Remarkable enhancement in durability of Pd/H-ZSM-5 zeolite catalysts for CH4-SCR

Effect of second components on the catalytic performance of Pd/H-ZSM-5 zeolite (Pd: 0.4 wt.%) was evaluated by a durability test of NO reduction with CH₄ at a relatively high temperature of 500°C in the presence of water vapor for a prolonged period. The Pd/H-ZSM-5 showed high stable activity for this reaction without H₂O in the reactant feed, while immediate and irreversible deactivation was observed in the presence of H₂O, resulting in no activity after 7 h. The second components such as Co, Rh, Ag, Ce, and Fe introduced individually to the Pd/H-ZSM-5 enhanced the durability, and in particular the addition of 3.3 wt.% Co led to a stable NO conversion for more than 40 h in the presence of H₂O.     

Tensile, Solubility, and Electrophoretic Properties of Egg White Films as Affected by Surface Sulfhydryl Groups

Films plasticized with polyethylene glycol were cast from alkaline (pH 10.5, 11.0, or 11.5), aqueous egg white (EW) solutions with or without heating (40°C for 30 min). Prior to casting, concentration of surface sulfhydryl (SH) groups was determined and they increased (P < 0.05) (3.81–19.45 μM/g protein) with both pH and heating, presumably due to protein denaturation and cleavage of disulfide (S-S) bonds. Concentration of surface SH groups correlated (P < 0.05) with film tensile strength (r = 0.70), elongation at break (r = 0.86), and film total soluble matter (r =−0.94). Most likely, surface SH groups formed S-S bonds through air oxidation and/or sulfhydryl/disulfide interchange, thus contributing to EW film formation. SDS-PAGE patterns in presence or absence of 2-mercaptoethanol confirmed occurrence of S-S bonding in dried EW films.     

Eleven phthalate esters and di(2-ethylhexyl) adipate in oneweek duplicate diet samples obtained from hospitals and their estimated daily intake

Plasticizers in duplicate diet samples obtained over 1 week were analysed in order to estimate daily intake. The phthalate esters were as follows: diethyl, dipropyl, dibutyl, dipentyl, dihexyl, butylbenzyl, dicyclohexyl, di(2-ethylhexyl), dioctyl, diisooctyl (mixture of isomers) and diisononyl (mixture). Di(2-ethylhexyl) adipate was also determined. Homogenized samples of composite meals were extracted with acetonitrile, lipids were removed by extraction into n-hexane and the acetonitrile layer was cleaned using FlorisilR and R Bondesil PSA dual layer column. Phthalates were determined by GC/MS (SIM). Phthalate recovery from the fortified food mixture by this method was 62.5-140.8%. Quality assurance as assessed by three laboratories indicated coefficient of variance in the levels of detected phthalates in same lot samples as below 10%. Detection limits were 0.1-23ng/g for each phthalate. One-week duplicate diet samples provided by three hospitals in three remote prefectures of Japan were analysed as individual meals. In all 63 samples, DEHP was present at the highest level among all phthalates in the range 10-4400ng/g. The intake of plasticizers estimated from all samples was 519 µ g DEHP/day, 86 µ g DEHA/day, 65 µ g DINP/day, and 4.7 µ g BBP/day. Calculated DEHP in 2-day samples out of 21 days exceeded EU TDI for a person of 50kg body weight (1850 µ g per day). Disposable PVC gloves used during the preparation of meals were suspected as the source of the high DEHP content. One-day intake of the other phthalates and DEHA was below 7% of TDI in all cases. High concentrations of DEHP (5990ng/g) was found in baby food used in quality assurance work. The source of contamination was the PVC-tube used during production and was effectively reduced by replacing the tube by one made of stainless steel.     

Dynamic finite element simulation of the gunshot injury to the human forehead protected by polyvinyl alcohol sponge

Although there are some traditional models of the gunshot wounds, there is still a need for more modeling analyses due to the difficulties related to the gunshot wounds to the forehead region of the human skull. In this study, the degree of damage as a consequence of penetrating head injuries due to gunshot wounds was determined using a preliminary finite element (FE) model of the human skull. In addition, the role of polyvinyl alcohol (PVA) sponge, which can be used as an alternative to reinforce the kinetic energy absorption capacity of bulletproof vest and helmet materials, to minimize the amount of skull injury due to penetrating processes was investigated through the FE model. Digital computed tomography along with magnetic resonance imaging data of the human head were employed to launch a three-dimensional (3D) FE model of the skull. Two geometrical shapes of projectiles (steel ball and bullet) were simulated for penetrating with an initial impact velocity of 734 m/s using nonlinear dynamic modeling code, namely LS-DYNA. The role of the damaged/distorted elements were removed during computation when the stress or strain reached their thresholds. The stress distributions in various parts of the forehead and sponge after injury were also computed. The results revealed the same amount of stress for both the steel ball and bullet after hitting the skull. The modeling results also indicated the time that steel ball takes to penetrate into the skull is lower than that of the bullet. In addition, more than 21 % of the steel ball’s kinetic energy was absorbed by the PVA sponge and, subsequently, injury sternness of the forehead was considerably minimized. The findings advise the application of the PVA sponge as a substitute strengthening material to be able to diminish the energy of impact as well as the load transmitted to the object.     

