A brief review on α-zirconium phosphate intercalation compounds and nano-composites

The layer structured zirconium phosphate(Zr P) can be intercalated with atoms, molecules, small organic groups and even polymers. The structures and properties of the Zr P intercalation compounds can be deliberately tuned, leading to promising potential applications in many fields. This article provides a brief review on the experimental results of the Zr P intercalation compounds, with the focus on the polymer/a-zirconium phosphate (α-Zr P) nano-composites. The computer simulations of the Zr P intercalation compounds at the atomic level play a significant role in designing and understanding the properties of Zr P, and in the promotion of the applications of compounds.     

以品牌专业建设为契机 抓住发展机遇 全面提高专业建设质量

专业建设是高等学校最重要的教学基本建设,是教育教学工作的基础和重要生命线,是高等学校人才培养的重要依托。加强本科品牌专业的建设可提升学校本科专业建设的整体水平,提高学校本科人才培养质量、效益和竞争力。文章围绕如何开展品牌专业建设,结合学校实际,着重从品牌专业内涵、建设原则、内容和评价办法等方面进行了阐述。     

介质阻挡放电反应器降解邻二甲苯的特性研究

采用介质阻挡放电(DBD)降解常压下流动态的邻二甲苯模拟废气,系统地考察了放电极值电压,气体的初始质量浓度、停留时间以及相对湿度等工艺参数对邻二甲苯降解的影响,并初步探讨了邻二甲苯的降解产物.实验研究结果表明:在7.0kV的放电极间电压下,邻二甲苯的初始质量浓度为1 500mg/m3,停留时间为9s,其去除率可达到80%以上.降解产物主要为CO2、H2O以及苯甲酸、苯乙酸、苯乙醛等有机物,并且经降解后产物的生物可生化性得到提高,因而为后续的等离子-生物法联合处理VOCs提供了依据.     

Influence of Cryomilling on the Morphology and Composition of the Oxide Scales Formed on HVOF CoNiCrAlY Coatings

Commercially available, gas-atomized CoNiCrAlY powder was cryomilled to produce powder with nanocrystalline grains. The cryomilled powder and conventional gas-atomized powder were thermally sprayed using the HVOF process to prepare two coatings with fine-grain (～15 nm) and coarse-grain (～1 μm) microstructure, respectively. The two coatings were isothermally oxidized in air at 1000° C for up to 330 hr. The morphology and composition of the oxide scales formed on the two coatings were compared with each other. The results indicate that, while a fine-grain microstructure can promote the formation of a pure alumina layer on the coating by increasing the Al diffusion rate toward the surface, it can also accelerate the Al depletion by increasing the Al diffusion rate toward the substrate, which results in the formation of non-alumina oxides after long-term oxidation. The mechanisms governing the oxide formation are discussed in terms of atomic diffusion and thermodynamic stability.     

新颖的绕线拉紧装置

本文介绍一种新型适用的线圈绕制中的线材拉紧装置，并将其与传统的拉紧装置进行比较，得出各自的优缺点。     

Microstructural Investigation of Protective and Non-Protective Oxides on 11% Chromium Steel

FIB, SEM and STEM/EDX were used to investigate X20 stainless-steel samples exposed to dry O₂, or O₂ containing 40% H₂O, with a flow velocity of 0.5 cm/s or 5 cm/s, for 168 hr or 336 hr at 600°C. Thin protective Cr-rich (Cr,Fe)₂O₃ was maintained on the samples exposed to dry O₂, even after 336 hr, and on the sample exposed to O₂/H₂O mixture with the low-flow velocity (0.5 cm/s) for 168 hr. The oxide scale formed in the latter environment contained less Cr, due to Cr loss through CrO₂(OH)₂ evaporation. Breakaway oxidation occurred on the samples exposed in high-gas-flow velocity for shorter time (168 hr) or in low-gas-flow velocity (0.5 cm/s) for longer time (336 hr). The breakaway scales featured a two-layered structure: an outward-growing oxide “island” consisting of almost pure hematite (α-Fe₂O₃), and an inward-growing oxide “crater” consisting of (Cr,Fe)₃O₄. The transition from a thin protective (Cr,Fe)₂O₃ scale to a non-protective thick scale on this martensitic/ferritic steel originated locally and was followed by rapid oxide growth, resulting in a thick scale that covered the whole sample surface.     

保温条件下过共晶Al-Si合金半固态浆料的组织演变

研究了保温时间和保温温度对电磁搅拌ZL117合金半固态浆料稳定性的影响.试验结果表明：半固态浆料中初生Si的颗粒直径随着保温时间的延长而逐渐增大,但在前15 min内增长速度比较缓慢,15 min后增长较快;随着保温温度的升高而缓慢增大;初生Si的形状系数随着保温时间的延长而变得越来越大,但也在前15 min内变化较为缓慢,15 min后变大速度突然加快;初生Si的形状系数在620 ℃下保温时最小,在610～620 ℃之间随着保温温度的升高而缓慢变小;在620～650 ℃之间随着保温温度的升高而逐渐增加.     

中厚板在线30通道超声波探伤方法及应用

介绍了柳钢公司在生产锅炉板、压力容器板过程中，曾试用了６种探伤方法；而研制的３０通道在线超声波探伤法不仅可满足国家标准要求，而且能适应生产节奏，并具有快速、准确、简便的特点。     

国外小电流空气等离子弧切割技术的发展

本文就小电流空气等离子弧切割工艺的特性、切割质量、切割设备、存在问题和应用情况作了综合介绍。当工作气体含氧量为20％时,切割速度急剧增加,大大优于气割。