Performance analysis of Push-To-Talk over IEEE 802.16e with? sleep mode and idle mode

We investigate how much power saving can be achieved for a Push-To-Talk (PTT) service by employing sleep mode and idle mode in the IEEE 802.16e. In this paper, a mobile station by employing sleep mode during an on-session and idle mode during an off-session of the PTT service is modeled as a semi-Markov chain. We obtain power consumption of the mobile station, call setup delay and talker arbitration delay. Using our mathematical model, we can find the optimal sleep window satisfying the required quality of service (QoS) on call setup delay and talker arbitration delay. The numerical examples show that the sleep mode and idle mode provide a considerable reduction on energy of the mobile stations.     

Acidic leaching both of zinc and iron from basic oxygen furnace sludge

During the steel production in the basic oxygen furnace (BOF), approximately 7-15 kg of dust per tonne of produced steel is generated. This dust contains approximately 1.4-3.2% Zn and 54-70% Fe. Regarding the zinc content, the BOF dust is considered to be highly problematic, and therefore new technological processes for recycling dusts and sludge from metallurgical production are still searched for. In this study the hydrometallurgical processing of BOF sludge in the sulphuric acid solutions under atmospheric pressure and temperatures up to 100 °C is investigated on laboratory scale. The influence of sulphuric acid concentration, temperature, time and liquid to solid ratio (L:S) on the leaching process was studied. The main aim of this study was to determine optimal conditions when the maximum amount of zinc passes into the solution whilst iron remains in a solid residue.     

Achieving chiral resolution in self-assembled supramolecular structures through kinetic pathways

Chiral phase transitions were studied in a self-assembled 2,6-dibromoanthraquinones supramolecular system prepared on Au(111) using scanning tunneling microscopy. As the molecules were deposited at about 150?K, they formed heterochiral chevron structures (a racemate) consisting of two alternating prochiral molecular rows. When the as-deposited sample was warmed to 300?K followed by cooling to 80?K, phase-separated homochiral structures (a conglomerate), as well as the chevron structures, were observed. We propose molecular models for the structures that are in good agreement with ab?initio studies and can be explained by hydrogen bonds and halogen bonds. We found that heterochiral chevron structures were more stable than homochiral structures due to two additional [Formula: see text] halogen bonds per molecule. We considered kinetic pathways for the phase transitions that were made possible via a disordered liquid phase entropically stabilized at 300?K. We show how chiral resolution can be achieved by exploiting kinetic paths allowed in supramolecular systems.     

Effect of boron substitution on the properties of NiZnCu ferrite for multilayer chip inductors

The initial permeability of the toroidal core sample with boron substituted NiZnCu ferrite (Ni_0.36Zn_0.44Cu_2.2Fe_1.96 − xB_xO₄(x = 0.0, 0.2, 0.4, 0.6, and 0.8)) which was annealed at 900 °C for 2 h decreased from 162.4 to 123.2 as boron concentration x is increased from 0.2 to 0.8. The quality factor and density of 0.2 mol% boron substituted NiZnCu ferrites sintered at 900 °C for 2 h was about 240.0 and 4.84 g/cm³, respectively. The density, shrinkage and saturation magnetization were increased with increasing annealing temperature. It was shown that the boron substituted NiZnCu ferrite systems were promising as a high quality factor material in the fabrication of multilayer chip inductors (MLCIs).     

Enhanced light output of angled sidewall light-emitting diodes with reflective silver films

A proof-of-concept of applying laser micro-machining to fabricate high performance GaN light-emitting diode (LED) was presented in this study. Laser micro-machining was applied to fabricate GaN LED chip with angled sidewalls (ALED). The inclined sapphire sidewalls were coated with highly reflective silver film which functions as an efficient light out-coupling medium for photons within the LED structure. Thus, more laterally-propagating photons can be redirected to the upward direction of the ALED with silver coating (Ag-ALED). Performances of the Ag-ALED, ALED and conventional planar GaN LED were evaluated. At an injection current of 30 mA, the light output intensity of Ag-ALED was significantly improved by 97% and 195% as compared to ALED and conventional planar LED, respectively. The corresponding wall-plug efficiency of Ag-ALED was remarkably increased by 95% and 193% as compared to ALED and conventional planar LED, respectively. The results of this study demonstrated that the Ag-ALED showed a pronounced increase in light output intensity compared to conventional planar LED, which may have many potential applications in the field of display engineering.     

Humidity control porous ceramics prepared from waste and porous materials

This study investigated the feasibility of generating humidity control porous ceramics by sintering a mixture of volcanic ash, weathered volcanic ash, and waste glass. The sintering conditions, including sintering time, sintering temperature, and various mixed portions of glass amendment, were tested. The final ceramics were analyzed for their pore distribution, pore volume, adsorption and desorption characteristics, and bending strength. The results indicate that the pore size of the volcanic ash ceramics tends to distribute in the range from 70 to 100 nm, whereas that of the weathered volcanic ash ceramics is in the range of 7-9 nm. The humidity controlling conditions of the ceramics take advantage of the inherent porosity of the natural materials. The bending strengths in both cases were all satisfying with the fractural intensity specification of ceramics (> 6 Mpa).     

A proportional-integral-differential control of flow over a circular cylinder

In the present study, we apply proportional (P), proportional-integral (PI) and proportional-differential (PD) feedback controls to flow over a circular cylinder at Re=60 and 100 for suppression of vortex shedding in the wake. The transverse velocity at a centreline location in the wake is measured and used for the feedback control. The actuation (blowing/suction) is provided to the flow at the upper and lower slots on the cylinder surface near the separation point based on the P, PI or PD control. The sensing location is varied from 1d to 4d from the centre of the cylinder. Given each sensing location, the optimal proportional gain in the sense of minimizing the sensing velocity fluctuations is obtained for the P control. The addition of I and D controls to the P control certainly increases the control performance and broadens the effective sensing location. The P, PI and PD controls successfully reduce the velocity fluctuations at sensing locations and attenuate vortex shedding in the wake, resulting in reductions in the mean drag and lift fluctuations. Finally, P controls with phase shift are constructed from successful PI controls. These phase-shifted P controls also reduce the strength of vortex shedding, but their results are not as good as those from the corresponding PI controls.     

Strength prediction and failure modes of concrete specimens subjected to the split test

This paper deals with modelling and test of concrete specimens subjected to the Brazilian split test. Based on the fictitious crack concept, a simple model for the crack propagation process in the splitting plane is developed. From the model, it is possible to determine the distribution of residual tensile strength as crack propagation take place. The residual tensile strength is thereafter used in a rigid plastic analysis of the splitting failure. Based on this combined approach, the ultimate load may either be governed by crack propagation or by a plastic failure, which then terminates the crack growth process. It is shown that the model is able to replicate a number of experimental observations. This includes size effect and influence of loading width.     

PEGylated antibody in organic media

Antibodies were covalently conjugated with poly(ethylene glycol) (PEG) and the properties of the PEGylated antibodies in organic media were investigated. Two types of monoclonal antibody were used in this study. One was a monoclonal antibody (abzyme) that was prepared against a hapten mimicking a transition state of hydrolysis. Another was a monoclonal antibody against estrogen, which is not soluble in water. By electrophoresis and mass spectral analysis, the covalent conjugation with PEG chains was confirmed. The PEGylated antibodies bound to antigens and the PEGylated abzyme catalyzed a hydrolysis reaction in an aqueous solution. The PEGylated antibodies were soluble in dichloromethane and acetone and interacted with antigen either in dichloromethane or in acetone. In conclusion, PEGylated antibodies can be employed as analytical tools for water-insoluble analytes.