High Field ESR System and Its Application to the Study of Quantum Spin Systems

Developments of the high field ESR system in Kobe University is presented. Using Gunn oscillators and backward traveling oscillators (BWO), we can cover the frequency region from 30 to 1183.6 GHz with the use of InSb detector. Pulsed magnetic field up to 30 T is available and we are now trying to extend the field up to 40 T. Temperature range is from 1.8 to 300 K. Using this system, we studied S=1/2 ladder like system Cu₂(C₅H₁₂N₂)₂Cl₄, and found a new magnetic transition at 10.1 T at 1.8 K. The temperature dependence of ESR in Cu₂(C₅H₁₂N₂)₂CI₄ shows g-shift below 8 K which corresponds to the maximum of the magnetic susceptibility. The g-shift below 8 K suggests the increase of the quantum fluctuation in the system, and the role of the quantum fluctuation in Cu₂(C₅H₁₂N₂)₂CI₄ is discussed.     

A multichannel FES system for the restoration of motor functions inhigh spinal cord injury patients: a respiration-controlled system formultijoint upper extremity

A multichannel functional electrical stimulation (FES) system for the restoration of quadriplegic upper extremity function is described. The system is composed of a personal computer NEC PC-8801mkII, peripheral electronic circuits, CRT display and respiratory sensors for volitional control by the patient, and percutaneous electrodes. A C4 quadriplegic patient could drink canned tea by herself by using this FES system. Distinct features of the system are as follows: 1) Versatile volitional control was realized by controlling the memory allocation of the stored stimulation data by voluntary respiratory signals. 2) Sophisticated fine control of the fingers, wrists, and elbow was realized by creating the multichannel stimulation data from recorded myoelectric activities of normal subjects during movements of the upper limb.     

Study on fabrication of 3-D microstructures by synchrotron radiation based on pixels exposed lithography

We report research on the development of a method of fabricating three-dimensional microstructures that uses synchrotron radiation light. Some research on three-dimensional processing methods using SR lithography has already been reported. They have involved techniques of applying exposure energy distributions to resist surfaces. Complicated energy distributions need to be applied to resist surfaces to fabricate arbitrary three-dimensional structures. However, we devised a new method that made it possible to fabricate arbitrary three-dimensional microstructures by using a mask with pattern created function. The advantages of this method are that it is suitable for rapid prototyping and it reduces the fabrication time and cost since it is not necessary to fabricate conventional photolithographic masks. Our research involved a basic experiment on this method of fabrication where we succeeded in fabricating a free-form surface by exposing it through an overlapping array of pixels that created a single aperture. Moreover, the pixel size could be made smaller than the aperture size by overlapping adjoining pixels.     

Construction and field measurement of high-speed railway test embankment built on Indian expansive soil “Black Cotton Soil”

The railway embankment applied to high-speed railways is required to have high performance in terms of strength and deformation characteristics. Especially in the case of railway embankments that support slab tracks, the allowable settlement is very small. There are two technical challenges in constructing high-speed rail embankments to support slab tracks in India. The first challenge is dealing with problematic black cotton soil (BCS), which is widely distributed in India but very unusual soil in Japan. The second challenge is posed by the strict deformation requirement in the construction of the embankments. In this study, a 6 m-high test embankment was constructed on BCS in India. The deformation of the embankment and changes in water content were measured over a period of 18 months. In the construction of the test embankment, two different BCS countermeasures were applied. The results of the tests on this embankment were compared with those from an embankment without countermeasures. Complicated deformation behaviors, including settlement and the uplift of embankment, were observed in the section without countermeasure. However, in the embankment with cement-mixed gravelly soil (CGS) slab improvement with geosynthetics, the much lower amplitude of embankment deformation is evidence of the effectiveness of this countermeasure. The cohesive non-swelling soil (CNS) layer applied immediately below the embankment to reduce the water content fluctuation of BCS was not effective enough for use for high-speed railway embankment. Besides determining the technical challenges for the BCS countermeasures, the results of this study confirmed that a high-performance embankment can be constructed with Indian embankment material by performing sufficient compaction management.     

Negative Pore Air Pressure Generation in Backfill of Retaining Walls During Earthquakes and its Effect on Seismic Earth Pressure

In order to investigate the seismic behavior of conventional type and geosynthetic-reinforced soil retaining walls, 1-g model shaking tests were conducted. Model walls having a height of about 50 cm were placed on a subsoil layer and backfilled with a layer of dense dry Toyoura sand. They were subjected to several steps of horizontal irregular excitations. As a result, generation of negative pore air pressure in the backfill was observed. The maximum amplitude of the negative pore air pressure during each shaking step increased with the base acceleration. Based on analyses of the measured data, it was inferred that such negative pore air pressure was caused by outward wall displacement relative to the backfill and not by dilative behavior of the backfill. It would cause a reduction in the seismic earth pressures exerted from the backfill. This feature suggests an advantage of a rigid full-height facing for reinforced soil walls over the segmental types of facing. A simplified numerical procedure to evaluate earth pressure was applied while considering the effects of the negative pore air pressure, and it could qualitatively simulate the measured behavior in terms of the seismic earth pressure and the angle of failure plane in the backfill.