Effects of Sesame Oil Addition to Soybean Oil During Frying on the Lipid Oxidative Stability and Antioxidants Contents of the Fried Products During Storage in the Dark

ABSTRACT: Effects of sesame oil addition to soybean oil during frying on the lipid oxidative stability and antioxidants contents of fried products during storage in the dark were studied. Flour dough pieces (2 cm × 2 cm × 0.1 cm) were fried at 160 °C for 1 min in sesame oil-added soybean oil. Concentrations of sesame oil in the frying oil were 0%, 10%, and 20% by volume. Fried products were put into a glass bottle, and the bottles were tightly sealed and stored at 60 °C in the dark for 18 d. Lipid oxidation of fried products was determined by fatty acid composition changes and conjugated dienoic acid (CDA) and p -anisidine (PA) values. Tocopherols and lignan compounds in the fried products were determined by high-performance liquid chromatography. Relative content of linolenic acid decreased, and CDA and PA values increased during storage of the fried products in the dark. Fatty acid composition change and CDA and PA values during storage were lower in the products fried in sesame oil-added soybean oil than in the products fried in soybean oil without sesame oil. The results clearly showed that addition of roasted sesame oil to soybean oil at 10% and 20% during frying decreased the lipid oxidation of fried products during storage in the dark for 18 d by extension of induction period and decrease in decomposition of oxidized lipids. Fried products contained 134 to 267 ppm tocopherols and 0 to 148 ppm lignans before storage; however, their contents decreased during storage in the dark. Lignan compounds were more stable than tocopherols, and the rate of tocopherols degradation was lower in the products fried in sesame oil-added soybean oil than in the products fried in soybean oil without sesame oil, which could be because of protection of tocopherols from degradation by lignan compounds.     

Design and test of a miniature hydrogen production reactor integrated with heat supply,fuel vaporization,methanol-steam reforming and carbon monoxide removal unit

This study presents a designed and tested integrated miniature tubular quartz-made reactor for hydrogen (H₂) production. This reactor is composed of two concentric tubes with an overall length of 60 mm and a diameter of 17 mm. The inner tube was designed as the combustor using Pt/Al₂O₃ as the catalyst. The gap between the inner and outer tubes is divided into three sections: a liquid methanol-water vaporizer, a methanol-steam reformer using RP-60 as the catalyst and a carbon monoxide (CO) methanator using Ru/Al₂O₃ as the catalyst. The experimental measurements indicated that this integrated reactor works properly as designed. The methanol conversion, hydrogen production rate and CO concentration were found to increase with an increasing methanol/air flow rate in the combustor and decreases with an increasing methanol/water feed rate to the reformer. The methanator experimental results indicated that the CO conversion and H₂ consumption can be enhanced by increasing the Ru loading. It was also found that the CO methanation depends greatly on the reaction temperature. With a higher reaction temperature, the CO methanation, carbon dioxide (CO₂) methanation, and reversed water gas shift reactions took place simultaneously. CO conversion was found to decrease while H₂ consumption was found to increase. At a lower reaction temperature both the CO conversion and H₂ consumption were found to increase indicating that only CO methanation took place. From the experimental results the maximum methanol conversion, hydrogen yield, and CO conversion achieved were 97%, 2.38, and 70%, respectively. The actual lowest CO concentration and maximum power density based on the reactor volume were 90 ppm and 0.8 kW/L, respectively.     

Fermentative hydrogen production using a real-time fuzzy controller

This work builds a real-time monitoring and control system for bio-hydrogen production fermentation plants using LabVIEW software. The best fermentation environment factors pH and temperature are successfully estimated with stable control ability to create the best hydrogen production environment. The concentrate molasses fermentation waste is as nutrients to hold biomass hydrogen production by dark fermentation in a continuous stirred anaerobic bioreactor, CSABR. In order to verify the applicability of this system, this study compares the proposed anaerobic bioreactor system which's maximum hydrogen production was 3.12 (L/Day) and the system with the fuzzy controller which's hydrogen production rose to 13.44 (L/Day). The result shows that the proposed fuzzy control can not only control feeding pump and heater operations, but also successfully reduce the energy required for hydrogen production, making sure the growth of micro-organisms is in the best environmental conditions for the best growth rate and raise of the maximum hydrogen production.     

