添加WC对镍基合金激光熔敷层硬度及腐蚀磨损行为的影响

探讨了添加ＷＣ的镍基合金Ｇ１１２激光熔敷层的性能，结果表明，添加２０％ＷＣ的激光熔敷层的硬度ＨＶ０．２比末添加的提高近一倍，在酸性介质中的耐蚀性有所降低，但腐蚀磨损性能却得到大改善，其腐蚀磨损机制在低冲击速度下，由犁削磨损，坑穴腐蚀及应力腐蚀变为犁削磨损为主，在高冲击速度下，两者的腐蚀磨损机制趋于一致，均为犁削磨损为主，伴以抗穴腐蚀及应力腐蚀。     

CO2气体保护的激光焊接12mm厚低碳钢板

采用CO2 作为保护气体消除大熔深激光焊接低碳钢时易发生的气孔问题 ,并对比研究了CO2 和Ar气保护条件下 12mm厚低碳钢板激光焊缝的组织和韧性。焊接试验利用 4kWNd :YAG激光器 ,采用双面深熔焊的方法 ,焊接条件为 4kW激光功率和0 .3 ,0 .5m/min的焊接速度。冲击试验采用一种自行设计的带侧面缺口的三缺口冲击试样 ,以保证断裂全部发生在焊缝。结果表明 ,利用CO2 作保护气体焊接低碳钢板 ,可以有效消除大熔深激光焊接时的气孔问题 ,并获得比Ar气保护下硬度较低 ,冲击韧性高的焊缝。研究工作为解决大功率激光深熔焊时容易发生的气孔问题提供了一条有效途径     

形成针对太湖流域三类水源的综合解决方案实现典型和新型污染物的协同控制

太湖流域是我国典型的水质缺水型地区,饮用水安全保障工作面临较大挑战。"十三五"水专项"太湖流域饮用水安全保障工程技术与综合管理技术集成研究"课题梳理了太湖流域饮用水专项实施以来的课题及关键技术,针对太湖流域水源水质特征和区域供水特征,通过水源水质评估、关键技术遴选、工艺协同优化和示范工程验证,形成了针对太湖流域三类典型水源水质特征的分类综合解决方案,实现了典型和新型污染物的协同控制,以期为太湖流域饮用水安全保障提供技术支撑,为国家饮用水安全保障战略实施提供可借鉴的方案。     

Synergistic effects of organically modified montmorillonite in combination with metal oxides on the fire safety enhancement of intumescent flame-retarded epoxy resins

Synergistic effects of organically modified montmorillonite (OMMT) in combination with different metal oxides (Bi₂O₃, Sb₂O₃, and MoO₃) on the fire safety enhancement of the intumescent flame-retarded epoxy resins (EPs) were systematically evaluated. The results from X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses show that the OMMT and metal oxides acquire a uniform distribution in the EP matrix, and OMMT platelets exhibit a fully exfoliated state. The flammability and thermogravimetry (TG) tests show that the intumescent flame retardant (IFR)-OMMT-metal oxide ternary system can endow EPs with the higher synergistic efficiencies on the enhancement of flame retardancy, smoke suppression properties, and charring ability compared to those of IFR or IFR-OMMT system, and the synergistic efficiency is the following order: IFR/OMMT/Sb₂O₃ > IFR/OMMT/MoO₃ > IFR/OMMT/Bi₂O₃. In particular, the sample, filled with 1.5 wt% OMMT, 1.5 wt% Sb₂O₃, and 27 wt% IFR, passes the UL94 V-0 rating and acquires the highest limiting oxygen index value of 28.5% among the samples. The IFR-OMMT-metal oxide ternary system exerts a better synergistic effect on the generation of crosslinking and aromatic structures that supply the excellent charring effect and barrier effect for the EPs, and the synergistic efficiency of IFR-OMMT-metal oxide ternary system is varied with the types of metal oxides.     

Pd/Mg(OH)2 Heterogeneous Nanocatalysts Synthesized by a Facile One-Pot Hydrothermal Method for CO Direct Esterification to Dimethyl Oxalate

Catalysis Letters - Pd-based heterogeneous nanocatalysts have wide application in chemical industry. However, the traditional synthesis process contains multi-steps such as impregnation, dry,...     

Novel Mo-V Oxide Catalysts with Nanospheres as Templates for the Selective Oxidation of Acrolein to Acrylic Acid

Catalysis Letters - Novel Mo-V-PMMA and Mo-V-PS catalysts are prepared by addition of hard polymethyl methacrylate (PMMA) and polystyrene (PS) nanospheres into Mo/V compounds in the preparation...     

Hydroxyl Groups Promoted Ag Dispersion and Excellent Performance of Ag/Al2O3 Catalyst for HCHO Oxidation

Catalysis Letters - Hydroxyl groups are considered as anchoring sites for active components on catalysts. Guided by this viewpoint, 4 wt. % Ag/Al2O3 catalyst derived from Boehmite (AlOOH) was...     

Enhanced luminescent performance of 1,8-naphthalic anhydride-loaded bimodal mesoporous silicas modified by europium nitrate

Journal of Porous Materials - Eu(NO3)3 was selected as an enhancer to improve the performance of luminescent hybrid bimodal mesoporous silica (LHMS), and a series of LHMS-EN(x)...