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排序方式: 共有619条查询结果,搜索用时 15 毫秒
21.
Tina Marolt Cebasek Jakob Likar 《土木工程与建筑:英文版》2014,(11):1457-1466
The design procedure is made for a mine shaft where permanent underground facilities are interconnected. The highly faulted grounds were identified using empirical and semi-empirical theories. Furthermore, the behavior types are presented. This paper presents excavation and support methods in such ground conditions and the calculations results show that the installation of the yielding elements have an effect on support elements and prevent shotcrete damage during the curing stage. Different numerical analyses carried out showed that, with the yielding elements installed, the total displacements increase but the final axial force reduces, and therefore, the characteristic compressive strength of shotcrete is not exceeded. The calculation results of ground loads and displacements on the designed support system are presented with a 3D numerical geo-mechanical model adopted for highly faulted ground surrounding deeper complex underground structures. 相似文献
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Bor‐Sen Chiou Diana Valenzuela‐Medina Mark Wechsler Cristina Bilbao‐Sainz Artur K. Klamczynski Tina G. Williams Delilah F. Wood Greg M. Glenn William J. Orts 《应用聚合物科学杂志》2015,132(10)
Torrefied almond shells and wood chips were incorporated into polypropylene as fillers to produce torrefied biomass‐polymer composites. The composites were prepared by extrusion and injection molding. Response surface methodology was used to examine the effects of filler concentration, filler size, and lignin factor (relative lignin to cellulose concentration) on the material properties of the composites. The heat distortion temperatures, thermal properties, and tensile properties of the composites were characterized by thermomechanical analysis, differential scanning calorimetry, and tensile tests, respectively. The torrefied biomass composites had heat distortion temperatures of 8–24°C higher than that of neat polypropylene. This was due to the torrefied biomass restricting mobility of polypropylene chains, leading to higher temperatures for deformation. The incorporation of torrefied biomass generally resulted in an increase in glass transition temperature, but did not affect melting temperature. Also, the composites had lower tensile strength and elongation at break values than those of neat polypropylene, indicating weak adhesion between torrefied biomass and polypropylene. However, scanning electron microscopy results did indicate some adhesion between torrefied biomass and polypropylene. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41582. 相似文献
24.
Živec Tina Anžur Andreja Verbovšek Timotej 《Bulletin of Engineering Geology and the Environment》2019,78(3):1631-1643
Bulletin of Engineering Geology and the Environment - Terrestrial laser scanning (TLS) was performed in tectonically undisturbed flysch in the Elerji quarry (south-west Slovenia), which represents... 相似文献
25.
Genoveva Buelna Mutlu Ulutagay-Kartin Tina M. Nenoff 《Chemical Engineering Communications》2006,193(5):606-619
Alkylation reactions of benzene with propylene using heterogeneous catalysts H+-β zeolite, MCM-22, and ZSM-5 were studied for their affinity for cumene production. This work focused on the gas-phase reaction using different crystalline catalysts at several temperatures and amounts of reactants using both batch and continuous fixed-bed reactors. The properties of baseline commercial H+-β catalysts versus versions modified with Ga, La, and Pt were studied. Quantitative analysis of product mixture was performed by gas chromatography. For the batch reactor, β-zeolite produced the highest cumene yield and selectivity of 72% and 92%, respectively, at 225°C. At this temperature, a benzene:propylene dilution of 7:1 molar ratio was the optimum. For the continuous system, cumene production is favored at lower space velocities, higher benzene-to-propylene ratio, and temperatures close to 225°C. Ga modification of the H+-β zeolite significantly enhanced cumene yield in the continuous fixed-bed reactor at 225°C, from 27% of the unmodified β-zeolite to 36% for the Ga-modified one. The life span of modified β-catalysts was studied in the fixed-bed reactor for the first eight hours of reaction. 相似文献
26.
