11B NMR Study of Pure and Lightly Carbon-Doped MgB2 Superconductors

We report a ¹¹B NMR line shape and spin-lattice relaxation rate (1/(T₁T))(1/(T_1T)) study of pure and lightly carbon-doped MgB_2-xC_x_{2-x}{\rm C}_x for x = 0,0.02x = 0,0.02, and 0.04, in the vortex state and in magnetic field of 23.5 kOe. We show that while pure MgB₂_2 exhibits the magnetic field distribution from superposition of the normal and the Abrikosov state, slight replacement of boron with carbon unveils the magnetic field distribution of the pure Abrikosov state. This indicates a considerable increase of H^c_c2H^c_{c2} with carbon doping with respect to pure MgB₂_2. The spin-lattice relaxation rate 1/(T₁T)1/(T_1T) demonstrates clearly the presence of a coherence peak right below T_cT_{\rm c} in pure MgB₂_2, followed by a typical BCS decrease on cooling. However, at temperatures lower than ?\approx 10 K strong deviation from the BCS behavior is observed, probably from residual contribution of the vortex dynamics. In the carbon-doped systems both the coherence peak and the BCS temperature dependence of 1/(T₁T)1/(T_1T) weaken, an effect attributed to the gradual shrinking of the σ hole cylinders of the Fermi surface with electron doping.     

Estimating the creep behavior of polycarbonate with changes in temperature and aging time

Thermoplastic resins are typically used without any kind of physical aging treatment. For such materials, creep behavior and physical aging, which depend on time and temperature, occur simultaneously. The effects of these processes are evident after quenching and are recorded in the material as a thermal history. This history strongly influences mechanical properties and creep behavior in particular. Thus, a more thorough understanding of the physical aging process is desirable. We examined the creep deformation of polycarbonate (PC) to reveal the effects of physical aging on creep behavior. The effects were dependent on both time and temperature. The relationship between physical aging and creep behavior exemplified superposition principles with regard to time and both pre-test aging time and pre-test aging temperature. The superposition principles allowed the calculation of creep deformations at a given temperature; the calculated results were corroborated by experimental data.     

Growth of AgGaTe2 and AgAlTe2 Layers for Novel Photovoltaic Materials

AgGaTe₂ and AgAlTe₂ layers were grown on a-plane sapphire substrates by closed-space sublimation. These compounds replace Cd in CdTe with group I and III elements, and are, hence, expected to be ideal novel candidate materials for solar cells. The grown layers were confirmed to be stoichiometric AgGaTe₂ and AgAlTe₂ by x-ray diffraction (XRD). The AgAlTe₂ layers had strong preference for the (112) orientation. The XRD spectrum of the AgGaTe₂ layer was different from that of the AgAlTe₂ layer, and strong peaks were observed for (103) and (110) diffraction. The variation in orientations of the grown layers was analyzed in detail by use of XRD pole figures, which revealed that the AgGaTe₂ layers had an epitaxial relationship with the a-plane sapphire substrates.     

Moisture profiles of wheat noodles containing hydroxypropylated tapioca starch

Wheat noodles were prepared using flour to which hydroxypropylated tapioca starch was added, and the effect of this addition on the moisture distribution within the noodles during cooking was examined using a digital image processing technique. The addition of the modified starch slightly increased the moisture content and narrowed the flat distribution near the noodle surface. The distribution features reflected the changes in the water absorption behaviour caused by the properties of the modified starch and the reduction in the gluten content. Addition of the modified starch lowered Young's modulus and the energy for 99% strain of the noodles in the texture analysis to, at maximum 35% and 65%, and decreased the breakability of the noodles. These changes in the moisture distribution and textural properties have been ascribed to changes in both the state of the starch granules near the surface and the structure of the gluten network.     

Effects of drying temperature and relative humidity on spaghetti characteristics

This study aimed at investigating the effect of drying conditions on spaghetti properties, i.e., its color, surface structure, rupture strength, rehydration characteristics, texture, and sauce retention capacity. The effects of temperature and humidity were independently examined under constant drying conditions, which were compared to those applied industrially, where the temperature and relative humidity are changed stepwise with time. The knowledge obtained in this study is considered useful for reasonably determining the drying conditions for producing spaghetti with desired properties.     

