An Environmentally Benign,Highly Efficient Catalytic Reduction of p‐Nitrophenol using a Nano‐Sized Nickel Catalyst Supported on Silica‐Alumina

A green and effective method is reported for the reduction of p‐nitrophenol to p‐aminophenol using a nano‐sized nickel catalyst supported on silica‐alumina in the presence of hydrazine hydrate as an alternative source of hydrogen. It was found that nickel loaded on a silica‐alumina support is a very effective catalyst in the hydrogenation of p‐nitrophenol to p‐aminophenol. Thus it attained 100% conversion in only 69 seconds instead of 260 seconds for commercial Raney nickel. In addition, the possibility to reuse it more than one time with great efficiency gives it another advantage over commercial Rainey nickel which cannot be used more than once. This economical and environmentally friendly method provides a potentially new approach for the synthesis of the intermediate product of paracetamol in industry, which overcomes the drawbacks of the known reduction methods. The prepared catalysts were fully characterized by X‐ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X‐ray (EDX), and electron spin resonance (ESR) tehniques.     

Improvement and stabilization white of bread flavour

Effect of adding the model system mixture (D,L-lysine · HCl, L-proline and D-glucose) on the sensory properties and volatile components of fresh bread and bread stored for 3 days were investigated. The results showed that the model system mixture improved the crust colour and flavour of fresh bread and kept the freshness, retarded the staling and improved the quality of the bread samples stored for 3 days. Analysis of the crust aroma of the bread samples showed that 2-acetyl pyrazine, 2-acetyl pyridine and 2-methyl-3-ethyl pyrazine, which may be responsible for bread crust aroma, were determined at high concentration in the bread sample containing 0.24% model system mixture. The concentration of pyrazine derivatives increased during storage whereas the carbonyl, pyrrol and furan derivatives decreased.     

EGYPTOR Tokamak: Modification of the Original Design Using Permanent Compensation Coils and First Results of the Breakdown Discharge

The EGYPTOR tokamak is a small device of rectangular cross section 25 × 20 cm. Modification of the original design is done by adding compensation coils connected to the Toroidal field (TF) coils and Ohmic heating (OH) coils. These compensation coils are used to compensate most of the stray magnetic field components that prevent a breakdown discharge. First results of the breakdown discharge are reported. A gated ICCD camera is used to obtain side view images of the visible light emitted from the plasma.     

Radiation-induced oxidative degradation of isotactic polypropylene

Gas evolution, oxygen consumption, and change of mechanical properties were studied for the γ-ray irradiation of isotactic polypropylene from ⁶⁰Co under various conditions, such as vacuum, air, and oxygen at room temperature. For irradiation under vacuum, G(H₂) = 2.9 and G (CH₄) = 0.09; the G values for other gases were very small. In the presence of oxygen, G(H₂) was the same, and the G values for other hydrocarbons were two times those under vacuum. The G values of oxidative products and oxygen consumption were G(CO₂) = 2.5, G(CO) = 1.1, and G(O₂) = 50 at oxygen pressure of 500 torr and were dependent on oxygen pressure. With irradiation under vacuum at 2–3 Mrad, mechanical properties scarcely changes immediately after irradiation but degrade gradually with storage time in air at room temperature.     

A Scalable Parallel Algorithm for Reachability Analysis of Very Large Circuits

This paper presents a scalable method for parallelizing symbolic reachability analysis on a distributed-memory environment of workstations. We have developed an adaptive partitioning algorithm that significantly reduces space requirements. The memory balance is maintained by dynamically repartitioning the state space throughout the computation. A compact BDD representation allows coordination by shipping BDDs from one machine to another. This representation allows for different variable orders in the sending and receiving processes. The algorithm uses a distributed termination protocol, with none of the memory modules preserving a complete image of the set of reachable states. No external storage is used on the disk. Rather, we make use of the network, which is much faster.We implemented our method on a standard, loosely-connected environment of workstations, using a high-performance model checker. Initial performance evaluation of several large circuits shows that our method can handle models too large to fit in the memory of a single node. The partitioning algorithm achieves reduction in space, which is linear in the number of workstations employed. A corresponding decrease in space requirements is measured throughout the reachability analysis. Our results show that the relatively slow network does not become a bottleneck, and that computation time is kept reasonably small.