全文获取类型
收费全文 | 1621篇 |
免费 | 35篇 |
国内免费 | 8篇 |
专业分类
电工技术 | 143篇 |
综合类 | 5篇 |
化学工业 | 431篇 |
金属工艺 | 67篇 |
机械仪表 | 38篇 |
建筑科学 | 31篇 |
矿业工程 | 5篇 |
能源动力 | 26篇 |
轻工业 | 91篇 |
水利工程 | 3篇 |
石油天然气 | 7篇 |
无线电 | 110篇 |
一般工业技术 | 327篇 |
冶金工业 | 184篇 |
原子能技术 | 64篇 |
自动化技术 | 132篇 |
出版年
2022年 | 13篇 |
2021年 | 15篇 |
2020年 | 15篇 |
2019年 | 17篇 |
2018年 | 22篇 |
2017年 | 14篇 |
2016年 | 17篇 |
2015年 | 27篇 |
2014年 | 32篇 |
2013年 | 95篇 |
2012年 | 49篇 |
2011年 | 71篇 |
2010年 | 59篇 |
2009年 | 66篇 |
2008年 | 98篇 |
2007年 | 67篇 |
2006年 | 59篇 |
2005年 | 49篇 |
2004年 | 53篇 |
2003年 | 40篇 |
2002年 | 33篇 |
2001年 | 45篇 |
2000年 | 33篇 |
1999年 | 32篇 |
1998年 | 74篇 |
1997年 | 59篇 |
1996年 | 47篇 |
1995年 | 36篇 |
1994年 | 36篇 |
1993年 | 34篇 |
1992年 | 17篇 |
1991年 | 15篇 |
1990年 | 16篇 |
1989年 | 17篇 |
1988年 | 20篇 |
1987年 | 28篇 |
1986年 | 25篇 |
1985年 | 19篇 |
1984年 | 23篇 |
1983年 | 24篇 |
1982年 | 24篇 |
1981年 | 21篇 |
1980年 | 27篇 |
1979年 | 24篇 |
1978年 | 17篇 |
1977年 | 6篇 |
1976年 | 14篇 |
1974年 | 5篇 |
1970年 | 3篇 |
1969年 | 2篇 |
排序方式: 共有1664条查询结果,搜索用时 0 毫秒
51.
Study on dominant mechanism of high-cycle fatigue life in 6061-T6 aluminum alloy through microanalyses of microstructurally small cracks 总被引:1,自引:0,他引:1
Yoshimasa Takahashi Takahiro Shikama Shinji Yoshihara Tadashi Aiura Hiroshi Noguchi 《Acta Materialia》2012,60(6-7):2554-2567
The mechanism controlling the fatigue life of a precipitation-hardened Al–Mg–Si alloy (6061-T6) at a high-cycle fatigue (HCF) regime of over 107 cycles was investigated in detail. It was found that over 90% of the total fatigue life was occupied by the growth process of a microstructurally small crack at relatively low stress amplitude. The small crack was often found to be arrested and halted for a long period (more than 106 cycles) before it began to grow again, which resulted in a significantly slow growth process. The small crack was then analyzed not only by the conventional fractography but also by the cross-sectional observation of the crack tip region using a focused ion beam and transmission electron microscopy. These observations, supplemented also by a grain orientation analysis using electron backscattered diffraction, explicitly revealed the following points: (i) the small crack growth observed on the specimen surface is primarily related to facet-type cracking that occurs exclusively at the specimen surface; (ii) the growth direction of the small crack has strong anisotropy (i.e. surface-induced growth); (iii) the facet-type cracking is related to the formation of persistent fine slip bands that accompany no structural change of the matrix. On the basis of these results, the micromechanism of small crack growth and its relation to the concept of fatigue limit at the HCF regime is discussed in detail. 相似文献
52.
Homogeneous periodate oxidation of cellulose was achieved through methylol cellulose. The dissolution of methylol cellulose into aqueous periodate solution was followed by the gradual decomposition of methylol groups at random sites along the methylol cellulose chain. The recovery of glycol hydroxyl groups at the C2 and C3 positions on the glucopyranose ring during the above decomposition process caused uniform cleavage of C2? C3 bonds by the periodate ion. The oxidation level reached nearly 100% in 10 h. The reduced product of the resulting dialdehyde cellulose, i.e., dialcohol cellulose, resulted in mechanical properties quite different from those of conventional dialcohol cellulose. Examination of the thermal deformation and tensile properties revealed that no notable cellulose degradation occurred during the reaction. Our dialcohol cellulose gave a clear and transparent film with a flexible nature. 相似文献
53.
