Preparation of phenolic resin derived 3-D ordered macroporous carbon

Three-dimensionally ordered long-range macroporous carbon structures were prepared using commercially available phenolic resin by utilizing sacrificial colloidal silica crystalline arrays as templates that were subsequently removed by HF etching after pyrolysis in an argon atmosphere. SEM, TEM, and BET were employed to characterize the morphology and the surface area of the porous carbon structures. The pore size (150–1000 nm) and BET surface area, which reflect pore volume (298.6 m²/g (1.32 cm³/g) ∼ 93.7 m²/g (0.12 cm³/g)), of the macroporous carbon structures produced were approximately proportional to the size (150–1000 nm) of the sacrificial silica sphere templates used (annealing temp. 550°C). The achieved 550 nm porous carbon structures were examined to function as potential catalyst carriers and were successfully impregnated with Ag or Pt-Ru on their inner walls after borohydride reduction at room temperature. In addition, porous carbon patterns were fabricated using the ‘micromolding in capillary’ technique, which has potential applications in the microreaction technology.     

悬浮液进样-火焰原子吸收光谱法测定茶叶中的微量铬

将茶叶悬浮于琼脂胶体中制成悬浮液 ,直接喷入空气 -乙炔火焰 ,用火焰原子吸收光谱法测定茶叶中的微量铬 ,方法简便、快速、灵敏度和精密度高、测定结果与用灰化法处理样品一致 ,检验表明 ,两种样品前处理方法之间无显著性差异。相对标准偏差为 3.4 %～ 6 .1% ,加标回收率为 95 .7%～ 10 3.8 %。     

心理资本前因变量研究

采用心理资本问卷对分别属于医药、建筑、水利工程、电信、通讯运营和服务行业的6家企业的员工进行了调查.根据对回收的283份有效问卷的统计分析,认为员工的性别、受教育程度和所在企业的性质对员工心理资本不会产生显著性影响,而员工年龄的影响显著,50岁以上员工的总体心理资本水平高于其他年龄段员工.     

Deformation and failure study of surrounding rocks of dynamic pressure roadways in deep mines

In order to understand the change rules of stress-displacement in surrounding rocks of dynamic pressure roadways in deep mines and to obtain a theoretical basis for analyses of roadway stability and designs of support,we established a coupling equation of adjacent rock strength,mining stress and supporting resistance on the basis of an elastic-plastic theory of mechanics.We obtained an analytical solution for stress and displacement distribution of elastic and plastic regions in surrounding rock of dynamic pressure roadway..Based on this theory,we have analyzed the changes in stress-displacement in elastic and plastic regions of surrounding rocks of dynamic pressure roadways in the Haizi Coal Mine.The results show that:1) radial and tangential stress change violently within the first 4 m from the inner surface of a roadway after excavation;radial stress increases while tangential stress decreases within a range of about 6 m from the inner surface of the roadway as a function of q3;2) radial and tangential stress increase with an increase in the mining pressure coefficient k;the increase in the rate of tangential stress is greater than that of radial stress;3) the radial displacement of the inner surface of roadways decreases with an increase in q3,provided that k remains unchanged.     

Fabrication and characterization of nano silver powder prepared by spray pyrolysis

Silver powder was fabricated by spray pyrolysis, using 2%–20% AgNO₃ solution, 336–500 mL/h flux of AgNO₃ solution, 0.28–0.32 MPa flux of carrier gas and in the 620–820 °C temperature range. The effects of furnace set temperature, concentration of AgNO₃ aqueous solution, flux of AgNO₃ aqueous solution as well as carrier gas on the morphology and particle size distribution of silver powder, were investigated. The experimental results showed that with the high concentration of AgNO₃ aqueous solution, the average grain size of silver decreased with the increasing of furnace set temperature. But the gain size distribution was not homogenous, the discontinuous grain growth occurred. With the low concentration of AgNO₃ aqueous solution, the higher furnace set temperature made the nano sliver grains sintered together to grow. Nano silver powder about 100 nm was fabricated by spray pyrolysis, using 2wt% AgNO₃ solutions, 336 mL/h flux of AgNO₃ aqueous solution, 0.32 MPa flux of carrier gas at 720 °C furnace set temperature.     

电磁领域中复超越方程的遗传算法求解方法

将遗传算法与参数跟踪策略有效结合,跟踪过程中进行搜索域压缩与位移操作,形成了一种功能强大的新算法,可成功应用于电磁领域中各种各样复超越方程的高精度求解问题.在算法实现过程中,使用参数跟踪策略有效地缩小了搜索区域,保证了解的单一性,提高了运算速度;使用动态搜索域提高了解的精度;应用三阶差商公式预估新的搜索中心,使运算速度得以进一步提高.应用本文发展的算法详细求解了终端短路法测量材料的复介电常数时得到的复超越方程和部分填充矩形波导的特征方程,计算结果表明该算法能够轻松地解决复超越方程中的多值问题,解集完备性好,算法鲁棒性强.     

Electroless nickel plating on the surface of carbon fibers

The electroless nickel plating on the surface of carbon fibers was prepared by pretreating the carbon fibers in order to increase their conductivity,and consequently enhance the EMI shielding effectiveness of the composites.The relationship between the performance of depositing coat and pH value,temperature,reaction time and the way of agitation was studied.Results show that the depositing quality is stable under pH between 4.5 and 5.0,temperature between 75 ℃ and 85 ℃,reaction time for 10 min and air agitation.The uniform and compact nickel layer deposited on carbon fibers was proved by XRD and SEM,and the electrical resistivity of carbon fibers with nickel coating was tested.Results indicate that the electrical resistivity of carbon fibers with electroless nickel plating is decreased by an order of magnitude compared with that of carbon fibers.It means that nickel coating can greatly improve the electromagnetic interference shielding properties of carbon fibers.     

Zonal disintegration phenomenon in enclosing rock mass surrounding deep tunnels -- Elasto-plastic analysis of stress field of enclosing rock mass

The zonal disintegration phenomenon (ZDP) is a typical phenomenon in deep block rock masses. In order to investigate the mechanism of ZDP, an improved non-linear Hock-Brown strength criterion and a bi-linear constitutive model of rock mass were used to analyze the elasto-plastic stress field of the enclosing rock mass around a deep round tunnel. The radius of the plastic region and stress of the enclosing rock mass were obtained by introducing dimensionless parameters of radial distance. The results show that tunneling in deep rock mass causes a maximum stress zone to appear in the vicinity of the boundary of the elastic and the plas-tic zone in the surrounding rock mass. Under the compression of a large tangential force and a small radial force, the rock mass in the maximum stress zone was in an approximate uniaxial loading state, which could lead to a split failure in the rock mass.     

自激振荡脉冲射流的研究与进展

指出了自激振荡脉冲射流的产生机理,概述了国内外主要的研究和应用成果,并对这些成果进行分析后指出：目前的研究方法主要基于经验,基于理论或基于方法;目前主要的应用领域为石油钻井、油罐清淤和渔业充氧等.最后对进一步研究的方向和应用的领域作出了展望,可为相关研究参考.     

制备温度和压力对纳米氧化锆相组成的影响

利用压力[CD*2/3]热液法制备纳米氧化锆粉体,考察不同温度和压力下的制备工艺条件,以及采用XRD分析经过热处理后粉体的相组成和晶粒的长大倾向.结果表明,制备出的氧化锆粉体平均粒径约15 nm,粉体在600℃、800℃、1 000℃热处理1 h后,晶粒随温度长大趋势较小,抗老化能力较好.