高负荷轴流压气机内以氦-氙混合气为工作介质的评估（英文）

本文评价了分子量为15g/mole的氦-氙双项混合气体作为流动工质在核电厂轴流压气机的应用。由于纯氦具有普遍的传输特性,在很多情况下很难被压缩,因此是一种最佳的冷却剂。同时,纯氦工质在高温气冷堆(HTGR)的应用引起了涡轮机械的尺寸更大、质量越来越大、成本更高及叶轮机械的动力问题。为此,本文设计了一台高负荷氦氙压气机,并对其性能进行了分析。结果显示,只有18%的氦气压气机级需要在高负荷氦气-氙气压气机中将气体压缩至所需压力。通过设计分析,工作在闭式布雷顿循环(CBC)中高温气冷堆(HTGR)压气机,可由16级减少到2级。因此,在高温气冷堆电厂的涡轮压压气中,氦氙比纯氦更有优势。     

Synthesis of composite material of cobalt oxide (Co3O4) with hydroxide functionalized multi-walled carbon nanotubes (MWCNTs) for electrochemical determination of uric acid

The gout is mainly found due to accumulation of uric acid crystals into the joints which produces the inflammatory symptoms. Thus, it is highly demanded to detect uric acid from our body. Herein, we prepare a composite material of cobalt oxide (Co₃O₄) with hydroxide functionalized multi-walled carbon nanotubes (MWCNTs) by hydrothermal method. The composite material is used for the modification of glassy carbon electrode (GCE) and investigated for the electrochemical determination of uric acid (UA). The analytical techniques such as scanning electron microscopy (SEM), powder X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and Fourier Infra-red spectroscopy (FTIR) are used to characterize the composite material. The Co₃O₄ exhibits a dendrite morphology and very well chemically coupled with MWCNTs. The elemental analysis confirms the presence of cobalt (Co), oxygen (O) and carbon (C) as main constituent of the composite material. The Co₃O₄ exhibitsa cubic unit cell crystallography in the composite system. The FTIR study reveals the characteristic bands of Co–O bands in the composite material. The cyclic voltammetry isused to study the electrochemical properties of prepared materials. The composite sample with highest percentage of MWCNTs shows an excellent electrochemical activity towards the oxidation of uric acid in phosphate buffer solution pH 7.3. The enzyme free uric acid sensor possesses a linear range of 0.1 mM to 3 mM with a quantified limit of detection of 0.005?±?0.0023 mM. The modified electrode is stable, selective, and very sensitive towards uric acid, therefore it may be used for the monitoring of uric acid from clinical samples. The proposed composite material can be of great interest for energy and biomedical fields.

     

Synthesis and Antimicrobial Activity of p-tetranitrocalix[4]arene Derivative

The present study demonstrates the synthesis and antimicrobial activity of the p-tetranitrocalix[4]arene (3). The microbial activity was determined against a variety of microorganisms, i.e., Gram-positive and Gram-negative bacterial strains such as Staphylococcus aureus ATCC 10231, Streptococcus viridans ATCC 12392, Escherichia coli ATCC 8739, as well as some fungal species including Aspergillus niger ATCC 16404, Aspergillus flavus ATCC 90906, and Candida albicans ATCC 32333. Kirby-Bauer well agar diffusion method was employed for the determination of antimicrobial activity. All the microorganisms were applied to a selective agar medium (Mueller Hinton Agar) for growth. It was observed that compound 3 is considerably effective against selected microorganisms. The MIC values were also evaluated. Thus, from the results it could be deduced that compound 3 may be a valuable addition to the therapeutic index.     

Influence of Nd-Co Substitution on Structural,Electrical, and Dielectric Properties of X-Type Hexagonal Nanoferrites

A series of single phase X-type hexagonal ferrites with concentration Sr_2?x Nd _x Ni₂Fe_28?y Co _y O₄₆ (x = 0.02, 0.04, 0.06, 0.08, 0.10 and y = 0.1, 0.2, 0.3, 0.4, 0.5) has been prepared by sol-gel method sintered at 1250 °C for 6 h. The x-ray diffraction analysis reveals the single phase of X-type hexagonal ferrites. The particle size was calculated by using SEM and TEM. The ferrite substituted with Nd³⁺ and Co²⁺ has average particle size in the range of 40-50 nm. The room temperature electrical resistivity experiences the significant enhancement from a value of 1.1 × 10⁷ to 2.03 × 10⁸ Ωcm with the increase in Nd³⁺ and Co²⁺ concentration. The dielectric constant exhibits high value at low frequencies and decreases with the increase of frequency. The tangent dielectric loss shows the abnormal behavior which can be explained on the basis of hopping between the Fe²⁺ and Fe³⁺ ions on octahedral sites. The maximum value of tangent loss at low frequencies reflects the application of these materials in medium frequency devices (MF).     

Consideration of future safety consequences: A new predictor of employee safety

Background

Compliance with safety behaviors is often associated with longer term benefits, but may require some short-term sacrifices. This study examines the extent to which consideration of future safety consequences (CFSC) predicts employee safety outcomes.

Methods

Two field studies were conducted to evaluate the reliability and validity of the newly developed Consideration of Future Safety Consequences (CFSC) scale. Surveys containing the CFSC scale and other measures of safety attitudes, behaviors, and outcomes were administered during working hours to a sample of 128 pulp and paper mill employees; after revising the CFSC scale based on these initial results, follow-up survey data were collected in a second sample of 212 copper miners.

Results

In Study I, CFSC was predictive of employee safety knowledge and motivation, compliance, safety citizenship behaviors, accident reporting attitudes and behaviors, and workplace injuries – even after accounting for conscientiousness and demographic variables. Moreover, the effects of CFSC on the variables generally appear to be direct, as opposed to mediated by safety knowledge or motivation. These findings were largely replicated in Study II.

Conclusions

CFSC appears to be an important personality construct that may predict those individuals who are more likely to comply with safety rules and have more positive safety outcomes. Future research should examine the longitudinal stability of CFSC to determine the extent to which this construct is a stable trait, rather than a safety attitude amenable to change over time or following an intervention.