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71.
E Donois V del Marmol A Ta?eb G Ghanem JE Surlève-Bazeille 《Canadian Metallurgical Quarterly》1998,20(4):275-287
Chemical antioxidants and catalase have been shown to be ineffective in improving the motility of ram spermatozoa in a chemically-defined diluent (RSD-1). In an attempt to identify the biochemical basis of this observation, the activity of aromatic amino acid oxidase (AAAO), the enzyme responsible for generation of hydrogen peroxide in ram and bull spermatozoa, has been investigated. Ram spermatozoa contained higher levels of AAAO activity than bull spermatozoa, although the physico-chemical properties of the enzyme were generally similar in both species. Components of the medium had a marked effect upon AAAO activity. In the presence of glutamate and 3-(N-morpholino)propanesulfonic acid (MOPS), AAAO activity was decreased. Pyruvate appeared to increase AAAO activity. This was due to the ability of this substance to destroy hydrogen peroxide. Pyruvate in RSD-1 works as an effective antioxidant and therefore eliminates the need for other antioxidants in the semen diluent. 相似文献
72.
Natural fiber reinforced composites is an emerging area in polymer science. These natural fibers are low cost fibers with low density and high specific properties. These are biodegradable and nonabrasive. The natural fiber composites offer specific properties comparable to those of conventional fiber composites. However, in development of these composites, the incompatibility of the fibers and poor resistance to moisture often reduce the potential of natural fibers, and these draw backs become critical issue. Wood‐plastic composites (WPC) are a relatively new class of materials and one of the fastest growing sectors in the wood composites industry. Composites of wood in a thermoplastic matrix (wood–plastic composites) are considered a low maintenance solution to using wood in outdoor applications. WPCs are normally made from a mixture of wood fiber, thermoplastic, and small amounts of process and property modifiers through an extrusion process. In this study, Wood–plastic composites (WPC) are produce by adding a maleic anhydride modified low density polyethylene coupling agent to improve interfacial adhesion between the wood fiber and the plastic. Mixing is done with twin screw extruder. Subsequently, tensile strength, the modulus of elasticity, % elongation, hardness, Izod impact strength, melt flow index (MFI), and heat deflection temperature (HDT) are determined. Thermal transition temperatures and microstructure are determined with DSC and SEM, respectively. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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74.
Xiaoqin Yang Huy Q. Ta Huimin Hu Shuyuan Liu Yu Liu Alicja Bachmatiuk Jinping Luo Lijun Liu Jin-Ho Choi Mark H. Rummeli 《Advanced functional materials》2021,31(38):2104340
In this study, in situ transmission electron microscopy is performed to study the interaction between single (monomer) and paired (dimer) Sn atoms at graphene edges. The results reveal that a single Sn atom can catalyze both the growth and etching of graphene by the addition and removal of C atoms respectively. Additionally, the frequencies of the energetically favorable configurations of an Sn atom at a graphene edge, calculated using density functional theory calculations, are compared with experimental observations and are found to be in good agreement. The remarkable dynamic processes of binary atoms (dimers) are also investigated and is the first such study to the best of the knowledge. Dimer diffusion along the graphene edges depends on the graphene edge termination. Atom pairs (dimers) involving an armchair configuration tend to diffuse with a synchronized shuffling (step-wise shift) action, while dimer diffusion at zigzag edge terminations show a strong propensity to collapse the dimer with each atom diffusing in opposite directions (monomer formation). Moreover, the data reveals the role of C feedstock availability on the choice a single Sn atom makes in terms of graphene growth or etching. This study advances the understanding single atom catalytic activity at graphene edges. 相似文献
75.
Kinetics of reversible addition–fragmentation transfer (RAFT) miniemulsion polymerization of styrene using dibenzyl trithiocarbonate as RAFT reagent and costabilizer
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The roles of dibenzyl trithiocarbonate (DBTTC) as both costabilizer and reversible addition–fragmentation transfer (RAFT) reagent in RAFT miniemulsion polymerizations of styrene were investigated. The effectiveness of DBTTC costabilizer in retarding Ostwald ripening involved in the storage stability of miniemulsion is comparable to that of conventional low‐molecular‐weight costabilizers such as cetyl alcohol, but inferior to that of hexadecane. The major variables chosen for studying kinetics of RAFT miniemulsion polymerizations include the type of initiators and levels of DBTTC and surfactant. At a constant level of DBTTC, the rate of polymerization for benzoyl peroxide (BPO)‐initiated polymerization is slower than that for sodium persulfate (SPS)‐initiated polymerization. Furthermore, the polymerization rate decreases with increasing level of DBTTC for polymerizations initiated by BPO (or SPS). It is the monomer droplet nucleation that governs BPO‐initiated polymerizations. In contrast, for SPS‐initiated polymerizations, the probability for homogeneous nucleation to take place is greatly increased, especially for polymerizations with lower levels of DBTTC and higher levels of surfactant. © 2015 Society of Chemical Industry 相似文献
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77.
