Epitaxial growth of binary and ternary metallic strained superlattices and their magnetic properties

Since the structure at/near the interface of superlattices influences physical properties such as magnetic property, it is important to investigate details of the structure. The interface structure is characterized by the factors like atomic species, strain, mixing and roughness. The reflection high-energy electron diffraction (RHEED) system installed in our molecular-beam epitaxy (MBE) system enables us to observe, continuously, the change of the surface in-plane lattice constant, which is affected by atomic species, strain and/or mixing, on a realtime basis. Ternary superlattices consisting of three elements can clarify the effect of stacking sequence by comparison between the two types of superlattices with the reverse deposition sequences, since the effect caused by the combination of the same atomic species is cancelled out and the effect caused by the different stacking sequences remains. In the present paper, we review growth behaviors of binary and ternary metallic strained superlattices, especially magnetic ones, investigated mainly by our group, and summarize the discussion on their magnetic properties, mainly on the magnetic anisotropy, in terms of their structural characteristics. First, we introduce our RHEED system that works efficiently under a magnetic field arising from evaporation sources for low vapor-pressure materials. Then, MBE-grown binary strained superlattices, Co/Au, Co/Pt and Cu/Au, are discussed, with comparing to incoherent superlattices of Co/Ag and Cu/Ag having nearly the same lattice mismatch of constituents. Next, we review ternary strained superlattices with immiscible constituents with reverse deposition order, Au/Co/Ag and Ag/Co/Au superlattices, and Au/Co/Cu and Cu/Co/Au superlattices, in relation to the growth behaviors of binary superlattices. Finally, ternary strained superlattices containing both miscible and immiscible constituents, Pt/Co/Ag and Ag/Co/Pt superlattices, and Au/Ni/Ag and Ag/Ni/Au superlattices, are reviewed.     

Plasma behavior and characteristics of a pulsed‐laser‐driven MHD electrical power generation

The fundamental electrical power generation experiment of a pulsed‐laser‐driven magnet hydrodynamics generator with a divergent channel and segmented electrodes has been conducted with a rough estimate of gas heating efficiency of laser energy. The output energy is increased with the decrease in the initial filling gas pressure because of the increase in the gas velocity and the electrical conductivity with the gas temperature. The output power is surely improved in comparison with the previously examined generator with constant height channel and continuous electrode. About 70% of the incident laser energy is absorbed and less than 20% is transferred to the blast wave energy at low initial filling gas pressure in the present experimental setup.     

Thermal conductivity and electrical resistivity of liquid Ag–In alloy

To understand and predict the progression of core meltdown accidents in nuclear power plants, it is important to understand the behavior of molten core materials. We focused on the melting behavior of Ag–In–Cd alloys used in the control rods of pressurized water reactors that are known to melt first when a severe accident occurs. To obtain fundamental knowledge about these alloys, we studied the thermal conductivity of Ag–In binary alloys in this study. We evaluated thermal conductivity using two approaches: evaluating from thermal diffusivity up to 873 K measured by the laser-flash method, and calculating based on the Wiedemann–Franz law using the electrical resistivity up to 1273 K measured by the four-probe method. The values of thermal conductivity of liquid Ag–In alloys obtained by these two methods agreed well except for pure indium. Although Ag is known as a material that has one of the highest thermal conductivities, the thermal conductivity of liquid Ag–In alloys is much lower than that of pure liquid Ag (177 W/mK at 1273 K), but almost the same or less than that of liquid In (59.2 W/mK at 1273 K) in all Ag_1?xIn_x (x = 0.2–0.8) alloys at all temperatures in this measurement.     

Three‐Dimensional Stereolithography of Alumina Photonic Crystals for Terahertz Wave Localization

Using stereolithography as an additive manufacturing (AM) process, photonic crystals, with a diamond‐like structure composed of alumina microlattices, were fabricated and their electromagnetic band gap profiles, in terahertz frequency ranges, were investigated. Acrylic resins with dispersed alumina particles were fabricated by stereolithography with micrometer‐order accuracy. After dewaxing and sintering processes, alumina lattices were obtained with high relative densities that reflected the terahertz waves, through Bragg diffraction, perfectly in all directions. Twinned crystal structures with mirror symmetric diamond lattices were designed to introduce defect interfaces. Double‐cavity defects consisting of unit cells hollowed from the diamond lattices formed the coupled resonation modes.     

Reversible polycolour change of viologens from violet through transparent to white

The electrochromic properties of 1,1′-dibenzyl-4,4′-bipyridinium and 1,1′-diheptyl-4,4′-bipyridinium were investigated in the presence of MBr (M = Li⁺, Na⁺, and K⁺). The cyclic voltammograms of these viologens showed a white-coloured state in addition to the usual violet one-electron reduction state and the colourless divalent state. Chemical analyses (FT-IR and XPS spectra) of the white film and some control experiments with different supporting electrolytes, MX (X = Cl⁻ and I⁻), revealed that the viologens formed water-insoluble ion pairs with tribromide generated by the electrooxidation of monobromide to produce a white film. The film was reversibly decolourized electrochemically to the initial transparent state, providing the polyelectrochromism using the simple viologen/MBr systems. The colouration efficiencies for the violet and the white-coloured states were 170 cm²/C and 104 cm²/C, respectively.     