Robert Dittmer Wook Jo Jürgen Rödel Sergei Kalinin Nina Balke 《Advanced functional materials》2012,22(20):4208-4215
Piezoresponse force microscopy (PFM) is used to afford insight into the nanoscale electromechanical behavior of lead‐free piezoceramics. Materials based on Bi1/2Na1/2TiO3 exhibit high strains mediated by a field‐induced phase transition. Using the band excitation technique the initial domain morphology, the poling behavior, the switching behavior, and the time‐dependent phase stability in the pseudo‐ternary system (1–x)(0.94Bi1/2Na1/2TiO3‐0.06BaTiO3)‐xK0.5Na0.5NbO3 (0 <= x <= 18 mol%) are revealed. In the base material (x = 0 mol%), macroscopic domains and ferroelectric switching can be induced from the initial relaxor state with sufficiently high electric field, yielding large macroscopic remanent strain and polarization. The addition of KNN increases the threshold field required to induce long range order and decreases the stability thereof. For x = 3 mol% the field‐induced domains relax completely, which is also reflected in zero macroscopic remanence. Eventually, no long range order can be induced for x >= 3 mol%. This PFM study provides a novel perspective on the interplay between macroscopic and nanoscopic material properties in bulk lead‐free piezoceramics. 相似文献
27.
Cationic Nanogels: Reduction‐Sensitive Dextran Nanogels Aimed for Intracellular Delivery of Antigens (Adv. Funct. Mater. 20/2015)
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28.
Nina Hammer Karina Mathisen Tina Zscherpe De Chen Magnus R?nning 《Topics in Catalysis》2011,54(13-15):922-930
The impact of thermal treatment at various preparation stages of carbon supported Au/TiO2 catalysts prior to oxidation of CO in the presence and absence of hydrogen was studied. An increase in catalytic activity for thermally treated samples due to a more ordered structure of TiO2 was observed. A reversible deactivation of the catalysts occurred in the absence of hydrogen. However, the activity was restored at preferential CO oxidation conditions in presence of hydrogen. 相似文献
29.
In this work, we investigated the effects of quantum dot (QD) annealing (as-grown, 600°C-annealed, and 750°C-annealed) on the preliminary performances of 1.3-μm InAs-InGaAs-GaAs quantum dot electroabsorption modulators (QD-EAMs). Both extinction ratio and insertion loss were found to vary inversely with the annealing temperature. Most importantly, the 3-dB response of the 750°C-annealed lumped-element QD-EAM was found to be 1.6 GHz at zero reverse bias voltage - the lowest reverse bias voltage reported. We believe that this work will be beneficial to researchers working on on-chip integration of QD-EAMs with other devices since energy consumption will be an important consideration. 相似文献
30.
Lütke-Eversloh T Fischer A Remminghorst U Kawada J Marchessault RH Bögershausen A Kalwei M Eckert H Reichelt R Liu SJ Steinbüchel A 《Nature materials》2002,1(4):236-240
The development of non-petrochemical sources for the plastics industry continues to progress as large multinationals focus on renewable resources to replace fossil carbon. Many bacteria are known to accumulate polyoxoesters as water-insoluble granules in the cytoplasm. The thermoplastic and/or elastomeric behaviour of these biodegradable polymers holds promise for the development of various technological applications. Here, we report the synthesis and characterization of microbial polythioesters (PTEs), a novel class of biopolymers of general technological relevance. Biosynthesis of PTE homopolymers was achieved using a recombinant strain of Escherichia coli that expressed a non-natural pathway consisting of a butyrate kinase, a phosphotransbutyrylase, and a PHA synthase. Different homopolymers were produced, consisting of either 3-mercaptopropionate, 3-mercaptobutyrate, or 3-mercaptovalerate repeating units, if the respective mercaptoalkanoic acids were provided as precursor substrates to the fermentative process. The PTEs contributed up to 30% (w/w) of the cellular dry weight and were identified as hydrophobic inclusions in the cytoplasm. The chemical and stereochemical homogeneity of the purified PTEs were identified by different methods, and the estimated physical properties were compared to the oxypolyester equivalents, revealing low crystalline order and, for the poly(3-mercaptopropionate) improved thermal stability. The ability to produce PTEs through a biosynthetic route opens up new avenues in the field of biomaterials. 相似文献