石灰石在煤气化过程中的催化和固硫作用

基于CaO在煤气化中的催化和固硫作用,以及石灰石加热分解的性质,石灰石有可能作为煤气化过程中的催化剂和固硫剂。本文根据国内外对石灰石在煤燃烧和煤气化中作用的研究,从石灰石结构、Ca/C,Ca/S,可能的反应机理等几个方面进行了介绍和分析,并指出需进一步研究的内容。     

Correlation of the reactivity,the active surface area and the total surface area of thin films of pyrolytic carbon

Using thin films of pyrolytic carbon the rate of the reaction with oxygen has been measured over the temperature range 625–740°C and at pressures of oxygen from 6–100 torr. The active surface area (ASA) of the films was measured from the total concentration of strongly-bound complexes with oxygen on the surface and the relative total surface area (TSA) was measured by low-temperature adsorption of nitrogen. A maximum in reactivity and in ASA was observed for films of average thickness of about 20 nm with a TSA of about 30 m² g^?1. At the maximum the ASA and TSA were essentially equal. The results are interpreted in terms of the mechanism of formation of pyrolytic carbon in the initial stages.     

纳米SiO2粉体的制备与研究

纳米SiO2粉体的制备是以硅酸钠和盐酸为原料，添加适宜的稳定剂(非离子表面活性剂)和分散剂，在适宜的pH值和温度下，采用化学沉淀法合成。研究表明，要得到性能优良纳米的SiO2粉体，最佳工艺条件为：温度20～40℃，pH=6，反应液质量浓度P1=20g／L，P2=1．20g／L，反应时间15min。结果表明：制备的纳米SiO2粒径30～50nm，比表面积大，分散性好，质量优良，可达到产业化的生产。     

HDPE新牌号树脂的研究

根据扬子石化公司开发HDPE新牌号产品的生产经验,从分子量及分子量分布与树脂性能的关系、密度对HDPE性能的影响、HDPE的共聚改性、HDPE的共混改性、添加剂与HDPE改性等5个方面讨论了HDPE新牌号产品开发的方法。     

火电厂发电机组常见的电气故障与维修研究

发动机组是火电厂各生产环节中重要的组成部分,其运行效率不但决定了生产效率,还关系着各类生产资源应用的有效性,对实现节能降耗具有重要意义,所以,必须加强对其运行稳定性的管理。分析了火电厂发动机组常见电气故障,并提出了相应的解决措施。     

Robust state estimation for uncertain linear systems with deterministic input signals

In this paper, we investigate state estimations of a dynamical system in which not only process and measurement noise, but also parameter uncertainties and deterministic input signals are involved. The sensitivity penalization based robust state estimation is extended to uncertain linear systems with deterministic input signals and parametric uncertainties which may nonlinearly affect a state-space plant model. The form of the derived robust estimator is similar to that of the well-known Kalman filter with a comparable computational complexity. Under a few weak assumptions, it is proved that though the derived state estimator is biased, the bound of estimation errors is finite and the covariance matrix of estimation errors is bounded. Numerical simulations show that the obtained robust filter has relatively nice estimation performances.     

Photopolymerization of methyl methacrylate initiated by benzophenone/aromatic tertiary amines

Summary The photopolymerization of methyl methacrylate initiated by benzophenone-tertiary aromatic amines was studied under irradiation at 365 nm. The initiating amino radicals were investigated with combined ESR and spin-trapping method. The rate of polymerization for different amines was found in the sequence of p-hydroxymethyl-N,N-dimethylaniline>N,N-dimmethyltoluidine>N,N-dimethylaniline>p-methyl-N,N-dihydroxyethylaniline. The influence of diphenylmethanol on the polymerization reveals the incapacity of the benzophenone ketyl radical to initiate, while the amino end-group was detected in the polymers. This end-group can interact with benzophenone again, leading to initiate further polymerization to give a copolymer.     

CaO-SiO2系玻璃的析晶动力学研究

利用溶胶-凝胶法制得CaO-SiO2系基础玻璃,通过差热分析曲线分析质量比为CaO-SiO2玻璃的析晶能力。经分析,其析晶活化能E=457.1kJ·mol-1,而晶化生长指数是随升温速率的不同而不同,速率越大,晶化生长指数越小。     

Containment control of multi‐agent systems by exploiting the control inputs of neighbors

This paper studies the containment control problem for multi‐agent systems consisting of multiple leaders and followers connected as a network. The objective is to design control protocols so that the leaders will converge to a certain desired formation while the followers converge to the convex hull of the leaders. A novel protocol is proposed by exploiting the control input information of neighbors. Both continuous‐time and discrete‐time systems are considered. For continuous‐time systems, it is proved that the protocol is robust to any constant delays of the neighbors' control inputs. For discrete‐time systems, a sufficient condition on the feedback gain for the containment control is given in terms of the time delay and graph information. Some numerical examples are given to demonstrate the results. Copyright © 2013 John Wiley & Sons, Ltd.