Production of eicosapentaenoic acid by a recombinant marine cyanobacterium, Synechococcus sp. 总被引:1,自引:0,他引:1
The eicosapentaenoic acid (EPA) synthesis gene cluster from an EPA-producing bacterium, Shewanella sp. SCRC-2738, was cloned into a broad-host range vector, pJRD215, and then introduced into a marine cyanobacterium, Synechococcus sp. NKBG15041c, by conjugation. The transconjugant cyanobacteria produced 3.7±0.2% (2.24±0.13 mg/L) EPA (n-3) and 2.5 ±0.2%
(1.49±0.06 mg/L) eicosatetraenoic acid (n-3) of the total fatty acids when the cells were cultured at 23°C at a light intensity
of 1,000–1,500 Lux. The EPA and eico-satetraenoic acid contents of the cells were increased to 4.6±0.6% (3.86±1.11 mg/L) and
4.7±0.3% (3.86±0.82 mg/L), and 7.5±0.3% (1.76±0.10 mg/L) and 5.1±0.2% (1.19±0.06 mg/L) when they were cultured at low temperature
(18°C) and at lower light intensity (40 Lux), respectively. 相似文献
54.
Tomoharu Suzuki Shigeru Oshio Mari Iwata Hisayo Saburi Takashi Odagiri Tadashi Udagawa Isamu Sugawara Masakazu Umezawa Ken Takeda 《Particle and fibre toxicology》2010,7(1):1-8
Background
Epidemiological studies suggest that inhalation of carbonaceous particulate matter from biomass combustion increases susceptibility to bacterial pneumonia. In vitro studies report that phagocytosis of carbon black by alveolar macrophages (AM) impairs killing of Streptococcus pneumoniae. We have previously reported high levels of black carbon in AM from biomass smoke-exposed children and adults. We therefore aimed to use a mouse model to test the hypothesis that high levels of carbon loading of AM in vivo increases susceptibility to pneumococcal pneumonia.Methods
Female outbred mice were treated with either intranasal phosphate buffered saline (PBS) or ultrafine carbon black (UF-CB in PBS; 500 μg on day 1 and day 4), and then infected with S. pneumoniae strain D39 on day 5. Survival was assessed over 72 h. The effect of UF-CB on AM carbon loading, airway inflammation, and a urinary marker of pulmonary oxidative stress was assessed in uninfected animals.Results
Instillation of UF-CB in mice resulted a pattern of AM carbon loading similar to that of biomass-smoke exposed humans. In uninfected animals, UF-CB treated animals had increased urinary 8-oxodG (P = 0.055), and an increased airway neutrophil differential count (P < 0.01). All PBS-treated mice died within 72 h after infection with S. pneumoniae, whereas morbidity and mortality after infection was reduced in UF-CB treated animals (median survival 48 h vs. 30 h, P < 0.001). At 24 hr post-infection, UF-CB treated mice had lower lung and the blood S. pneumoniae colony forming unit counts, and lower airway levels of keratinocyte-derived chemokine/growth-related oncogene (KC/GRO), and interferon gamma.Conclusion
Acute high level loading of AM with ultrafine carbon black particles per se does not increase the susceptibility of mice to pneumococcal infection in vivo. 相似文献55.
Thermosensitive 4VP‐NIPAAm‐4G copolymer beads containing pyridyl groups were first prepared by suspension copolymerization of 4‐vinylpyridine (4VP), N‐isopropylacrylamide(NIPAAm), and tetraethylene glycol dimethacrylate (4G; crosslinking reagent) in a saturated Na2SO4 aqueous solution in the presence of surfactant and MgCO3 as dispersants. Then the copolymer beads containing pyridinium groups were obtained by the quaternization of the copolymer beads with various alkyl iodides (CH3I, C4H9I, C8H17I) in N,N‐dimethylformamide. The 4VP‐NIPAAm‐4G (15 : 97 : 3) copolymer bead and the 4VP‐NIPAAm‐4G copolymer beads quaternized with butyl iodide exhibited high thermosensitivity in water, although the 4VP‐NIPAAm‐4G copolymer beads quaternized with methyl iodide or octyl iodide hardly exhibited thermosensitivity. All the quaternized copolymer beads exhibited antibacterial activity against Escherichia coli (E. coli), although the 4VP‐NIPAAm‐4G copolymer bead did not. In particular, the copolymer bead quaternized with butyl iodide exhibited the highest antibacterial activity against E. coli at 30°C. It was also found that the antibacterial activity of the quaternized 4VP‐NIPAAm‐4G copolymer beads was greatly affected by not only chain length of alkyl groups in alkyl iodides, with which the 4VP‐NIPAAm‐4G copolymer beads were quaternized, but also by temperature of the solutions. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
56.
