Reducing inventory data requirements for scenario representation in comparative life cycle assessment (LCA), demonstrated on the urban wastewater system

Wastewater reuse has become an attractive option for alleviating the stress from water resources. Centralized wastewater reuse is a common and continuously expanding practice worldwide, but the advantages of centralized over decentralized approaches are lately being questioned. Life cycle assessment (LCA) is a well-accepted means of assessing the overall environmental performance of service systems, however, construction of a life cycle inventory (LCI) for complex systems such as urban wastewater systems, is very time consuming. Lack of resources and unavailability of data often enforce constraints on the scope of the assessment. In such cases it may be beneficial to consider the approach presented here, which manifests the differences between the studied alternatives. By eliminating processes that remain unchanged, less data and human resources are required in building the inventory, and less parameter uncertainty is introduced into the analysis. The proposed approach is demonstrated through the conceptual modeling steps of an assessment of decentralized urban wastewater reuse alternatives.     

Corrosion inhibition of magnesium by combined zirconia silica sol-gel films

The inhibition of Mg (AZ91D) corrosion by thin sol-gel films was studied. The sol-gel films were prepared by the traditional acid or base-catalyzed hydrolysis and condensation, and finally deposited by dip coating. Two different sol-gel monomers were used: phenyltrimethoxysilane (PTMOS) and zirconium(IV)tetra-1-propoxide (ZrTPO). Films were made of each of the individual monomers and by depositing first a PTMOS film followed by ZrTPO-based film. The corrosion inhibition of the films and their characterization were examined by different methods including potentiodynamic polarization, contact angle measurement, adhesion test, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS).We found that while the ZrTPO-based film did not show a significant corrosion inhibition, the PTMOS-based film provided moderate protection. Interestingly, the combined film exhibited superior corrosion inhibition as compared with the other films.     

An “O/S” Emulsion in a System Containing Tween 80 Surfactant and Hexadecane Oil

An emulsion was prepared from hexadecane and a surfactant, Tween 80 (a commercial polyoxyethylene sorbitan mono-oleate), and the destabilization process was followed by visual observation of the separation of the emulsion aided by optical microscopy to estimate droplet size versus time. The emulsions had inferior stability, and the destabilization was completed within a few days. The results showed the emulsion to destabilize with the flocculation step immediately followed by coalescence. The separation rate was at a level calculated from the sedimentation rate of a dilute emulsion. This result was not anticipated, considering the large fraction of the dispersed phase, and an assumption was made as to what counteracting factors may have affected the results.

Fate of the pathogen indicators phage ΦX174 and Ascaris suum eggs during the production of struvite fertilizer from source-separated urine

Human urine has the potential to be a sustainable, locally and continuously available source of nutrients for agriculture. Phosphate can be efficiently recovered from human urine in the form of the mineral struvite (MgNH₄PO₄·6H₂O). However, struvite formation may be coupled with the precipitation of other constituents present in urine including pathogens, pharmaceuticals, and heavy metals. To determine if struvite fertilizer presents a microbiological health risk to producers and end users, we characterized the fate of a human virus surrogate (phage ΦX174) and the eggs of the helminth Ascaris suum during a low-cost struvite recovery process. While the concentration of phages was similar in both the struvite and the urine, Ascaris eggs accumulated within the solid during the precipitation and filtration process. Subsequent air-drying of the struvite filter cake partially inactivated both microorganisms; however, viable Ascaris eggs and infective phages were still detected after several days of drying. The infectivity of both viruses and eggs was affected by the specific struvite drying conditions: higher inactivation generally occurred with increased air temperature and decreased relative humidity. On a log-log scale, phage inactivation increased linearly with decreasing moisture content of the struvite, while Ascaris inactivation occurred only after achieving a minimum moisture threshold. Sunlight exposure did not directly affect the infectivity of phages or Ascaris eggs in struvite cakes, though the resultant rise in temperature accelerated the drying of the struvite cake, which contributed to inactivation.     

Direct Electricity Production from Nematostella and Arthemia’s Eggs in a Bio-Electrochemical Cell

In recent years, extensive efforts have been made to develop clean energy technologies to replace fossil fuels to assist the struggle against climate change. One approach is to exploit the ability of bacteria and photosynthetic organisms to conduct external electron transport for electricity production in bio-electrochemical cells. In this work, we first show that the sea anemones Nematostella vectensis and eggs of Artemia (brine shrimp) secrete redox-active molecules that can reduce the electron acceptor Cytochrome C. We applied 2D fluorescence spectroscopy and identified NADH or NADPH as secreted species. Finally, we broaden the scope of living organisms that can be integrated with a bio-electrochemical cell to the sea anemones group, showing for the first time that Nematostella and eggs of Artemia can produce electrical current when integrated into a bio-electrochemical cell.     

A meeting with clay: Individual narratives, self-reflection, and action.

The arts-based qualitative research presented in this article explores the interaction between nonartists and a specific art material, clay, and on reflection, the meaning that they make from this interaction. The aspect of meaning making focused on relates to a typology of thinking and doing strategies that emerged from the research. Thinking and doing are seen as 2 aspects of a creative process here with clay, which are interdependent. The thinking category encompasses 4 groups in which the participants employ different modes of thinking strategies. Different modes of thinking create a different kind of doing with the material. These "dialogues" between creator and material can be seen to exemplify individual ways of "making sense" in the interaction between sensing, feeling, thinking, and doing; and the material, in which structure, process, content, and meaning intertwine. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Cation Radicals of Covalently Linked Porphyrin Dimers and their Monomeric Constituents: An ESR and ENDOR Study

The spin density distributions in the cation radicals of various covalently linked porphyrin dimers have been studied by liquid phase ESR and ENDOR methods to find out whether these systems show intramolecular electron delocalization. Such a delocalization is known to occur in the bacteriochlorophyll dimer (“special pair”) in the photosynthetic reaction center. The dimers that were studied in this work were derived from zinc mesotetratolylporphyrin (ZnTTP) and linked at the ortho or para positions of one phenyl ring with varying bridge lengths. ¹H and ^I4N hyperfine coupling constants could be measured for the dimer cation radicals and compared with those of monomeric ZnTTP as well as ZnTTP derivatives that carry alkoxy or hydroxy substituents to mimic the bridges of the dimers. By comparing the hyperfine data of the monomer and dimer cation radicals it is concluded that in the present dimers the unpaired electron is localized on one porphyrin unit.