongation, and strain at break were computed. As compared to unfilled samples, micron‐sized fillers reinforced systems exhibited higher ageing resistance. Finally, an investigation was made on the influence of ion‐beam irradiation on microcomposites of NR, XSBR latices, and their 70/30 blend systems using 28Si8+ performed at 100 MeV. The surface changes of the samples after irradiation were analyzed using X‐ray photoelectron spectroscopy. The results of XPS measurements revealed that the host elements were redistributed without any change in binding energies of C1s, O1s, and Si2p. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007  相似文献   
100.
Machining experiments using tooling prepared with thin perfluoropolyether (PFPE) lubricant films, which were applied to diamond-like carbon (DLC) PVD coatings, were compared to traditional tooling used in wet-machining conditions for the drilling of a cast aluminum-silicon B319 alloy. Multi-layered DLC + PFPE coatings show promise under minimum quantity lubrication (MQL) machining conditions of aluminum alloys. The positive impact on performance of this surface treatment is compared to wet machining by studying tool life, wear behavior and chip formation using coated cemented carbide drill bits. Cutting torque was measured in situ together with the characteristics of the chips. Also the chip cross-section micro-structure was evaluated using a scanning electron microscope (SEM). This article was presented at Materials Science & Technology 2007, Automotive and Ground Vehicles symposium held September 16-20, 2007, in Detroit, MI.  相似文献   
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