Mamoru Ishida Takeo Uehara Toshio Arai Hideki Takeda Tadashi Yamaguchi Takeshi Taniguchi Tetsuya Katsumi Masayuki Kobayashi Hitoshi Ofune 《Intermetallics》2002,10(11-12)
The performance of MU/SC conversion sleeve produced by bulk metallic glass (Zr55Al10Ni5Cu30) was examined. A precision die-casting method was applied to improve size accuracy. The size accuracy of the conversion sleeve produced by the precision die-casting method was ±1 μm, and optical insertion loss (Li) was less than 0.3 dB for a standard value. The wear resistance of metallic glass is improved by surface oxidation treatment in air at 673 K. The MU/SC conversion sleeve produced from bulk metallic glass has superior characteristics for optical parts. 相似文献
57.
Shinya Inai Yuji Hiruma Muneyasu Suzuki Hajime Nagata Tadashi Takenaka 《Ceramics International》2008,34(4):741-744
The temperature dependence of the piezoelectric properties of vanadium substituted strontium bismuth niobate, SrBi2Nb1.95V0.05O9 (SBNV) ceramics, were investigated in various vibration modes. The effects of grain orientation in SBNV ceramics on the piezoelectric properties were also studied by the hot-forging (HF) method. The anisotropy of the piezoelectric properties of each vibration mode was confirmed by observing the grain orientation. In particular, HF-SBNV ceramics of the (33) and (15) modes showed excellent piezoelectric properties with relatively high mechanical quality factors, Qm (2200, 4600), and high electrical quality factors, Qe max (66.0, 21.6), respectively. In addition, HF-SBNV ceramics showed low temperature coefficients of resonance frequency TC-fr (−16.5, −27.0). HF-SBNV ceramics are considered to be superior candidates for the lead-free piezoelectric application of ceramic resonators. 相似文献
58.
Yoshihisa Matsushita Nobuko Ohba Tadashi Suzuki Teijiro Ichimura 《Catalysis Today》2008,132(1-4):153-158
A photocatalytic microreaction system was developed and photocatalytic N-alkylation process of benzylamine, aniline, and piperidine was examined. The reaction proceeded quite rapidly in the microreactors with immobilized Pt-free TiO2 as well as Pt-loaded TiO2, while it has been reported that the N-alkylation did not occur by the irradiation of Pt-free TiO2 in conventional batch reactors. It was revealed that by using the unique features of the continuous-flow microreactor, for instance spatial illumination homogeneity and precise control of flow and irradiation conditions, one can control the selectivity of N-alkylation and N,N-dialkylation processes. These results suggest the possibilities of a photocatalytic microreaction system on organic synthetic reactions. 相似文献
59.
Tomiko M. Suzuki Tadashi Nakamura Eiichi Sudo Yusuke Akimoto Kazuhisa Yano 《Microporous and mesoporous materials》2008,111(1-3):350-358
A new type of sulfonic acid-functionalized monodispersed mesoporous silica spheres (MMSS) were synthesized directly by co-condensation and subsequent oxidation. By changing the methanol ratio, sulfonic acid-functionalized MMSS with different particle diameters (390–830 nm) and the same mesopore sizes were successfully synthesized. TEM observations revealed that the mesopores were aligned radially from the center towards the outside of the spheres, even in the sulfonic acid-functionalized MMSS. The catalytic activities of the sulfonic acid-functionalized MMSS were studied in condensation reactions between 2-methylfuran and acetone, and it was found that their catalytic activities are highly dependent on the particle diameters. In addition, the catalytic activity of MMSS was much higher than that of other forms of mesoporous silica due to its radially-aligned mesopores. 相似文献
60.
The objective is to characterize the effects of the bimodal distribution of rubber particles and its blend ratio on the mechanical properties of the thermoplastic polypropylene blended with two different styrene‐ethylene‐butadiene‐styrene triblock copolymer at the intermediate and high strain rates. Tensile tests are conducted at the nominal strain rates from 3 × 10?1 to 102 (1/s). Phase morphology is investigated to estimate the bimodal rubber particle size distribution. In addition, the in situ observation is conducted during uniaxially stretching within transmission electron microscopy step by step to investigate the deformation events depending on the elongation of samples. The elastic modulus increased gradually as the blend ratio of large rubber particle increased. An increase in the rupture strain and the strain energy up to failure was found for the bimodal rubber particle distributed blend system where the blend ratios of small rubber particle and large rubber particle were same. This is because the smaller particles dominant blend systems show the bandlike craze deformation while the localized plastic deformation is taken place in the larger particles dominated blend systems. The synergistic effect of these rubber particles gives rise to a strong increase in the ductility of these bimodal rubber particle distributed polypropylene systems. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献