水泥工厂长形堆场和圆形堆场选型分析

通常用于石灰石和原煤及辅助原料等预均化处理和存储的预均化堆场,其投资造价较高,占地面积大,且对征地和总图布置有明显的影响。目前,水泥工厂预均化堆场有屋盖落地或抬高的长形堆场和圆形堆场二类,其机械设备成本、土建成本大和生产运行电耗成本差别大,因此选择合理的堆场形式就非常重要。以已经建成的实际工程决算数据为基础,在满足类似工艺参数要求的情况下,进行落地长堆和抬高圆堆的投资成本、建设用地、生产运行方面对不同的堆场做了对比分析;在此基础上,进行了选型优劣的排序。     

环氧树脂改性硅丙乳液的制备及水性涂料的研究

采用半连续单体滴加乳液聚合法制得稳定性好,凝胶率少,转化率高,综合性能良好的环氧树脂改性硅丙乳液。通过实验确定了所需的最佳条件,即阴离子与非离子乳化剂的最佳配比是2∶1,适宜温度78~80℃,引发剂的最佳用量0.7%,有机硅的最佳用量3%,环氧树脂最佳用量7%。并且以环氧树脂E-44改性硅丙乳液为主要成膜物质,制备了水性隔热防腐涂料。经检测,涂料的各项性能均满足国家技术标准。     

浮法玻璃领域专利技术分析

文章分析了国内企业关于浮法玻璃申请量的排名,与浮法玻璃生产线的企业拥有量排名存在差异的原因。并以浮法玻璃生产线拥有量最多的前7家企业为研究对象,检索了该企业中专利申请的领域分布,研究了玻璃行业在当前形势下,发展自主知识产权、扩展玻璃深加工和应用技术的必要性。     

糠醇聚合物的制备研究

文章对糠醇(FA)聚合物的制备进行了研究。研究结果表明:糠醇的聚合反应受到反应时间、温度和催化剂量的较大影响。延长反应时间、提高反应温度或增大催化剂用量,均可增大糠醇聚合物的分子量,使其粘度增大。同时,对甲苯磺酸对糠醇(FA)聚合物具有较好的固化效果。     

《高分子专业综合实验》教学体系构建和探索

文章在深入分析本校高分子材料与工程专业的培养目标及本校教学条件现状基础上,从教学内容设计、课程教学实施、课后教学延伸和教学考核四个方面探索新开课程《高分子专业综合实验》的构建,提出了一套切实可行的、完整的课程教学体系。     

天然气长输管道末段压力变化研究

阐述了长输管道末段的基本功能,并对长输管道末段的储气能力对管道末段长度以及压力变化的影响进行了论述,包括储气初期与储气终了末段管道压力变化、副管添加进行了研究,研究采用了建模计算、假设、迭代、校核等方法。     

乙二胺的生产及其市场发展状况与前景

乙二胺是一种用途非常广泛的重要化工原料,本文对乙二胺的生产技术进行了详细的介绍,论述了乙二胺在国内的市场发展状况,并在以上论述的基础上预测了其发展前景。     

Diastereo‐ and Enantioselective Synthesis of Chiral Pyrrolidine‐Fused Spirooxindoles via Organocatalytic [3+2] 1,3‐Dipolar Cycloaddition of Azomethine Ylides with Maleimides

In the presence of a Cinchona alkaloid‐based squaramide organocatalyst, the [3+2] cycloaddition of isatin‐derived azomethine ylides with maleimides proceeded readily, thus delivering the desired pyrrolidine‐fused spirooxindoles in 61–89% yields with >20:1 dr and 12 to >99 % ee. The absolute configuration of 5‐chloro‐1,5′‐dimethyl‐3′‐phenyl‐3′,3a′‐dihydro‐2′H‐spiro[indoline‐3,1′‐pyrrolo[3,4‐c]pyrrole]‐2,4′,6′(5′H,6a′H)‐trione was unambiguously determined by means of X‐ray single crystal structure analysis. The reaction mechanism was hypothesized to account for the enantioselective formation of 5‐chloro‐1,5′‐dimethyl‐3′‐phenyl‐3′,3a′‐dihydro‐2′H‐spiro[indoline‐3,1′‐pyrrolo[3,4‐c]pyrrole]‐2,4′,6′(5′H,6a′H)‐trione.

     

二氧化碳汽提法池式冷凝器的设计缺陷

对斯塔米卡邦改进型二氧化碳汽提工艺中池式高压甲铵冷凝器管侧隔板腐蚀问题进行了剖析,指出池式冷凝器管侧隔板的设计缺陷,并提出相应防腐措施.     

Discrete-time sliding mode control of flexible rotor-magnetic bearing systems

This paper is concerned with the computer-based sliding mode control of flexible rotor—magnetic bearing systems (FR-MBS). The plant dynamics consisting of actuator dynamics and flexible rotor dynamics are described. The reduced-order model for controller design is given by eliminating higher-order modes of the mechanical and electrical magnetic interaction system. A discrete-time sliding mode controller with a new robust reduced-order variable structure system (VSS) observer is proposed and its robust performance is evaluated with several simulations based on a calculation model. This digital controller is implemented to replace a linear analogue PID compensator. Levitation tests using the proposed digital controller are performed and compared with those of the PID compensator. The unstable modes can be easily controlled with the good stability and the spillover phenomena due to ignored higher-order modes are not generated. It is indicated that the discrete-time sliding mode control has robustness to the model parameter variations and external disturbances. Using the discrete time sliding mode controller with the reduced-order VSS observer, the test rig of the magnetic bearing system can be successfully rotated in a speed range of 0–35 000 rpm, which includes the first critical shaft frequency of the flexible rotor.