Synthesis of poly(1,3-phenyleneethynylenes) membranes having one-handed helical conformation without any chiral side groups by in-situ desubstitution of d-menthoxy groups

In this study, we synthesized four chiral helical poly(phenyleneethynylenes) having optically active menthoxycarbonyl groups and desubstituted the chiral groups in membrane state. Polycondensations of (+)-menthyl 3,5-diethynylbenzoate with (+)-menthyl 3,5-diiodobenzoate, 1,2-diiodobenzenen, 1,3-diiodobenzene, and 1,4-diiodobenzene using PdCl₂(PPh₃)₂–PPh₃–CuI were afforded helical polymers in good yields (named as PMtMt, o-PMtH, m-PMtH, and p-PMtH, respectively). Among them, PMtMt in a mixture of chloroform/benzene showed the largest Cotton effect in absorption region and gave self-supporting membrane by solvent-casting method. PMtMt membrane also showed a Cotton signal similar to that observed in solution. Desubstitution of PMtMt proceeded quantitatively by immersing the membrane into alkaline solution at room temperature for 3 days. The desubstituted PMtMt membrane showed circular dichroism (CD) signals similar shape to that of the original membrane in the UV region in despite of the polymer having no chiral moieties except for helical conformation. This is the first example of synthesis of chiral helical poly(phenyleneethynylenes) without the coexistence of any other chiral moieties.     

Increasing chemisorbed silane coupling agents in surface-treated layer of silica particles

In the surface treated inorganic particles with silane coupling agent (SCA), chemisorbed and physisorbed molecules are present in the treated layer. Increasing the amount of chemisorption by increasing the molecular weight of SCAs was investigated. Oligomers formed via self-condensation during storage more than 10 days at room temperature for 3-methacryloxypropyltrimethoxysilane-treated silica particles. Monomeric SCA evaporates easily by heating. The oligomers restrict evaporation, and heating increases the chemisorption. The influence of molecular weight of SCA was investigated. In the case of amino group, the amount of chemisorbed was greater for aminoethylaminooctyltrimethoxysilane with high molecular weight than for 3-aminopropyltriethoxysilane. For SCAs with hydrocarbon chains, the amount of chemisorption was lower for both low molecular weight molecules and decyltrimethoxysilane (D) with a high molecular weight. For fluorocarbon chains, the amount of chemisorption was lower for low molecular weight molecules, whereas it increased significantly by heating for high molecular weight type of 1H,1H,2H,2H-heptadecafluorodecyltriethoxysilane (F). Wide-angle X-ray diffraction analysis of F-treated silica particles showed that the fluorocarbon chains formed an ordered structure. There was no such indication for the D-treated system. This ordered structure seems to influence on higher chemisorption for F-treated systems.     

Investigation of meshing phenomenon of hypoid gears with different offsets via high response infrared video thermography

Forschung im Ingenieurwesen - Hypoid gears are widely used in automobile differentials. Furthermore, it is well known that the efficiency of hypoid gears is lower than that of other gears due to...     

Unstable sinking of spheres at higher air velocity in a gas-solid fluidized bed

Float-sink of large objects (on order of cm) in a gas-solid fluidized bed of powder (on order of 100 s of microns) based on density difference has been utilized for dry density separation in industry. The air velocity u₀/u_mf is one of the important factors operating the fluidized bed, where u₀ and u_mf are the superficial air velocity and the minimum fluidization air velocity, respectively. It is empirically known that the sinking of heavy objects is “occasionally” unstable in the fluidized bed combustor, for which the higher air velocity u₀/u_mf > 4 is used. Unstable sinking means heavy objects that are expected to sink but sometimes do not. However, the precise conditions at which the unstable sinking occurs are not clear. In this study, we investigated the float-sink characteristics at a given air velocity u₀/u_mf = 2–7 using glass beads of size D_gb = 425–600 μm and 600–850 μm as the fluidized powder bed media. The float-sink experiments were carried out at the bed height h_gb = 150 mm and 75 mm using density adjusted spheres (diameter = 30 mm). We found that the spheres stably float or sink based on density difference at D_gb = 425–600 μm & h_gb = 150 mm and at D_gb = 600–850 μm & h_gb = 75 mm. However, the unstable sinking does occur at u₀/u_mf > 4 at D_gb = 600–850 μm & h_gb = 150 mm. These results indicate that the powder size and the bed height are key factors to induce the unstable sinking at the higher air velocity.