Effect of the graft yield of maleic anhydride on the rheological behaviors,mechanical properties,thermal properties,and free volumes of maleic anhydride grafted high‐density polyethylene

The rheological behavior, thermal properties, and molecular mobility of a series of maleic anhydride (MA) grafted high‐density polyethylenes were characterized and evaluated. The rheological behavior was studied with a Haake minilaboratory. The viscosity of the samples in their melt state decreased with an increase in the graft yield, and this could be attributed to the higher molecular mobility for samples with a higher degree of grafting. The thermal properties were investigated with dynamic mechanical analysis and differential scanning calorimetry. Positron annihilation lifetime measurements were used to study the effect of the degree of grafting on the chemical environment and the atomic‐scale free‐volume properties. It was found that the grafted MA group played a significant chemical inhibition role in positronium formation when the graft yield was low. The results also indicated that the higher the degree of grafting was, the broader the free‐volume distribution was. The relationship between the microstructure and rheological behavior is discussed. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Synthesis and structural characterization of methacrylic acid/octadecyl acrylate‐graft‐poly(methylhydrosiloxane) by hydrosilylation

Methylmethacrylate (MMA) and octadecyl acrylate (OA) were grafted to poly(methylhydrosiloxane) (PMHS) by hydrosilylation, respectively, with hexachloroplatinic acid as catalyst, and the former was further hydrolyzed to prepare methacrylic acid (MAA)‐graft‐PMHS under the alkaline condition. Through orthogonal experiment, main factors affecting the graft reaction between OA and PMHS were discussed and arranged in a decreasing order according to their abilities of the effect on the hydrosilylation of OA with PMHS: catalyst dosage, reaction temperature, reaction time, material ratio, and solvent dosage. It was found that the hydrosilylation of OA with PMHS was easier to that of MMA with PMHS. Under optimal conditions, the grafting ratios of MMA with PMHS and OA with PMHS reached about 90 and 95%, respectively. FTIR and ¹H NMR spectra indicated that the hydrosilylation reactions followed the Markovnikov's rule and played a strong preference toward β‐1,2‐addition. The test of contact angle indicated that surface energy of a system was mainly dependent on the polar groups. The surface energy of OA‐graft‐PMHS (35.07 mN/m) was similar to those of PMHS (35.62 mN/m) and polyoctadecyl acrylate (36.57 mN/m), and lower than that of MAA‐graft‐PMHS (43.50 mN/m). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

Accelerated wear testing with a microfabricated surface to evaluate the lubrication ability of biomolecules on polyethylene

Wear of ultrahigh‐molecular‐weight polyethylene (UHMWPE) and wear‐particle‐induced osteolysis and bone resorption are the major factors causing the failure of total joint replacements. It is feasible to improve the lubrication and reduce the wear of artificial joints. We need further understanding of the lubrication mechanism of the synovial fluid. The objective of this study is to evaluate the lubricating ability of three major components in the synovial fluid: albumin, globulin, and phospholipids. An accelerated wear testing procedure in which UHMWPE is rubbed against a microfabricated surface with controlled asperities has been developed to evaluate the lubrication behavior. An analysis of the wear particle dimensions and wear amount of the tests has provided insights for comparing their lubrication performance. It is concluded that the presence of biomolecules at the articulating interface may reduce friction. A higher concentration of a biological lubricant leads to a decrease in the wear particle width. In addition, in combination with the wear results and mechanical analysis, the roles of individual biomolecules contributing to friction and wear at the articulating interface are discussed. These results can help us to identify the role of the biomolecules in the boundary lubrication of artificial joints, and further development of lubricating additives for artificial joints may be feasible. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

转炉脱磷效果影响因素分析

从氧气顶吹转炉脱磷的热力学分析入手,探讨了冶炼过程中温度、炉渣碱度、(FeO)对磷含量的影响,回磷的原因、影响因素及防止措施等,指出应控制炉渣碱度、终点温度、(FeO)在合理范围内,应重视钢水回磷问题。     

建筑结构施工图设计常见质量问题分析

为贯彻落实国务院关于建设工程施工图设计文件审查制度,确保建设工程勘察设计质量,全国各地对建筑工程施工图设计进行了认真审查,特别是对结构设计施工图审查更为严格。工程结构设计施工图审查的重点是结构安全和强制性标准执行情况。经过审查发现,施工图一次性审查合格率不高,原因是建设结构施工图设计中违反国家强制性标准的情况较为普遍。究其原因,既有由于设计人员频于赶任务没有认真校审而出现的设计质量“通病”,诸如“错、漏、碰、撞”等问题,也有设计人员结构概念模糊,对强制性标准条文理解不深或未予高度重视等造成的严重错误。本…     

影响GPS水准高程的因素及高程拟合方法的探讨

在简单介绍高程系统的基础上，对影响GPS高程精度的几何水准联测误差、卫星分布不对称、星历误差、多路径误差等因素逐一进行了分析，并提出了相应的改进措施。同时，还对高程拟合使用的稳健估计方法进行了探讨。     

丰满流域可能最大暴雨与可能最大洪水分析研究

依据丰满漉域的水文气象资料,计算丰满流域可能最大暴雨,推求白丰区间的可能最大洪水并进行成果合理性分析.     

Thermokinetics of Liquid-Liquid Reaction of Dy（NO3 ）3 with Histidine

The thermokinetics of liquid-liquid reaction of dysprosium nitrate with histidine were studied using a microcalorimeter. On the basis of experimental and calculated results, threethermodynamic parameters (the activation enthalpy, the activation entropy and the activation free enegy),the rate constant, three kinetic parameters (the activation energy, the pre-exponential constant and the reaction order) wereobtained. On the basis of thermodynamics and kinetics, the for marion reaction of the complex was discussed.     

MC^2电缆介质结构及阻抗分析

本文将用数学和实验两种方法证实MC～2电缆不仅能保证特性阻抗变化不超出电缆技术规范。而且能保证在设计频率范围内电缆结构反射损耗最小。