Experimental and numerical studies on periodic convection flow and heat transfer in a lid-driven arc-shape cavity

This paper presents experimental and numerical studies on periodic convection flow and heat transfer in a lid-driven arc-shape cavity with temperature differential. Three cases were considered: Gr = 2 × 10⁵, 5 × 10⁵ and 1.2 × 10⁶ at Re = 100 (Gr = Grashof number; Re = Reynolds number). The mathematical model was proposed in our previous study. The current study performs an experiment to validate this model, to corroborate the existence of the periodic flow, and to more deeply probe the internal flow and temperature characteristics. The experimental setup primarily comprised an arc-shape cavity, a moving lid, a thermo-system, a smoke generator and an image acquisition system. The periodic convection flow in the cavity was visualized using kerosene smoke. The numerical and experimental results consistently reveal that the periodic flow pattern was observed in the case with Gr = 5 × 10⁵, whereas the steady-state flow pattern took place in the other two cases (Gr = 2 × 10⁵ and Gr = 1.2 × 10⁶). The numerical simulation produced reasonable and satisfactory agreement with the experiment for the periodic flow pattern and period. The difference between the predicted and measured periods is less than 5%. The transport properties, such as average kinetic energy, overall Nusselt number, stream function, phase space trajectory, local kinetic energy, velocity history and temperature distribution, were further analyzed and discussed in this paper. The proposed numerical simulation not only confirms the experimental observation, but also enhances the understanding of periodic convection in an arc-shape cavity subjected to a moving lid and temperature differential.     

Browning characteristics of fresh-cut ‘Tsugaru’ apples as affected by pre-slicing storage atmospheres

The change in browning characteristics of the slices processed from ‘Tsugaru’ apples stored at 0 °C for 5 months under controlled atmosphere (CA, 1 kPa O₂ + 1 kPa CO₂, 3 kPa O₂ + 3 kPa CO₂) or air has been investigated for 5 days at 20 °C. Respiration and ethylene production of the slices from apples stored in CA were retarded. Electrolyte leakage and browning index were lower in the slices from apples stored under CA than air. Vitamin C and phenolic contents in the slices from apples stored under air were maintained at higher level compared to the slices from apples stored under CA. Polyphenol oxidase activity in the slices was not affected by pre-slicing storage atmospheres. Therefore, the atmospheres of pre-slicing storage affected browning development in fresh-cut products of ‘Tsugaru’ apples and browning was found to be correlated with the levels of electrolyte leakage and phenolic compounds.     

The efficient lignocellulose-based sorbent for oil spill treatment from polyurethane and agricultural residue of Vietnam

In this study, new and efficient sorbent with density 0.2 g/cm³ was fabricated by incorporating rice straw into polyurethane matrix to get an open cell structure material with high oil uptake capacity. The influences of various important factors such as amount of adding rice straw, size of rice straw particles, and adsorption time on oil adsorption capacity of new sorbent material were investigated. The results showed that the oil absorption rate occurred fast in first 15–30 min, then slowed down and reached saturation level after about 2 h of treatment. Oil adsorption capacity of the new sorbent material was relatively high, up to 12.0 g/g. In comparison with pristine polyurethane or lignocellulosic materials, the new sorbents had higher oil adsorption capacity. Some characteristics of the as-obtained sorbent, such as surface shapes and porosity, were also studied by SEM analysis.     

Exposure assessment of caffeine in children’s snacks in Korea

This study was conducted to develop an appropriate management strategy for the safe consumption of children’s snacks. In this study, a caffeine content analysis was performed on children’s snacks which were distributed at stores located near to schools. A total of 213 samples (63 chocolates, 40 ice cakes, 19 canned instant coffees, and 91 beverages) were analyzed for caffeine content. The caffeine content of chocolates, ice cakes, canned instant coffees, and beverages was 94.30, 35.03, 391.78, and 68.32 mg/kg, respectively. The results of the exposure assessment for caffeine were expressed as estimated daily intake (EDI) compared to the acceptable daily intake (ADI). The EDI/ADI ratio of the high risk group (95^th percentile) for caffeine intake was 7.63–27.13 %. The results of this study indicate that the EDI of caffeine from snacks sold at stores located near to schools is much lower than the ADI in general. Consequently, children’s snacks are thought to be safe for consumption.     