Dual-Function Semaphorin 4D Released by Platelets: Suppression of Osteoblastogenesis and Promotion of Osteoclastogenesis

Effects of the antiosteoblastogenesis factor Semaphorin 4D (Sema4D), expressed by thrombin-activated platelets (TPs), on osteoblastogenesis, as well as osteoclastogenesis, were investigated in vitro. Intact platelets released both Sema4D and IGF-1. However, in response to stimulation with thrombin, platelets upregulated the release of Sema4D, but not IGF-1. Anti-Sema4D-neutralizing monoclonal antibody (mAb) upregulated TP-mediated osteoblastogenesis in MC3T3-E1 osteoblast precursors. MC3T3-E1 cells exposed to TPs induced phosphorylation of Akt and ERK further upregulated by the addition of anti-sema4D-mAb, suggesting the suppressive effects of TP-expressing Sema4D on osteoblastogenesis. On the other hand, TPs promoted RANKL-mediated osteoclastogenesis in the primary culture of bone-marrow-derived mononuclear cells (BMMCs). Among the known three receptors of Sema4D, including Plexin B1, Plexin B2 and CD72, little Plexin B2 was detected, and no Plexin B1 was detected, but a high level of CD72 mRNA was detected in RANKL-stimulated BMMCs by qPCR. Both anti-Sema4D-mAb and anti-CD72-mAb suppressed RANKL-induced osteoclast formation and bone resorptive activity, suggesting that Sema4D released by TPs promotes osteoclastogenesis via ligation to a CD72 receptor. This study demonstrated that Sema4D released by TPs suppresses osteogenic activity and promotes osteoclastogenesis, suggesting the novel property of platelets in bone-remodeling processes.     

Approach to the Practical Use of Thermoelectric Power Generation

The results of research and development in the Japanese national project “Development for Advanced Thermoelectric Conversion Systems” are summarized, and the approaches to practical use of advanced thermoelectric modules and power generation systems are presented. The 5-year national project was successfully completed in March 2007. Three kinds of high- efficiency cascaded thermoelectric modules and two kinds of innovative Bi-Te thermoelectric modules were successfully developed. Heat cycle tests for three types of modules were also completed. Moreover, four types of advanced thermoelectric power generation systems were experimentally demonstrated for recovery of waste heat from the industrial and private sectors. In order to proceed further, thermoelectric power generation systems using practical heat sources were followed after installation of the developed modules. In parallel, various approaches for practical use by private companies, as well as plans for the next-phase project by the National Institute of Advanced Industrial Science and Technology (AIST) and the Engineering Advancement Association (ENAA), were also followed. The scenarios to proceed to the commercial phase of thermoelectric power generation are discussed on the basis of the results of the national project.     

Model analysis on dispersion characteristics of fine particles in Newtonian molten polymer

In this paper, a model estimating the time-dependent distribution of cluster size consisting of fine particles in Newtonian molten polymer was proposed. The present model for agglomerative suspension was developed based on Usui’s thixotropy model, derived by taking the balance between shear breakup, shear coagulation and Brownian coagulation processes. The analysis was applied to the experimental results for silica/(ethylene methyl-meta acrylate copolymer) suspensions. The time variations of cluster size distributions, of viscosities and of the mean numbers of particles in a cluster were calculated and the results were compared with experimental results for the cases of shear rates from 0.2 to 10 s^?1 when the solid volume fraction was set at 0.15. From the results, it was found that the present model can estimated the steady state values of the slurry viscosity and the mean particle numbers in a cluster as well as Usui’s original model. However, the model could not sufficiently express the time variation of rheological characteristics due to the over-estimation of the contribution of shear rate when the cluster size is small.     

Highly reliable copper dual-damascene interconnects with self-formed MnSi/sub x/O/sub y/ barrier Layer

Copper (Cu) dual-damascene interconnects with a self-formed MnSi/sub x/O/sub y/ barrier layer were successfully fabricated. Transmission electron microscopy shows that approximately 2-nm thick and continuous MnSi/sub x/O/sub y/ layer was formed at the interface of Cu and dielectric SiO/sub 2/, and that no barrier was formed at the via bottom because no oxygen was at the via bottom during annealing. No leakage-current increase was observed, and electron energy loss analysis shows that no Cu was in SiO/sub 2/, suggesting that MnSi/sub x/O/sub y/ layer has sufficient barrier properties for Cu, and that the concept of self-forming barrier process works in Cu dual-damascene interconnects. Via chain yield of more than 90% and 50% reduction in via resistance were obtained as compared with physical vapor deposited tantalum barrier, because there is no barrier at the via bottom. In addition, no failure in the stress-induced voiding measurement was found even after a 1600-h testing. No failure in electromigration (EM) testing was found, as the electron flow is from the lower level interconnects through via up to upper level interconnects even after 1000-h testing. At least, four times EM lifetime improvement was obtained in the case of electron flow from upper level interconnect through via down to lower level interconnects. Significant EM lifetime improvement is due to no flux divergence site at the via bottom, resulting from there being no bottom barrier at the via.