Antimicrobial effect of cranberry juice and extracts

The antimicrobial effect of cranberry juice and of three cranberry extracts (water-soluble (E1) and apolar phenolic compounds (E2), and anthocyanins (E3)) was investigated against seven bacterial strains (Enterococcus faecium resistant to vancomycin (ERV), Escherichia coli O157:H7 EDL 933, Escherichia coli ATCC 25922, Listeria monocytogenes HPB 2812, Pseudomonas aeruginosa ATCC 15442, Salmonella Typhimurium SL1344, and Staphylococcus aureus ATCC 29213). Each cranberry sample was analyzed to determine the minimum inhibitory concentration (MIC) and the maximal tolerated concentration (MTC) at neutral pH. The results, reported in μg phenol/mL, indicated that all the bacterial strains, both Gram-positive and Gram-negative, were selectively inhibited by the cranberry phenolic compounds. The extract rich in water-soluble phenolic compounds caused the most important growth inhibitions. The bacteria ERV, and to a lesser degree, P. aeruginosa, S. aureus and E. coli ATCC 25922, were the most sensitive to the antimicrobial activity of extract E1. The growth of P. aeruginosa and E. coli ATCC was also affected by the presence of the anthocyanin-rich cranberry extract E3, although the observed antibacterial effect was not as important as with extract E1. In general, L. monocytogenes, E. coli O157:H7 and S. Typhimurium were the most resistant to the antibacterial activity of the cranberry extracts. Within 30 min of exposure with pure neutralized cranberry juice, L. monocytogenes and ERV were completely inactivated.     

Carbon and sulfur cycling by microbial communities in a gypsum-treated oil sands tailings pond

Oil sands tailings ponds receive and store the solid and liquid waste from bitumen extraction and are managed to promote solids densification and water recycling. The ponds are highly stratified due to increasing solids content as a function of depth but can be impacted by tailings addition and removal and by convection due to microbial gas production. We characterized the microbial communities in relation to microbial activities as a function of depth in an active tailings pond routinely treated with gypsum (CaSO(4)·2H(2)O) to accelerate densification. Pyrosequencing of 16S rDNA gene sequences indicated that the aerobic surface layer, where the highest level of sulfate (6 mM) but no sulfide was detected, had a very different community profile than the rest of the pond. Deeper anaerobic layers were dominated by syntrophs (Pelotomaculum, Syntrophus, and Smithella spp.), sulfate- and sulfur-reducing bacteria (SRB, Desulfocapsa and Desulfurivibrio spp.), acetate- and H(2)-using methanogens, and a variety of other anaerobes that have been implicated in hydrocarbon utilization or iron and sulfur cycling. The SRB were most abundant from 10 to 14 mbs, bracketing the zone where the sulfate reduction rate was highest. Similarly, the most abundant methanogens and syntrophs identified as a function of depth closely mirrored the fluctuating methanogenesis rates. Methanogenesis was inhibited in laboratory incubations by nearly 50% when sulfate was supplied at pond-level concentrations suggesting that in situ sulfate reduction can substantially minimize methane emissions. Based on our data, we hypothesize that the emission of sulfide due to SRB activity in the gypsum treated pond is also limited due to its high solubility and oxidation in surface waters.     

Multipath optimized link state routing for mobile ad hoc networks

Multipath routing protocols for Mobile Ad hoc NETwork (MANET) address the problem of scalability, security (confidentiality and integrity), lifetime of networks, instability of wireless transmissions, and their adaptation to applications.Our protocol, called MultiPath OLSR (MP-OLSR), is a multipath routing protocol based on OLSR [1]. The Multipath Dijkstra Algorithm is proposed to obtain multiple paths. The algorithm gains great flexibility and extensibility by employing different link metrics and cost functions. In addition, route recovery and loop detection are implemented in MP-OLSR in order to improve quality of service regarding OLSR. The backward compatibility with OLSR based on IP source routing is also studied. Simulation based on Qualnet simulator is performed in different scenarios. A testbed is also set up to validate the protocol in real world. The results reveal that MP-OLSR is suitable for mobile, large and dense networks with large traffic, and could satisfy critical multimedia applications with high on time constraints.     

Comparison of a static and a dynamic in vitro model to estimate the bioaccessibility of As, Cd, Pb and Hg from food reference materials Fucus sp. (IAEA-140/TM) and Lobster hepatopancreas (TORT-2)

Bioaccessibility, the fraction of an element solubilized during gastrointestinal digestion and available for absorption, is a factor that should be considered when evaluating the health risk of contaminants from food. Static and dynamic models that mimic human physiological conditions have been used to evaluate bioaccessibility. This preliminary study compares the bioaccessibility of arsenic (As), cadmium (Cd), lead (Pb) and mercury (Hg) in two food certified reference materials (CRMs) (seaweed: Fucus sp., IAEA-140/TM; Lobster hepatopancreas: TORT-2), using two in vitro gastrointestinal digestion methods: a static method (SM) and a dynamic multicompartment method (TIM-1). There are significant differences (p < 0.05) between the bioaccessible values of As, Cd, Pb and Hg obtained by SM and TIM-1 in the two CRMs. The specific form in which the elements studied are present in the CRM may help to explain the bioaccessibility values obtained.     

