Influence of Cryomilling on the Morphology and Composition of the Oxide Scales Formed on HVOF CoNiCrAlY Coatings

Commercially available, gas-atomized CoNiCrAlY powder was cryomilled to produce powder with nanocrystalline grains. The cryomilled powder and conventional gas-atomized powder were thermally sprayed using the HVOF process to prepare two coatings with fine-grain (～15 nm) and coarse-grain (～1 μm) microstructure, respectively. The two coatings were isothermally oxidized in air at 1000° C for up to 330 hr. The morphology and composition of the oxide scales formed on the two coatings were compared with each other. The results indicate that, while a fine-grain microstructure can promote the formation of a pure alumina layer on the coating by increasing the Al diffusion rate toward the surface, it can also accelerate the Al depletion by increasing the Al diffusion rate toward the substrate, which results in the formation of non-alumina oxides after long-term oxidation. The mechanisms governing the oxide formation are discussed in terms of atomic diffusion and thermodynamic stability.     

Size and pressure effects on solid transition temperatures of ZrO2

Transition temperatures between tetragonal and monoclinic polymorphs of ZrO₂ nanoparticles, thin films and nanostructured materials are calculated by considering energetic contributions of surface (interface) energy and surface stress on total Gibbs free energy. The transition temperatures drop as the size of the nanocrystals decreases, which is consistent with available results.     

微小电偶腐蚀电流的准确测定

为了更多地获得电偶腐蚀的信息并揭示其本质规律，提出了电偶腐蚀试验实时监测模型。通过选用不同设备对试样的电偶腐蚀微小电流的测量，结果发现：选用现成设备测量试样的电偶腐蚀微小电流时，测量电流波动非常大，噪声明显超过实际信号输入——电偶腐蚀电流。经自行开发研制的MCD01电偶腐蚀计可以准确的测量腐蚀电流，特别是微小电偶腐蚀电流。     

FORMATION OF μ-PHASE AND ITS EFFECT ON MECHANICAL PROPERTIES OF CAST NICKEL-BASE SUPERALLOYS

本文研究了铸造镍基高温合金中沉淀的片状μ相,揭示了μ相的形成规律、化学成份、TTT曲线、断裂特征和对力学性能的影响。研究结果表明,μ相的形成温度范围很宽,从800—1140℃。片状μ相的宽面是六方指数的{0001},它沿基体γ的{111}面板出。在760℃以下冲击,拉伸和持久的断裂特征是沿μ相{0001},面解理断裂,电子空位数N_v值不是控制μ相形成的唯一因素,还与(Mo+W)at.-％和Mo(Mo+W)有关。此外,硼也是抑制μ相的有效因素。     

Microstructural Investigation of Protective and Non-Protective Oxides on 11% Chromium Steel

FIB, SEM and STEM/EDX were used to investigate X20 stainless-steel samples exposed to dry O₂, or O₂ containing 40% H₂O, with a flow velocity of 0.5 cm/s or 5 cm/s, for 168 hr or 336 hr at 600°C. Thin protective Cr-rich (Cr,Fe)₂O₃ was maintained on the samples exposed to dry O₂, even after 336 hr, and on the sample exposed to O₂/H₂O mixture with the low-flow velocity (0.5 cm/s) for 168 hr. The oxide scale formed in the latter environment contained less Cr, due to Cr loss through CrO₂(OH)₂ evaporation. Breakaway oxidation occurred on the samples exposed in high-gas-flow velocity for shorter time (168 hr) or in low-gas-flow velocity (0.5 cm/s) for longer time (336 hr). The breakaway scales featured a two-layered structure: an outward-growing oxide “island” consisting of almost pure hematite (α-Fe₂O₃), and an inward-growing oxide “crater” consisting of (Cr,Fe)₃O₄. The transition from a thin protective (Cr,Fe)₂O₃ scale to a non-protective thick scale on this martensitic/ferritic steel originated locally and was followed by rapid oxide growth, resulting in a thick scale that covered the whole sample surface.     

用计算机图形处理软件定量分析SEM图像

用图形处理软件PHOTOSHOP对SEM图像进行图像定量分析，对高温合金K23σ析出相的体积分数和M8钢样的夹杂物颗粒尺寸进行了定量测定。结果表明，该方法操作方便，有一定的可行性。     

保温条件下过共晶Al-Si合金半固态浆料的组织演变

研究了保温时间和保温温度对电磁搅拌ZL117合金半固态浆料稳定性的影响.试验结果表明：半固态浆料中初生Si的颗粒直径随着保温时间的延长而逐渐增大,但在前15 min内增长速度比较缓慢,15 min后增长较快;随着保温温度的升高而缓慢增大;初生Si的形状系数随着保温时间的延长而变得越来越大,但也在前15 min内变化较为缓慢,15 min后变大速度突然加快;初生Si的形状系数在620 ℃下保温时最小,在610～620 ℃之间随着保温温度的升高而缓慢变小;在620～650 ℃之间随着保温温度的升高而逐渐增加.     

铝—钢双金属复合轧制层厚比及轧制力的研究

用实验方法研究了铝－钢双金属复合轧制时层厚比的变化规律。给出了双金属复合时轧制力的计算式。     

移动定位技术的现状与发展趋势

基于位置服务为人们的日常生活带来了极大的方便,同时也推动了移动定位技术行业的快速发展。针对移动定位技术发展状况,分析目前主流定位技术的优劣,并对取得的突破作简单的总结归纳。