Preparation,characterization, and adsorption properties for metal ions of a novel chelating resin containing sulfoxide and diethylene glycol

A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg²⁺, Ag⁺, Cu²⁺, Zn²⁺, and Pb²⁺ at various pH values were determined. The maximum adsorption capacities for Hg²⁺ and Ag⁺ were 1.56 and 0.75 mmol g^?1 respectively. The resin had high selectivity for Hg²⁺ and Ag⁺ over the pH range 1.0–7.0. The adsorption capacities for Hg²⁺ and Ag⁺ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg²⁺ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006     

冷却器盘管失效分析及防范措施

本文介绍了冷却器盘管破裂泄漏的情况，分析了失效破坏的原因，并提出防止冷却器盘管破裂泄漏的措施。     

T.C.Powcrs模型若干问题的研究

从T.C.Powers水泥石模型出发,提出了描述水泥混凝土材料初始结构的主要参数是初始孔隙率。由此池绎了水泥浆体组成与结构的定量关系,比原模型有更明了的物理意义,研究结果表明,Powers模型在高孔隙率范围内具有适用性,但不适用于低孔隙率硬化水泥浆体,且在低孔隙率条件下不存在28％的固有凝胶孔隙率,水化产物成份和性质是渐变的。     

钴钼系耐硫变换催化剂硫化与水解问题探讨

钴钼系耐硫变换催化剂硫化与水解问题一直受到人们的关注。许多研究人员对硫化水解做了大量的报道，但都以热力学平衡为基础，计算出的结果存在理论和实际相背离。因此，作者想从化学平衡和动力学双重角度对硫化与水解问题做一探讨。     

硫磺延伸产品的现状及展望

介绍了硫脲、甲硫醇、蛋氨酸、硫肥、含硫建筑材料、不溶性硫磺、Na-S电池等硫磺延伸产品情况.指出硫酸企业要以硫磺、CS2、SO2、SO3和硫酸为原料,构建多层次、多元化的精细硫化工产业链,使硫酸企业走上特色化工和精细化工之路.     

硫醇自组装膜的电化学研究进展

综述了在金电极上硫醇自组装膜的电化学表征方法，性质和应用，介绍了自组装膜上的电子传递机理，并进行了简要的展望。     

Fabrication and amplification of Rhodamine B‐doped step‐index polymer optical fiber

A step‐index polymer optical fiber (SI POF) containing Rhodamine B in poly(methyl methacrylate) (PMMA) has been fabricated by a preform technique. Fluorescence of different fiber lengths were observed and discussed. A high gain (23 dB) for a SI POF with 60‐cm length, 400‐μm diameter was obtained. The Rhodamine B content of the doped SI POF is 5 ppm‐wt. The signal wavelength providing the highest gain for a 60 cm SI POF is around 630 nm, and the optimum fiber length is about 60 cm at 10 kW launched pump power. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 681–685, 2004     

Hydrothermal products of the C3MS2-C12A7-MgO system

The autoclave products of reduced steel-slag of an electronic furnace mainly containing C₃MS₂ phase were detected. The hydrothermal products of this slag included calcio-chondrodite, brucite, and hydrogarnet phases. When suitable (CaO + MgO)/SiO₂ molar ratios were chosen, C₃MS₂ can react with SiO₂ to produce calcium silicate hydrates tobermorite, xonotlite, gyrolite, and truscottite phases with different saturated water vapor pressures. The phase brucite was present along with tobermorite, whereas phases Mg-xonotlite, Mg-gyrolite, and Mg-truscottite can rarely coexist with brucite. Hydrogarnet phase disappeared when Mg-truscottite was formed.     

石灰石在煤气化过程中的催化和固硫作用

基于CaO在煤气化中的催化和固硫作用,以及石灰石加热分解的性质,石灰石有可能作为煤气化过程中的催化剂和固硫剂。本文根据国内外对石灰石在煤燃烧和煤气化中作用的研究,从石灰石结构、Ca/C,Ca/S,可能的反应机理等几个方面进行了介绍和分析,并指出需进一步研究的内容。