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11.
Photo- and Electrochromism of Polyoxometalates and Related Materials   总被引:2,自引:0,他引:2  
Yamase T 《Chemical reviews》1998,98(1):307-326
  相似文献   
12.
Although the melt structure of glass-forming ZnCl2 has so far been well studied, there exists quite little information on the structural change due to anion-substitution. In the present work, the short-range structure of ZnCl2–ZnBr2 mixture melts was analyzed systematically by time-of-flight pulsed neutron diffraction techniques, Raman spectroscopy, molecular orbital calculations, and molecular dynamics simulations. According to radial distribution analysis, it was found that there were tetrahedral structural units of ligand-substituted [ZnClnBr4−n]2− (n=0–4) in these melts, not implying the simple mixing of [ZnCl4]2− and [ZnBr4]2− units. Further detailed estimation indicated that the ligand-substituted complex anions were linked with each other by sharing a common anion.  相似文献   
13.
The purpose of this paper is to show that a first-order adaptive regulator globally stabilizes a class of infinite-dimensional systems having no right half plane zeros. Knowledge of the spectrum of the model's high-frequency gain is not required.  相似文献   
14.
Patients with liver diseases not only experience the adverse effects of liver-metabolized drugs, but also the unexpected adverse effects of renally excreted drugs. Bile acids alter the expression of renal drug transporters, however, the direct effects of bile acids on drug transport remain unknown. Renal drug transporter organic anion-transporting polypeptide 4C1 (OATP4C1) was reported to be inhibited by chenodeoxycholic acid. Therefore, we predicted that the inhibition of OATP4C1-mediated transport by bile acids might be a potential mechanism for the altered pharmacokinetics of renally excreted drugs. We screened 45 types of bile acids and calculated the IC50, Ki values, and bile acid–drug interaction (BDI) indices of bile acids whose inhibitory effect on OATP4C1 was >50%. From the screening results, lithocholic acid (LCA), glycine-conjugated lithocholic acid (GLCA), and taurine-conjugated lithocholic acid (TLCA) were newly identified as inhibitors of OATP4C1. Since the BDI index of LCA was 0.278, LCA is likely to inhibit OATP4C1-mediated transport in clinical settings. Our findings suggest that dose adjustment of renally excreted drugs may be required in patients with renal failure as well as in patients with hepatic failure. We believe that our findings provide essential information for drug development and safe drug treatment in clinics.  相似文献   
15.
Thermal cis–trans conversion has been examined in oligothiophene single molecules encapsulated in the molecular vessels of cyclodextrin and Na-mordenite. At high temperatures, optical absorption intensities are enhanced in bithiophene, terthiophene and quinquethiophene, while the intensity of quarterthiophene is temperature independent. Optical absorption comes from uncompensated transition dipole moment due to the thermal torsion between cis and trans forms.  相似文献   
16.
While the matrix converter has many advantages that include bidirectional power flow, a size reduction, a long lifetime, and sinusoidal input currents, it is vulnerable to the input voltage disturbances, because it directly exchanges the input voltage to the output voltage. The instantaneous effective power control (IEPC) method has been proposed to compensate the input voltage disturbances, in which the instantaneous effective power is kept constant by controlling input current. However, to date, no method has been proposed to maintain the stability of the system with the IEPC. The purpose of this paper is to propose a method to control the stability of the system with IEPC. First, this paper explains the IEPC theoretically. Next, a model of the system with the IEPC is developed, and stability analyses are conducted. Then, based on the results of the analyses, a stability control method for the system with the IEPC is proposed. Furthermore, the validities of the proposed method are demonstrated by simulation and experiments. Finally, a restart performance of the system after momentary power interruption is discussed. Because the IEPC does not need phase-locked-loop to detect the phase angle of the input voltage, fast restart is expected  相似文献   
17.
A high-density, 5-V-only, 4-Mb CMOS EEPROM with a NAND-structured cell using Fowler-Nordheim tunneling for programming is discussed. The block-page mode is utilized for high-speed programming and easy microprocessor interface. On-chip test circuits for shortening test time and for evaluating cell characteristics yield highly reliable EEPROMs. The NAND EEPROM has many applications for microcomputer systems that require small size and large nonvolatile storage systems with low power consumption  相似文献   
18.
A method is described for calculating the input impedance as seen by the detector for a twin slot antenna structure. This technique is then used to analyze several twin slot antenna configurations, leading to improved performance.  相似文献   
19.
780-nm-band high-power and 650-nm-band laser diodes (LDs) with real refractive index guided self-aligned (RISA) structures are monolithically integrated for the first time. High-power and fundamental transverse mode operation at an output power of 100-mW continuous wave (CW) up to 80°C is attained for the 780-nm-band LD. For the 650-nm-band LD, high temperature and fundamental transverse mode operation at an output power of 10-mW CW up to 80°C is obtained  相似文献   
20.
A retrodirective transponder based on a novel compact phase-conjugating mixer with conversion gain has been developed. The active circuit uses one port for both incoming and outgoing signals, enabling a reduction of circuit size, and the balanced structure provides suppression of undesired signals. By using a modulated local oscillator, the circuit can modulate the received signal in order to retransmit local information to the remote site. A microstrip antenna is integrated with the phase conjugator and the whole system was fabricated on a single substrate, enabling a one-card system. A four-element prototype array with 0.5λ0 array spacing demonstrated excellent measured retrodirectivity. Additionally, a simplified binary-phase-shift-keying signal transmitted by the array is recovered successfully at the source location, demonstrating great potential for remote tagging and wireless sensor applications  相似文献   
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