Graft copolymerization of mixtures of acrylic acid and acrylamide onto polypropylene film

Liquid phase ultraviolet irradiation in the presence of benzophenone as a photosensitizer and barium hydroxide as a pH controller were used to graft the mixtures of acrylic acid and acrylamide to a polypropylene surface. The surface of the grafted polypropylene samples were characterized by Fourier transform infrared spectroscopy‐attenuated total reflectance, electron spectroscopy for chemical analysis, scanning electron microscopy, and a contact angle meter. The pH value of the reaction medium that produced the graft with equal molar ratio was found to be ∼ 3.77. The optimal reaction condition was found at a monomer feed of 25%, a reaction time of 30 min, and a benzophenone concentration of 1%. Surface tension of the samples increased to a value of 40 dyn cm⁻¹ due to the graft of the hydrophilic monomers. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 72: 251–256, 1999     

Separation of CO2 by 2-amino-2-methyl-1-propanol aqueous solution in microporous hydrophobie hollow fiber contained liquid membrane

The absorption of CO₂ from a mixture of CO₂/N₂ gas was carried out using a flat-stirred vessel and the polytetrafluoroethylene hollow fiber contained aqueous 2-amino-2-methyl-1-propanol (AMP) solution. The reaction of CO₂ with AMP was confirmed to be a second order reversible reaction with fast-reaction region. The mass transfer resistance in the membrane side obtained from the comparison of the measured absorption rates of CO₂ in a hollow fiber contained liquid membrane with a flat-stirred vessel corresponded to about 90% of overall-mass-transfer resistance. The mass transfer coefficient of hollow fiber phase could be evaluated, which was independent of CO₂ loading.     

Esterification of lauric acid with isopropyl alcohol by tricaprylylmethylammonium chloride as a catalyst in a liquid-liquid heterogeneous system

Experiments were performed on the esterification of lauric acid with isopropyl alcohol by tricaprylylmethylammonium chloride in a stirred vessel with a flat liquid-liquid interface. The observed initial rate of reaction was used to analyze the reaction mechanism combined with the catalyst, and to evaluate the several kinds of reaction rate constant, from which equilibrium constants were expressed as a function of reaction temperature. The analysis of reaction kinetics indicated that the reaction was between a very slow and slow reaction regime.     

Copolymer derived from dihexyl-2H-benzimidazole and carbazole for organic photovoltaic cells

A new accepter unit, dihexyl-2H-benzimidazole, was prepared and utilized for the synthesis of the conjugated polymers containing electron donor-acceptor pair for OPVs. Dihexyl-2H-benzimidazole unit was designed to substitute the BT unit of PCDTBT. A new series of copolymers with carbazole as the electron-rich unit and dihexyl-2H-benzimidazole as the electron-deficient unit are synthesized. To obtain absorption in the longer wavelength region, bithiophene units without any alkyl group are incorporated as one of the monomers, which may result in low solubility of the polymers. In dihexyl-2H-benzimidazole, sulfur at 2-position of BT unit was replaced with dialkyl substituted carbon, while keeping the 1,2-quinoid form, to improve the solubility of the polymers. The spectra of the solid films show absorption bands with maximum peaks at 446-457 nm and the absorption onsets at 527-539 nm, corresponding to bandgaps of 2.30-2.35 eV. Under white light illumination (AM 1.5 G, 100 mW/cm²), the devices with PCBBTHBIs:PCBM layers showed open-circuit voltages (V_OC) of 0.13-0.23 V, short-circuit current densities (J_SC) of 3.52-5.69 mA/cm², and fill factors (FF) of 0.36-0.40, giving power-conversion efficiencies of 0.21-0.47%.     

Bubble Dynamics,Flow, and Heat Transfer during Flow Boiling in Parallel Microchannels

Significant efforts have recently been made to investigate flow boiling in microchannels, which is considered an effective cooling method for high-power microelectronic devices. However, a fundamental understanding of the bubble motion and flow reversal observed during flow boiling in parallel microchannels is lacking in the literature. In this study, complete numerical simulations are performed to further clarify the boiling process by using the level-set method for tracking the liquid–vapor interface which is modified to treat an immersed solid surface. The effects of contact angle, wall superheat, and the number of channels on the bubble growth, reverse flow, and heat transfer are analyzed.     

Highly Stretchable or Transparent Conductor Fabrication by a Hierarchical Multiscale Hybrid Nanocomposite

As is frequently seen in sci‐fi movies, future electronics are expected to ultimately be in the form of wearable electronics. To realize wearable electronics, the electric components should be soft, flexible, and even stretchable to be human‐friendly. An important step is presented toward realization of wearable electronics by developing a hierarchical multiscale hybrid nanocomposite for highly flexible, stretchable, or transparent conductors. The hybrid nanocomposite combines the enhanced mechanical compliance, electrical conductivity, and optical transparency of small CNTs (d ≈ 1.2 nm) and the enhanced electrical conductivity of relatively bigger Ag nanowire (d ≈ 150 nm) backbone to provide efficient multiscale electron transport path with Ag nanowire current backbone collector and local CNT percolation network. The highly elastic hybrid nanocomposite conductors and highly transparent flexible conductors can be mounted on any non‐planar or soft surfaces to realize human‐friendly electronics interface for future wearable electronics.     

Fabrication of Multiscale Gradient Polymer Patterns by Direct Molding and Spatially Controlled Reflow

Size variations of pattern spacing as well as gradient control of the as‐formed polymeric pattern via a spatially controlled reflow process are presented. Micro‐ and nanopatterns of polymethyl methacrylate (PMMA) in the form of line‐and‐space strips are first generated by capillary force lithography (CFL), and the residual layers are removed by ashing process. Subsequently, the exposed PMMA strips underwent a controlled reflow process above the glass transition temperature (T_g) while heating single or both sides of the substrate either in parallel to the line pattern (parallel reflow) or perpendicular to the line pattern (perpendicular reflow). As a result of this controlled reflow, a linear or a parabolic profile of pattern spacing is achieved depending on the heating mode. Furthermore, multiscale gradient patterns are formed with the spacing ranging from 98 nm to 4.23 μm (a difference of two orders of magnitude) in a single patterned layer using the original micropattern of 16 μm width and 8 μm spacing. In order to explain reflow behaviors, a simple theoretical model relating the normalized pattern width to the polymer viscosity is derived based on a leveling kinetics of polymer melt. Also, gradient PMMA channels are fabricated and bonded to a glass substrate, which are used to flow a liquid inside the channels by capillarity‐driven flow.     

Decision on the memory size of embedded information systems in an ubiquitous maintenance environment

Over the last decade, emerging information communication technologies have changed our stereotype of manufacturing and service companies. Now products equipped with embedded systems can be wirelessly networked, which leads to gathering and analyzing product status, and taking appropriate actions for maintenance operations during product lifecycle in an ubiquitous way. In this environment, it is necessary to determine the appropriate memory size of embedded systems for minimizing total maintenance system costs because the memory cost is a main cost factor for implementing the ubiquitous maintenance environment. We call it memory size decision problem in this study. We have formulated this problem with a non-linear model having constraints. The decision variable is the memory size of each embedded system. To solve this problem, we have proposed a meta heuristic search method based on genetic algorithms. To show the usefulness of the proposed heuristic, we have carried out computational experiments.