Canola oil was hydrogenated using a mixture of homogeneous methyl benzoate-Cr(CO)3 and heterogeneous nickel catalysts. The effect of the methyl benzoate-Cr(CO)3_to-nickel ratio on the activity, specific isomerization index, linoleate and linolenate selectivities, and fatty acid composition
was evaluated, and the results compared with those obtained with commercial nickel catalyst and methyl benzoate-Cr(CO)3 used individually. At higher chromium-to-nickel ratios the activity of nickel was inhibited and the system behaved essentially
like the pure chrome complex, while at low chromium-to-nickel ratios the characteristics of the nickel predominated. In a
short transition zone relatively high reaction rates were obtained with significantly reducedtrans-isomer levels in the product. In a broader sense, it may be possible to combine a homogeneous and heterogeneous catalyst
while retaining the advantages of both. We may thus be able to design catalyst systems for specific applications. 相似文献
Zusammenfassung Die rasante Entwicklung des Internets bewirkt neben einer sich verst?rkenden Internationalisierung von Terrorismus und Organisierter
Kriminalit?t einen Strukturwandel weltweiter Kommunikation und Datenspeicherung. 相似文献
The morphology and electronic transport of ultrathin Au films with thicknesses d = 1 ? 5 monolayers (ML) deposited on Si(111)7 × 7 surfaces is investigated by in situ scanning tunneling microscopy and electrical resistance measurements for temperatures T = 2 ? 300 K. With decreasing film thickness, i.e. decreasing sheet conductance Gs, a transition from a weakly conducting regime described by a logarithmic temperature dependence to an insulating regime occurs. In the insulating regime, the temperature dependence is described by Gs ∝ exp[?(T0/T)n] with an exponent n which gradually changes from 0.69 to 1 with decreasing film thickness. In contrast, for the Si(111)6 × 6-Au reconstruction obtained after annealing, an exponent n = 1/2 is found suggesting the formation of a soft Coulomb gap due to electron-electron interaction. PACS numbers: 68.37.-d, 68.55.-a, 73.50.-h, 73.25.+i, 81.15.-z 相似文献
SiGe-HBTs have the potential for outstanding analog and digital or mixed-signal high frequency circuits widely based on standard Si technology. Here we review on MBE grown transistors and circuits. Processes and results of a research-like SiGe HBT and two possible production relevant HBT versions are presented. The high frequency results with fmax and fT up to 120 GHz and a minimum noise figure of 0.9 dB at 10 GHz demonstrate the advantage of using MBE samples with steep and high base doping and high germanium contents. A comparison to the concept of reported low doped, low germanium and triangular profiled SiGe base layers, realized by UHV-CVD, is given. In addition, some circuit demonstrators of SiGe-ICs will be presented. 相似文献
Atomic structures of crystallographic shear planes (CSPs) in nanocrystalline thin films of semiconductor SnO2 were investigated by high-resolution electron microscopy. The films were prepared by electron beam evaporation in high vacuum (10–6 torr) and followed by annealing in synthetic air at 700 °C for 1–2 H. CSPs with the displacement vector of [1/2 0 1/2] were observed in the planes parallel to (¯101), (110) and (¯3¯21). Most of the CPSs were found to terminate or interact with each other within SnO2 crystallites. Partial dislocations exist at terminal places of CSPs or along intersecting lines of CSPs. CSP steps were also observed. Structural models of these defects have been proposed. Based on analysis of experimental data, it has been suggested that the Sn/O ratio at CSPs which are not parallel to their displacement vector, at cores of partial dislocations and at CSP steps, is higher than that of the perfect structure, that is, these defects are able to provide extra free electrons with the films. 相似文献
This report contains results of a finite element study aiming to identify the influence of loading history and geometry for cracked pipes subjected to complex loading. The experiments have been performed within the International Piping Integrity Research Group (IPIRG) Program. The majority of the numerically analyzed experiments were conducted on straight pipes with an outside diameter of 168 mm and containing a large circumferential through-wall crack. The considered pipes were loaded in four-point bending under displacement control and at a temperature of 288°C. The types of loading were combinations of either quasi-static or dynamic and also monotonic or cyclic loading with different loading ratios R. Some analyses were also performed on surface-cracked pipes subjected to slow, monotonic loading.
In the finite element study, 20-node solid elements were used for the through-wall cracked pipes and a combination of shell and non-linear line spring elements for the surface-cracked pipes. Stable crack growth was simulated by gradual node relaxation and crack closure is accounted for by using simple contact elements. The J-integral for a remote contour is calculated and used as a characterizing fracture parameter although the cyclic loading violates the theoretical basis for this procedure. The near-tip J can not be used for growing cracks because of the weak energy singularity. The results of the numerical study confirm the trends from the experiments in that a high loading rate has a negative influence on the fracture properties of the studied carbon steel and that large cyclic loading, especially at R = −1, lowers the apparent JR-curve for both carbon and stainless steels. To some extent geometry effects appear to be present when comparing the results from pipes containing surface cracks and through-wall cracks with results from CT specimens. These effects are more pronounced for large amounts of stable crack growth than at initiation. 相似文献