Role of disorder-order transformation in consolidation of ceramics

The ordering of stacking-disordered silicon carbide prepared from the elements by high energy ball milling was investigated during sintering. A sharp increase in density in the temperature region 1700–1800°C was associated with a decrease in the disorder. Samples which had low disorder density showed a more continuous sintering behavior with temperature. Highly dense (up to 99% relative density) SiC can be obtained at 1900°C under a pressure of 70 MPa with no hold time. Similar results were observed for structurally disordered carbon with 10 at% of boron. The sintering behavior exhibited an abrupt density increase in the narrow temperature region of 1450–1600°C and was associated with disorder-order transformation.     

A coaxial pulsed plasma thruster using chemical propellants

Pulsed plasma thrusters (PPTs) have the advantages of mechanical simplicity and robustness compared to other electric propulsion systems. However the thrust power ratio of PPTs is lower than that of other electric propulsion systems. To enhance the thrust performance of the PPT, we propose to use several combustible solid chemicals as coaxial PPT propellants to replace Teflon^® (Polytetrafluoroethylene: PTFE). With the design, the force obtained thermodynamically is expected to augment the PPT thrust power ratio with the help of the chemical energy contained in the propellants. As a result, the thrust power ratio is increased using hydroxyl-terminated polybutadiene-ammonium perchlorate (HTPB-AP)-based propellants compared to the case of ordinary Teflon. The discharge current and voltage waveform does not change even when the propellant is changed. These findings could indicate that the impulse bits by gasdynamic contribution are lager in the case of chemical solid propellants than in the case of Teflon.     

Intracellular recovery of gold by microbial reduction of AuCl4 ions using the anaerobic bacterium Shewanella algae

Microbial reduction and intracellular precipitation of gold was achieved at 25 °C and pH 7 by using the mesophilic anaerobic bacterium Shewanella algae with H₂ as the electron donor. The reductive precipitation of gold by S. algae was a fast process: 0.1–1 mol/m³ AuCl₄⁻ ions were completely reduced to insoluble gold within 30 min. The biogenic precipitates were crystalline gold nanoparticles of 10–20 nm present in the periplasmic space. The reducing power of S. algae at 3.2 × 10¹⁵ cells/m³ and 25 °C was comparable to that of aqueous citric acid solution (chemical reductant) at 20 mol/m³ and 50 °C. The intracellular recovery of gold is potentially attractive as an environmentally friendly alternative to conventional methods.     

Recent Progress on Non‐oriented Silicon Steel

Control of crystalline orientation and consequent enhancement of magnetic properties are important for decreasing core loss of non‐oriented silicon steel as well as grain‐oriented silicon steel. Through the development of special process techniques to produce clean refined steel, it is now possible to use any element to improve the crystalline texture control of steel without producing harmful effects. Utilization of these effects have actually lowered the core loss and raised the magnetic flux density of the products, and a product series of high‐efficiency non‐oriented silicon steel has been developed. Recently, demand has grown for non‐oriented silicon steel with particular properties, such as lower core loss at high frequencies or high strength, as high‐speed motors have progressed in regard to high efficiency and miniaturization. In response to this trend, non‐oriented thin gauge silicon steel with a thickness of 0.20 and 0.15mm and high strength non‐oriented thin gauge silicon steel with the same thickness but a yield strength of more than 570MPa and 780MPa have been developed.     

Encapsulation of radioactive metals inside multilayered polyhedral shells of carbon as a barrier to radionuclide release

A carbon nanoencapsulate has a polyhedral outer shell of nested, concentric layers of carbon. The shell defines an internal cavity where a metal is encapsulated. Although the rare-earth carbides readily hydrolyze in moist air, the carbides in these carbon shells did not degrade after exposure to air for considerable lengths of time. This means that the carbide particle is physically enclosed within the carbon cavity completely, and the cavity protects it perfectly against attack of water molecules. Considering intrinsic chemical stability of carbon under oxygen free condition, this structure may be a perfect barrier to extremely long-term release of radionuclides. Because encapsulation of LaC₂ within carbon nanoparticles increased drastically from by-product to major product, it would be possible to find the optimized condition that complete encapsulation is achieved. Intrinsic stability of carbon and carbon coated waste nanoparticles may provide an improved barrier to radionuclide release by groundwater.     

