Model concrete beam-column joints subjected to cyclic loading at two rates

Small-scale models of reinforced concrete beam-column joint were subjected to large cyclic displacements at two rates: 2.5×10⁻³ and 1.0 Hz. To assess damage, free-vibration tests were conducted. The reliability of the modelling techniques was established by comparison of the results for the slower rate with those obtained from the full-scale tests on prototype. The higher rate of loading caused a greater damage than that at the lower rate. This was evidenced by the measurements of the energy absorbed in the hysteresis loops, equivalent damping, and the stiffness and damping obtained from the free-vibration test. The relatively greater extent of damage appears to result from the different bond behaviour at different rates of loading.     

Performance of a non‐load‐bearing steel stud gypsum board wall assembly: Experiments and modelling

A gypsum wall assembly was exposed to an intense real‐scale compartment fire. For the wall assembly, temperatures were measured at the exposed face, within the stud cavity, and at the unexposed face during the fire exposure. Total heat flux gauges were used to measure the temporal variation of the energy incident on the walls, and cameras, both visual and infrared, were used to image the unexposed face of the wall assembly during the fire exposure. The behaviour of the wall assembly under the fire load is discussed as are current model results for a simulation of the fire test. Copyright © 2006 John Wiley & Sons, Ltd.     

Copper(II) removal from aqueous solutions by fly ash

The removal of Cu(II) by adsorption on fly ash has been found to be concentration, pH and temperature dependent. The kinetics of adsorption indicates the process to be diffusion controlled. The Langmuir constants have been calculated at different temperatures, and the adsorption has been found to be endothermic (ΔH = 15.652 kcal mol^?1). The maximum removal is observed at pH 8.0, and variation in adsorption with pH has been explained on the basis of surface ionisation and complexation.     

Hydrolysis of Fe(OH)SO4 in the presence of metallic iron

Hydrolysis of Fe(OH)SO₄ was carried out in the presence of metallic iron in order to prevent the formation of iron(III) oxides with strongly bonded sulphate. Under the conditions of the experiment, the products were found to be mixtures of ?-Fe₂O₃ and α-FeOOH. The occluded sulphate, if any, could be easily washed out with water. The hydrolysis reaction passes through an equilibrium state before coming to completion. The entropy with enthalpy of the hydrolysis corresponding to the equilibrium state were found to be 4 e.u. and 0·5 kJ/mol, respectively. The activation energy of the hydrolysis reaction was found to be 21 kJ/mol.     

Corrosion characteristics of aluminium alloy graphite particulate composite in various environments

The present study was aimed at understanding the response of 2014 Al alloy dispersed with graphite particles in various corrosive environments. Marine (sodium chloride) as well as acidic media were selected for the purpose with a view to widen the range of utility of the composite for applications where such environments may be encountered. Studies were also extended to characterize the corrosion resistance of the composite in fresh as well as used lubricating oils to explore the possibilities of using it in bearing, bushing and such other applications. The corrosion behaviour of the base alloy processed under identical conditions was also examined in the above media to see the influence of graphite addition in the alloy. In order to assess the role of the matrix microstructure, the composite as well as the base alloy was subjected to corrosion in heat-treated as well as-cast conditions. It was observed that the specimens suffered from the maximum rate of corrosion in acid, while sodium chloride produced the minimum corrosion rate. Oil in both used and fresh conditions revealed a negligibly small extent of corrosion. The composite was found to show a higher rate of corrosion than the base alloy under identical test conditions. This was attributed to the dispersoid/matrix interfacial corrosion in the case of the graphitic aluminium alloy. Heat treatment of the composite and the base alloy was found to lower the rate of corrosion in the environments tested. Microstructural modifications of the matrix and possible relief of residual stresses were thought to be responsible for the lower rate of corrosion in the heat-treated condition.     

Response spectrum analysis of piping systems with elastic-plastic gap supports

A new seismic support device and its application in piping systems is described. The device, E-BAR (patented), can be cost effectively used for snubber replacement programs, mitigation of hydraulic transients, pipe whip and as a thermal stop. The device has pre-set gaps to allow free thermal movement. During a seismic or other dynamic load event, if the pipe movement exceeds the gap dimension, the device acts as an elastic or elastic-plastic restraint. The device also has a unique design feature for not exceeding the restraint force beyond a specified limit design value. To analyze piping systems with gap supports having elastic-plastic characteristics, modal analysis procedures for both response spectrum and time history methods are developed. The comparison of responses obtained from the procedures with nonlinear time history analysis and test results available in the literature shows excellent correlation. A pilot program conducted for snubber replacement with E-BARs demonstrates that the limit force feature of E-BAR makes them very attractive for snubber replacement. This is because a particular E-BAR with a specified limit design force can be selected, such that, the E-BAR replacing the snubber does not require any modifications be made to the existing support steel and hardware.     

Safety,liveness and fairness in temporal logic

In this paper we present syntactic characterization of temporal formulas that express various properties of interest in the verification of concurrent programs. Such a characterization helps us in choosing the right techniques for proving correctness with respect to these properties. The properties that we consider include safety properties, liveness properties and fairness properties. We also present algorithms for checking if a given temporal formula expresses any of these properties.This work is partly supported by NSF grant CCR-9212183. A preliminary version of this paper appeared in the Fourth ACM Symposium on Principles of Distributed Computing.     

Spectrophotometric determination of some antioxidants with potassium permanganate and metol

New spectrophotometric methods for the assay of some antioxidants have been developed using potassium permanganate and metol (p-N-methyl amino phenol). Metol is oxidised at pH 3.0 with potassium permanganate and coupled with antioxidants to give λ_max at 560 nm for propyl gallate and gallic acid and 510nm for butylated hydroxy anisole. The method is simple, sensitive, reproducible and accurate within ±1% and applicable to the assay of antioxidants (gallic acid, propyl gallate and butylated hydroxy anisole) in oils and fats.     

Raman studies of structural rearrangements induced in human plasma lipoprotein carotenoids by malondialdehyde

Raman and resonance Raman spectra of plasma lipoproteins ± malondialdehyde were studied at concentrations which block the normal receptor-mediated uptake by cells. The strong resonance Raman bands at about 1010, 1162 and 1530 cm⁻¹, due to the presence of carotenoids in the lipoproteins, are envisaged as structural probes. High resolution resonance Raman spectra of the 1500–1600 cm⁻¹ region reveal multiple features suggesting the coexistence of several structural populations of β-carotene whose precise assignment is complex. When plasma lipoproteins are reacted with malondialdehyde, a complex change occurs in the resonance Raman banding of β-carotene in the 1500–1600 cm⁻¹ region. Malonaldehyde (MDA) also modifies the acoustical region (70–200 cm⁻¹ of low density lipoprotein (LDL) lipids. We suggest that malondialdehyde association with plasma lipoproteins alters the lipid structure via apoprotein or apoprotein/lipid associations.