Effects of rumen-protected choline and dry propylene glycol on feed intake and blood parameters for Holstein dairy cows in early lactation

A 6 × 6 Latin square design was used to test 3 sets of comparisons simultaneously to study response in dry matter intake, milk yield, and blood parameters to propylene glycol (PG) supplementation delivered by 2 methods [incorporating PG into the total mixed ration (TMR) vs. top dressing; comparison I]; individual or combined dietary choline and PG supplementation as a 2 × 2 factorial (comparison II); or increasing amounts of dietary choline (comparison III). Six multiparous (lactation number = 1.5 ± 0.8 SD) Holstein dairy cows were at 41 d in milk (± 9 SD) at the start of the experiment. Propylene glycol used was a dry product containing 65% PG, and choline was a rumen-protected choline product (RPC; estimated to be 50% rumen-protected) containing 50% choline chloride. In comparison I, treatments compared were 1) control: no PG; 2) PG-TMR: 250 g/d of dry PG (corresponding to 162.5 g/d of PG) incorporated into the TMR; and 3) PG-top dress: 250 g/d of dry PG top-dressed onto the TMR. In comparison II, treatments compared were 1) control: no PG and no RPC; 2) PG: 250 g/d of dry PG incorporated into the TMR; 3) RPC: 50 g/d of RPC top-dressed onto the TMR; and 4) PG + RPC: combination of treatments 2 and 3. In comparison III, treatments compared were 0, 25, and 50 g/d of RPC top-dressed onto the TMR. Each experimental period lasted 10 d with 9 d of adaptation followed by 1 d of serial blood sampling. Dry matter intake and milk yield were recorded daily. During the serial blood sampling, jugular blood was sampled every 20 min for the first 4 h and at 8 and 12 h after treatment administration. Results obtained from comparison I showed that feeding 250 g/d of PG as a dry product decreased plasma β-hydroxybutyrate (BHBA) concentration (mean ± SEM) from 701 ± 81 (control) to 564 ± 76 μmol/L without affecting serum insulin, plasma glucose, or plasma nonesterified fatty acid concentrations. Top-dressing PG decreased plasma BHBA concentrations more than by incorporating it into the TMR [527 vs. 601 μmol/L (± 81 pooled SEM)]. Results obtained from comparison II showed that supplementing choline as RPC, PG, or both had no effect on dry matter intake, milk yield, or any of the blood parameters measured. Results obtained from comparison III showed that milk yield tended to increase linearly with increasing amounts of dietary choline as RPC. We concluded that feeding PG as a dry product reduced plasma BHBA concentration but top-dressing PG was more efficient at reducing plasma BHBA level than incorporating PG into the TMR. Dietary choline as RPC tended to increase milk yield linearly. However, a combined effect of dietary PG and choline was not evident and therefore not beneficial.     

Dextran-like exopolysaccharide-producing Leuconostoc and Weissella from kimchi and its ingredients

Dextran-like exopolysaccharide (EPS)-producing lactic acid bacteria were isolated from kimchi and its ingredients. Analysis of 16S rRNA genes (500–600 bp) of 158 isolates revealed that dextran-like EPS-producing strains were most similar to either Leuconostoc or Weissella. The gene sequence analysis of the strains revealed a similarity to Leuconostoc mesenteroides and Weissella confusa in the samples. The molecular masses of dextranlike polymers from the most isolated Leuconostoc and Weissella strains were 1,176 and 1,158 kDa, respectively. Fourier transform infrared analysis of these polymers showed a similarity to the structure of commercial dextran from Leu. mesenteroides B-512F.     

Axial heat conduction and heat supply effects on methanol-steam reforming performance in micro-scale reformers

The methanol-steam reforming (MSR) performance in micro-scale tubular reformers made by various materials is numerically studied. The physical domain considered includes an inlet section for methanol-steam mixture supply, a reformer section packed with CuO/ZnO/Al₂O₃ catalyst particles and an outlet section for reformed gas collection. The heat transfer effect with three different heat supply mechanisms on the MSR performance is addressed. For heat supplies from the applied heat fluxes at the reformer outer wall surface and from internal heat generation in the reformer wall, it is found that the axial conduction plays an important role in both heat transfer characteristics and MSR performance. It is suggested that the reformer have a small axial conduction parameter for high MSR performance which can be achieved by designing the reformer with low wall thermal conductivity, thin wall thickness and a small reactants feed rate. It is also found that an excess heat supply can be obtained when the axial conduction parameter is small. This excess heat supply enhances the MSR performance compared with the infinitely-thin walled reformer. For the reformer with a constant wall outer surface temperature, the wall material effect on the MSR performance is insignificant due to uniformly distributed reformer wall temperature.