Plan for first phase of safety demonstration tests of the High Temperature Engineering Test Reactor (HTTR)

Safety demonstration tests using the High Temperature Engineering Test Reactor (HTTR) will be conducted for the purpose of demonstrating inherent safety features of High Temperature Gas-cooled Reactors (HTGRs) as well as providing the core and plant transient data for validation of HTGR safety analysis codes. The first phase safety demonstration test items include the reactivity insertion test and the coolant flow reduction test. In the reactivity insertion test, which is the control rod withdrawal test, one pair out of 16 pairs of control rods is withdrawn, simulating a reactivity insertion event. The coolant flow reduction test consists of the partial loss of coolant flow test and the gas circulators trip test. In the partial loss of coolant flow test, primary coolant flow rate is slightly reduced by control system. In the gas circulators trip test one and two out of three gas circulators are run down, simulating coolant flow reduction events. The gas circulators trip tests, in which position of control rods are kept unchanged, are simulation tests of anticipated transients without scram (ATWS).     

Orthogonal queries in segments

We consider theorthgonal clipping problem in a set of segments: Given a set ofn segments ind-dimensional space, we preprocess them into a data structure such that given an orthogonal query window, the segments intersecting it can be counted/reported efficiently. We show that the efficiency of the data structure significantly depends on a geometric discrete parameterK named theProjected-image complexity, which becomes Θ(n ²) in the worst case but practically much smaller. If we useO(m) space, whereK log^4d−7 n≥m≥n log^4d−7 n, the query time isO((K/m)^1/2 log^{max{4, 4d−5}} n). This is near to an Ω((K/m)^1/2) lower bound.     

Evaluation of Desulphurization Flux in CaO‐Al2O3‐BaO‐CeO2‐MgO System

The flux of the CaO‐Al₂0₃‐BaO‐CeO₂‐MgO system as a desulphurization flux containing no fluorine for the secondary metallurgy process was evaluated in this study. The flux composition was designed using the eutectic compositions of the binary systems. The melting and desulphurization abilities of the fluxes were evaluated by measuring their liquidus temperatures and the distribution ratios of sulphur between the fluxes and the carbon‐saturated iron or stainless steel. The lowest liquidus temperature of 1325°C was obtained by adding 5.7 mass% MgO to the 80mass%A‐20mass%B flux. (A: 12CaO‐7Al₂O₃, B: BaCeO₃+12mass%Al₂O₃). The distribution ratios of sulphur and sulphide capacities of the fluxes in this study were higher than those of the commercial product of calcium aluminate flux. This means that the CaO‐Al₂O₃‐BaO‐CeO₂‐MgO fluxes developed in this study have higher desulphurization and melting abilities compared with the commercial product of calcium aluminate flux.     

Probabilistic output admissible set for systems with time-varying uncertainties

This paper considers time-varying uncertain constrained systems, and develops a method for computing a probabilistic output admissible (POA) set. This set consists of the initial states probabilistically assured to satisfy the constraint. The time-invariant counterpart has already been investigated in Hatanaka and Takaba [Computations of probabilistic output admissible set for uncertain constrained systems, Automatica 44 (2) (2008), to appear]. We first define the POA set for time-varying uncertainties with finite dimensional probability space. Then, we show that an algorithm similar to Hatanaka and Takaba [Computations of probabilistic output admissible set for uncertain constrained systems, Automatica 44 (2) (2008), to appear] provides the POA set also in the time-varying case, as long as an upper bound of a what we call future output admissibility (FOA) index is available. We moreover present two methods for computing the upper bound of the FOA index: probabilistic and deterministic methods. A numerical simulation demonstrates the effectiveness of our algorithm.