INTERACTIVE SEMANTIC ANALYSIS OF TECHNICAL TEXTS

Sentence syntax is the basis for organizing semantic relations in TANKA, a project that aims to acquire knowledge from technical text. Other hallmarks include an absence of precoded domain-specific knowledge; significant use of public-domain generic linguistic information sources; involvement of the user as a judge and source of expertise; and learning from the meaning representations produced during processing. These elements shape the realization of the TANKA project: implementing a trainable text processing system to propose correct semantic interpretations to the user. A three-level model of sentence semantics, including a comprehensive Case system, provides the framework for TANKA's representations. Text is first processed by the DIPETT parser, which can handle a wide variety of unedited sentences. The semantic analysis module HAIKU then semi-automatically extracts semantic patterns from the parse trees and composes them into domain knowledge representations. HAIKU's dictionaries and main algorithm are described with the aid of examples and traces of user interaction. Encouraging experimental results are described and evaluated.     

Concomitant use of liquid–liquid batch and continuous plug flow reactors for kinetic model discrimination. Application to the Rh/TPPTS catalysed reduction of the C–C double bond in dimethylitaconate

The biphasic catalytic reduction of the C–C double bond of dimethylitaconate with a water soluble rhodium/triphenylphosphinetrisulphonated sodium salt (TPPTS) complex is investigated. Kinetic studies in a well-mixed batch reactor provide kinetics parameters and an activation energy of 71 kJ mol⁻¹ but cannot discriminate between a first order or a complex kinetic model within the range of substrate concentration where the approximation of linear liquid/liquid partition is respected. Catalytic tests in the centrifugal partition chromatograph (CPC) reactor under steady-state operations in chemical regime and plug flow mode allow discriminating the kinetic models, the complex kinetic rate law being preferred.     

混合粉组成对烧结汽车零件尺寸稳定性的影响

粉末冶金工业正面临日益需要高力学强度以及高尺寸稳定性零部件应用的挑战。同步器齿毂、链轮和齿轮就是在汽车工业方面这种应用的例子。粉末冶金烧结零件的尺寸稳定性受许多因素的影响：粉末混合粉组成、添加剂的选择、混合方法、运送、压制、烧结和烧结后处理等。本文评价并量化了这样一些因素的影响，即混合料组成和添加剂类型对高性能材料制成的零件的尺寸稳定性的影响。使用统计学工具分析了影响尺寸稳定性的重要参数。并量化了其造成的影响。     

Photo-oxidation in an O2 atmosphere: A powerful tool to elucidate the mechanism of UV-visible light oxidation of polymers - Application to the photodegradation of MDMO-PPV

This article describes a new approach to improve the analysis of the chemical modifications that result from the degradation of polymers under UV-visible light exposure in the presence of oxygen. The tool which is used consists of an irradiation chamber whose atmosphere is composed of ¹⁸O₂. The ¹⁸O₂ pressure inside the chamber and the hygrometry can be adjusted. In this study, particular attention was paid to the photo-oxidation of poly[2-methoxy-5-(3′,7′-dimethyloctyloxy)-1,4-phenylenevinylene] (MDMO-PPV). Using infrared spectroscopy, irradiation under the oxygen 18 atmosphere allowed discrimination between compounds formed via fixation of oxygen from the atmosphere and those formed by reorganisation of the matrix. In addition, irradiation of MDMO-PPV in an ¹⁸O₂ wet atmosphere allowed for detection of the presence of phenyl formate and aromatic ketone functions. This permitted validating the mechanism of photo-oxidation previously proposed. Additionally, with regard to blends made with MDMO-PPV and methano-fullerene[6,6]-phenyl C₆₁-butyric acid methyl ester ([60] PCBM), it was demonstrated that this technique facilitates the identification of the photo-oxidation products formed.     

Spatial encoding in domestic cats (Felis catus).

Four experiments were performed to identify the spatial information that cats used to encode the position of an object they saw move and disappear. In Experiment 1 and 2, several sources of allocentric spatial information were manipulated. Results indicated that the cats used none of these sources and instead relied primarily on their own spatial coordinates (pure egocentric information) to locate the hidden object. In Experiment 3 and 4, pure egocentric information was made unreliable by a detour task. Results showed that the cats encoded a metric source of allocentric spatial information—the relationship between the walls of the room and the hiding place. Together, these results reveal that cats' encoding of spatial information is flexible and adapted to various kinds of situations that can be encountered in the natural environment. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Effect of artificial perspiration and cleaning chemicals on the mechanical and chemical properties of ballistic materials

During routine field use of soft body armor, the ballistic panels become saturated with perspiration. This condition motivates the user to clean and/or deodorize the armor, and anecdotal evidence is given for various methods used to accomplish this. Although the cleaning/deodorization is usually performed on the armor liners and coverings, there is concern that the chemicals could seep into the ballistic panels and damage the fibers. The purpose of this study was to assess the effect of artificial perspiration and cleaning chemicals on the mechanical and chemical properties of aramid, poly(p‐phenylene benzobisoxazole), and ultrahigh‐molecular‐weight polyethylene yarns after controlled cycles of exposure to artificial perspiration and dilute solutions of common cleaning chemicals. It was observed that the effect of the artificial perspiration on the properties of all of the materials tested was the same as that of water alone. Of all of the cleaning chemicals used, only chlorine bleach had a detrimental effect on the yarn properties. All other cleaning chemicals had the same effect as water alone. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009