Extended access control lists (ACLs) are used to filter packets for network security. However, in current network frameworks, ACL rules are not transferred simultaneously with devices that move across network segments. The Internet Engineering Task Force proposed the Locator/Identifier Separation Protocol (LISP), which enables routers (xTRs) to configure ACL rules for blocking immobile endpoint identifiers (EIDs). However, when an EID moves from the original xTR to a new xTR, the ACL rules at the original xTR cannot be transferred with the EID. Thus, the new xTR lacks the corresponding ACL rules to effectively block the EID, resulting in security risks. The highlights of this study are as follows. First, a method is proposed for dynamically transferring ACL rules in LISP environments and frameworks. Second, the map‐register and map‐notify protocols were combined to encapsulate and transfer the ACL rules and thus obviate an additional process required to transfer these rules. Third, the experimental results verified that the proposed method can be used to achieve synchronized security protection in an LISP environment involving cross‐segment EID movements. 相似文献
78.
Kun‐Ching Shen Chen‐Ta Ku Chiieh Hsieh Hao‐Chung Kuo Yuh‐Jen Cheng Din Ping Tsai 《Advanced materials (Deerfield Beach, Fla.)》2018,30(21)
Given the high demand for miniaturized optoelectronic circuits, plasmonic devices with the capability of generating coherent radiation at deep subwavelength scales have attracted great interest for diverse applications such as nanoantennas, single photon sources, and nanosensors. However, the design of such lasing devices remains a challenging issue because of the long structure requirements for producing strong radiation feedback. Here, a plasmonic laser made by using a nanoscale hyperbolic metamaterial cube, called hyperbolic metacavity, on a multiple quantum‐well (MQW), deep‐ultraviolet emitter is presented. The specifically designed metacavity merges plasmon resonant modes within the cube and provides a unique resonant radiation feedback to the MQW. This unique plasmon field allows the dipoles of the MQW with various orientations into radiative emission, achieving enhancement of spontaneous emission rate by a factor of 33 and of quantum efficiency by a factor of 2.5, which is beneficial for coherent laser action. The hyperbolic metacavity laser shows a clear clamping of spontaneous emission above the threshold, which demonstrates a near complete radiation coupling of the MQW with the metacavity. This approach shown here can greatly simplify the requirements of plasmonic nanolaser with a long plasmonic structure, and the metacavity effect can be extended to many other material systems. 相似文献
79.
Meng Xia Min Xu Chuan-en Lin Ta Ying Cheng Huamin Qu Xiaojuan Ma 《Computer Graphics Forum》2020,39(3):511-522
Problem-solving dynamics refers to the process of solving a series of problems over time, from which a student's cognitive skills and non-cognitive traits and behaviors can be inferred. For example, we can derive a student's learning curve (an indicator of cognitive skill) from the changes in the difficulty level of problems solved, or derive a student's self-regulation patterns (an example of non-cognitive traits and behaviors) based on the problem-solving frequency over time. Few studies provide an integrated overview of both aspects by unfolding the problem-solving process. In this paper, we present a visual analytics system named SeqDynamics that evaluates students ‘problem-solving dynamics from both cognitive and non-cognitive perspectives. The system visualizes the chronological sequence of learners’ problem-solving behavior through a set of novel visual designs and coordinated contextual views, enabling users to compare and evaluate problem-solving dynamics on multiple scales. We present three scenarios to demonstrate the usefulness of SeqDynamics on a real-world dataset which consists of thousands of problem-solving traces. We also conduct five expert interviews to show that SeqDynamics enhances domain experts’ understanding of learning behavior sequences and assists them in completing evaluation tasks efficiently. 相似文献
80.
An Braeken Pardeep Kumar Madhusanka Liyanage Ta Thi Kim Hue 《The Journal of supercomputing》2018,74(4):1695-1714
In a multi-server authentication environment, a user only needs to register once at a central registration place before accessing the different services on the different registered servers. Both, from a user point of view as for the management and maintenance of the infrastructure, these types of environments become more and more popular. Smartcard- or smartphone-based approaches lead to more secure systems because they offer two- or three-factor authentication, based on the strict combination of the user’s password, the user’s biometrics and the possession of the device. In this paper, we propose an efficient anonymous authentication protocol in multiple server communication networks, called the EAAM protocol, which is able to establish user anonymity, mutual authentication, and resistance against known security attacks. The novelty of the proposed scheme is that it does not require a secure channel during the registration between the user and the registration center and is resistant to a curious but honest registration system. These features are established in a highly efficient way with the minimum amount of communication flows between user and server during the establishment of the secret shared key and by using light-weight cryptographic techniques such as Chebyshev chaotic map techniques and symmetric key cryptography. The performance and security of the protocol are analyzed and compared with the latest new proposals in this field. 相似文献