Solidification behaviour,microstructure and mechanical properties of high Fe-containing Al–Si–V alloys

The paper deals with effect of Fe on the solidification behaviour and mechanical properties of unmodified and modified Al–V–Si alloys. Effect of thermo-mechanical processing on the mechanical properties of these alloys was also reported. The solidification proceeds through several invariant reactions, the first one corresponds to formation of Al₃(Fe,V,Si)-type phase. Modification with Ni–Mg master alloy changes the morphology, size and distribution of the primary as well as interdendritic phases. The modified alloys show an increase in first invariant reaction temperature and decrease in final invariant reaction temperature when compared with unmodified alloy, probably due to action of phase modification. In comparison to untreatable alloy, appreciable improvement in mechanical properties occurs on modification by Ni–Mg treatment. Hot rolling further improves the mechanical properties of the alloy.     

Reservoir Release Policy for Large Irrigation System

This paper describes the formulation of a model for optimized crop and water planning decisions in an irrigation system in Thailand. It facilitates consultation in which representatives of stakeholders, officials, farmers, and researchers can contribute to the decision making. Linear programming and the analytical hierarchy process are the principal modeling tools to optimize the collective system objectives: productivity, equity, and security. The results of the model are compared with observed events of one dry season. The optimized policy generated by the model suggested a diversified cropping pattern, which would decrease the water requirement by 16.4% and enhance net benefit per cubic meter of water used by 39.9%. The erratic water availability from the reservoir and the operational procedures inside the system are reviewed, analyzing historical data in terms of reliability, resiliency, and vulnerability. These include lack of proper assessment of available water, effective farmer organization, and prompt data processing and communication. Furthermore, for the effective implementation of an optimized irrigation policy, a water release pattern of the storage reservoir has been suggested.     

CFD analysis of natural convection heat transfer augmentation from square conductive horizontal and inclined pin fin arrays

Numerical investigations on natural convection heat transfer from a vertical isothermal plate with pin fins have been made by solving the Navier–Stokes equation along with the energy equation. Average Nusselt number for the plate with different configurations of pin fins have been obtained. It was observed that the maximum increase of the average Nusselt number occurs at S_v/L?=?0.2 for θ?=?45° with fin height of 24?mm (H/t?=?8). The average Nusselt number increases with fin aspect ratio and decreases with angle of inclination. There is not much difference between the average Nusselt number for in-line and staggered arrangement of fins for the range of parameters studied in the present work. A correlation is developed to predict the average Nusselt number of the plate as a function of fin spacing in stream- and span-wise direction, aspect ratio of fins and its angle of inclination.     

An Efficient,Stable and Reusable Palladium Nanocatalyst: Chemoselective Reduction of Aldehydes with Molecular Hydrogen in Water

Palladium nanoparticles (Pd‐BNP) stabilized by a binaphthyl‐backbone can be efficiently used for the chemoselective reduction of aldehydes in the presence of hydrogen at room temperature in water. The Pd‐BNP catalyst is easily recovered and reused for five catalytic cycles.

     

Comparative delivery of Diltiazem hydrochloride through synthesized polymer: Hydrogel and hydrogel microspheres

In this study, interpenetrating polymer network (IPN) hydrogel based on polyvinyl alcohol (PVA) networking with polyacrylic acid (PAA) were prepared by a non‐conventional emulsion method without any added crosslinker, using benzoyl peroxide as initiator and sodium chloride (NaCl) as additive. The IPN hydrogel was characterized by using Fourier transformed infrared (FTIR) spectrophotometry, Thermo gravimetric analysis (TGA), and Scanning electron microscopy (SEM). (PVA‐co‐PAA)/NaCl normal IPN hydrogel (H) were fabricated into hydrogel microspheres (HM) by modified emulsion crosslinking method using glutaraldehyde‐saturated toluene as crosslinker and were loaded with Diltiazem hydrochloride (DL). The IPN hydrogel showed more swelling in simulated intestinal fluid (SIF). (PVA‐co‐PAA)/NaCl HM formulation A1 showed comparatively higher DL entrapment (79%) and better control over DL release up to 24 h. By comparing antihypertensive activity of DL loaded two formulations in normotensive rats, HM formulation A1 found more effective in reducing blood pressure to 40.1%. The experimental results demonstrated that (PVA‐co‐PAA)/NaCl HM had the greater potential than normal hydrogel to be used as a drug carrier. A single use of the prepared hydrogel microsphere system of DL can effectively control hypertension in rats. The system holds promise for clinical studies. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Dissolution of waste plastics in biodiesel

The dissolution behavior of polystyrene (PS) and low‐density polyethylene (LDPE) in biodiesel was investigated with an eye towards developing methods to dispose waste plastics by burning them with fuel. To complement and guide the experimental investigations, molecular dynamics simulations were performed to calculate solubility parameters, cohesive energy densities, Flory‐Huggins χ parameters and phase diagrams of the target systems. Dissolution kinetics of PS and LDPE in methyl esters was monitored by gravimetry, from which parameters such as dissolution rates, activation energies, and scaling indices were estimated. The shear viscosity of the polymer solutions was measured to ascertain their suitability as fuel mixtures. The dissolution of PS in biodiesel appears to be controlled by the diffusion of polymer chains through a boundary layer adjacent to the polymer/solvent interface. Taken together, the experimental and modeling studies provide a predictive toolbox to design biodiesels of different compositions that will dissolve commodity polymers such as PS and LDPE to be used as fuels in engines. POLYM. ENG. SCI., 2010. © 2009 Society of Plastics Engineers     

Superior Analog Performance due to Source-Gate Overlap in Vertical Line-Tunneling FETs and Their Circuits

Silicon - This paper presents a Vertical Line-Tunneling FET (VLTFET) optimized for superior performance in analog applications. The saturation mechanism, DC, and small-signal behaviors are...     

Preparation of thermal resistant gas barrier chitosan nanobiocomposites

Nanobiocomposites of chitosan/clay were prepared by solution method using CuSO₄/glycine chelate complex as the catalyst with variable percentage of clay loading. The chemical interaction of chitosan and clay was studied by Fourier transform infrared spectroscopy. The structure of chitosan and clay nanobiocomposites was investigated by X‐ray diffraction and high resolution transmission electron microscopy. From thermogravimetric analysis, it was found that chitosan/clay nanobiocomposites were more thermally stable as compared to pure chitosan. A substantial reduction in oxygen permeability was obtained from the gas permeameter with increase in clay concentrations by which the synthesized nanocomposites materials may be used for packaging applications. POLYM. COMPOS., 35:2324–2328, 2014. © 2014 Society of Plastics Engineers     

Control system design for recycle systems

This paper considers the control system design for recycle systems. We derive a condition which quantifies the effect of recycling on closed-loop performance. The condition is independent of control/controller structure. With insight from this condition, we develop a set of heuristics for properly designing a controller without detailed knowledge of recycle dynamics for the important special case where the system is represented by a first-order-plus-time-delay model and where the IMC tuning rules are used. The heuristics require only a minimal amount of information on the recycle dynamics. Their effectiveness is illustrated on a reactor/feed-effluent heat exchanger/furnace process under various conditions.