无芯胶管的研制、工艺现状和发展建议

20世纪60年代初,我国胶管领域自主开发创新研制了无芯胶管制造技术,并且形成定型技术,一直沿用至今,笔者参与、见证了该产品从试验到投产的全过程。本文对该产品的工艺进行了新旧对比,提出了今后发展的建议。     

Reciprocating flow ion exchange part II: Application to saline water softening

The “hardness” components in sea water can be considerably reduced by means of a new economical fixed bed technique called “Reciprocating Flow Ion Exchange”, when used in conjunction with a closed cycle exchanger-evaporator system. Removal of 87.9% of the calcium and 54.5% of the magnesium in sea water has been obtained with an overall flow rate of 5.0 U. S. g. p. m./sq. ft. Results from bench scale and a 5,000 g. p. d. pilot plant were identical. The virtually continuous cyclic steady-state process requires a small amount of exchanger (0.5 to 2% of the usual ion exchange methods, such as conventional fixed beds or fluidized beds). The effects of variation in operating parameters are discussed.     

热熔凝聚法加工农药悬浮剂研究

介绍了采用热熔凝聚法对加工二氯喹磷酸、氟虫睛、乙霉威悬浮剂的试验结果，并测定了制剂的粒度分布、冷贮、热贮稳定性等理化性质。该法工艺简单、加工方便、节省能源、工业上切实可行。     

Guerbet十四醇的合成与表征

以正庚醇为原料 ,通过Guerbet反应合成Guerbet十四醇 (2 戊基壬醇 ,C14 GA)。用IR、NMR和元素分析测定了C14 GA的结构 ,并研究了反应温度和用料比对其产率的影响。实验结果如下 :(1)在较优化的反应条件下 (正庚醇的总加入量为 1mol,在实验过程中 ,先加入 1/ 3mol庚醇和 1/ 4mol的KOH ,在 16 0℃下反应 2h ,然后再加入剩下的 2 / 3mol庚醇和 4g 5 %Pd -C催化剂 ,在 15 5℃下反应 6h)合成产物 ,其产率可达到 5 4 2 0 % ;(2 )所合成的产物与试图要得到的Guerbet十四醇 (2 戊基壬醇 ,C14 GA)含有相同的基团 (2×—CH3、10×—CH2 —、1×CH、1×—CH2 —O—和 1×—OH) ,而且 ,所合成的产物中 ,w (C) =79 0 6 % ,w (H ) =13 6 2 % ,与从Guerbet十四醇分子式计算的理论值w(C) =78 5 0 % ,w (H) =14 0 1%基本一致。可见所合成的产物正是Guerbet十四醇 (C14 GA)     

Preparation of Titanium Nitride/Alumina Laminate Composites

A preparation route for TiN/Al₂O₃ laminate composites has been described. A water-based process using Al₂O₃ and TiN slurries with solids contents of 40 and 35 vol%, respectively, was used to make TiN and Al₂O₃ tapes. The removal of the binder was monitored by weight-loss measurements in a thermogravimetry unit. Bodies composed of Al₂O₃ and TiN tapes were densified at temperatures of 1400° and 1500°C using the Spark Plasma Sintering^® (SPS) technique. Densities of >98% of the theoretical densities were approached. Crack-free and almost fully densified TiN/Al₂O₃ compacts were prepared by heating the burned-out green bodies to the final sintering temperature (1500°C) at a rate of 100°C/min, and with a holding time of 5–10 min, under a pressure of 75 MPa. The microstructures of the obtained compacts were studied using scanning electron microscopy. Grain sizes in the sintered Al₂O₃ and TiN compacts were similar to those of the precursor powders. Hardness and indentation fracture toughness were measured at room temperature, and the monolithic compacts as well as the laminate composites exhibited anisotropic mechanical behavior; i.e., the cracks propagated much more easily in a direction parallel to the laminas than perpendicular to them.     

Surface Preparation of Tantalum for Encapsulation and Adhesive Bonding

A number of methods of surface preparation of tantalum for encapsulation in silicone rubber and for structural adhesive bonding were explored. The only ones which could be generally useful were boiling for 24 hours in distilled water (28% improvement) or boiling for 4 hours in 20% sodium hydroxide solution followed by boiling for 2 hours in dilute hydrochloric acid (34% improvement). An alternative, which could sometimes be used, was heating in air for at least 2 hours at 100°C.     

真空粉末绝热低温贮罐制造的部分工艺方法

在真空粉末绝热低温贮罐的制造过程中、通过吸附器分子筛的活化、夹层真空系统的处理和充装珠光砂等工艺方法的改进,可较大地缩短产品的制造周期并提高产品的质量。     

纳米SiO2粉体的制备与研究

纳米SiO2粉体的制备是以硅酸钠和盐酸为原料，添加适宜的稳定剂(非离子表面活性剂)和分散剂，在适宜的pH值和温度下，采用化学沉淀法合成。研究表明，要得到性能优良纳米的SiO2粉体，最佳工艺条件为：温度20～40℃，pH=6，反应液质量浓度P1=20g／L，P2=1．20g／L，反应时间15min。结果表明：制备的纳米SiO2粒径30～50nm，比表面积大，分散性好，质量优良，可达到产业化的生产。