83.
Hugh Brown has shown that interfacial entanglements govern adhesion between two polymers. We demonstrate this for three systems by adding interfacial chains
via chemical coupling. The adhesion between polypropylene (PP)/amorphous polyamide (aPA) was reinforced by the coupling reaction of maleic anhydride grafted PP (PP-
g-MA) and the primary amine groups on aPA; huge increases in adhesion were observed. A good correlation between critical fracture toughness,
G c , and PP-
g-MA concentration squared follows Brown's crazing mechanism. For a polystyrene (PS)/aPA interface reinforced by the coupling reaction of poly(styrene-
r-maleic anhydride) (PS-
r-MA)/aPA only modest adhesion increases in
G c were observed through the whole PS-
r-MA concentration range. This different behavior of
G c vs. functional polymer concentration is believed to be caused by segregation of the formed graft copolymers at the interface. The relationship between
G c and the extent of coupling was studied quantitatively with a model PS/PMMA system. The interface was reinforced by the coupling reaction of 0–10% PS-NH
2/PMMA-anh.
G c was measured with the asymmetric dual cantilever beam test (ADCB) and the amount of copolymer formed at the interface was determined by a fluorescence labeling technique.
G c is low and is linear in block copolymer interfacial coverage (Σ), indicating a chain scission mechanism. Reasonable agreement was achieved between experiment and theoretical prediction based on the energy to break C–C bonds.
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