Profile control of plastic sheet in an industrial polymer processing process

A control system was developed using a two-degree of freedom control structure with four input variables in the feedforward, and two inputs, the screw rotation speed and the gap of the forming roller, in the feedback loop. The feedforward signals were predetermined from first principles and the operators' heuristic rules for each changeover operation and prepared in a database. At the end of each changeover operation, the values in the database were rewritten by evaluating control performance. The magnitude of the true dead time changed as the production rate was changed. The rate of sampling and control action in the feedback control was adapted in each changeover operation so that the changing time delay was always expressed by a one-sampling-step time delay in the discrete models and dealt with by the controller robustness against parameter uncertainty. The developed control system was applied to an actual industrial plastic sheet production line and allowed one to easily perform the changeover operation and reduce material consumption.     

Comparative study of Nd:YAG laser-induced breakdown spectroscopy and transversely excited atmospheric CO2 laser-induced gas plasma spectroscopy on chromated copper arsenate preservative-treated wood

Taking advantage of the specific characteristics of a transversely excited atmospheric (TEA) CO(2) laser, a sophisticated technique for the analysis of chromated copper arsenate (CCA) in wood samples has been developed. In this study, a CCA-treated wood sample with a dimension of 20 mm × 20 mm and a thickness of 2 mm was attached in contact to a nickel plate (20 mm × 20 mm × 0.15 mm), which functions as a subtarget. When the TEA CO(2) laser was successively irradiated onto the wood surface, a hole with a diameter of approximately 2.5 mm was produced inside the sample and the laser beam was directly impinged onto the metal subtarget. Strong and stable gas plasma with a very large diameter of approximately 10 mm was induced once the laser beam had directly struck the metal subtarget. This gas plasma then interacted with the fine particles of the sample inside the hole and finally the particles were effectively dissociated and excited in the gas plasma region. By using this technique, high precision and sensitive analysis of CCA-treated wood sample was realized. A linear calibration curve of Cr was successfully made using the CCA-treated wood sample. The detection limits of Cr, Cu, and As were estimated to be approximately 1, 2, and 15 mg/kg, respectively. In the case of standard LIBS using the Nd:YAG laser, the analytical intensities fluctuate and the detection limit was much lower at approximately one-tenth that of TEA CO(2) laser.     

Identification and sensory evaluation of flavour enhancers in Japanese traditional dried herring (Clupea pallasii) fillet

Flavour-enhancing components of dried herring fillet (migaki-nishin in Japanese) were isolated and evaluated for their effects on sensory perception. Sensory evaluation revealed that addition of dried herring fillet water-soluble extracts to Japanese noodle soup significantly (P < 0.05) enhanced soup flavour characters, such as thickness, mouthfulness and continuity. The extracts were fractionated by dialysis and chromatography. Fractions containing flavour enhancers were isolated by sensory perception. Results from instrumental analyses showed that the kokumi flavour enhancers in dried herring fillet were creatine and creatinine.     

Nuclear transfer reprogramming does not improve the low developmental potency of embryonic stem cells induced by long-term culture

Epigenetic states of embryonic stem (ES) cells are easily altered by long-term cultivation and lose their developmental potential. To rescue this reduced developmental capacity, nuclear transfer (NT) of ES cells was carried out, and original ES and ES cells from cloned blastocysts (ntES) cells established after NT were compared with in vitro differentiation ability and developmental potential by embryoid body formation and tetraploid aggregation respectively. In the establishment of ntES cell lines, the oocytes fused with the ES cell were activated, and further cultured to cloned blastocysts. When in vitro differentiation ability was examined between original and ntES cell lines derived from ES cells with extensive passages (ES-ep), the day of appearance of simple embryoid body, cystic embryoid body, and spontaneous beating was almost similar. The developmental rates of ES-ep cells, that aggregated with tetraploid embryos to term, ranged from 3 to 6%. Moreover, the majority of live pups died soon after birth. In the ntES cell lines derived from ES-ep cells, developmental rates ranged from 0 to 5%. Those pups also died soon after birth, similar to the ES-ep-derived pups. These results suggest that profound epigenetic modifications of ES cells were retained in the re-established cell lines by NT.     

Synthesis of chloromethylstyrene‐tetraethyleneglycol dimethacrylate copolymer beads having various phenolic derivatives immobilized via amide bond and their antioxidation activity

Resins having phenolic derivatives were prepared by treating a resin (RAS‐4G), having benzylamino groups, with benzoic acids containing phenolic hydroxyl groups. The RAS‐4G was prepared by treating macroreticular chloromethylstyrene‐tetraethyleneglycol dimethacrylate (4G) copolymer beads with potassium phthalimide in N,N‐dimethylformamide, followed by reflux in an ethanol/hydrazine monohydrate mixture. 4‐Hydroxy benzoic acid, (2,4‐, 3,4‐, and 3,5‐)dihydroxy benzoic acids, 3,4,5‐trihydroxy benzoic acid, etc., were used as benzoic acids with phenolic hydroxyl groups. The antioxidation ability of the resins having phenolic derivatives was investigated against the generation of 1,4‐dioxane hydroperoxide. The resins showed high inhibition ability against the generation of hydroperoxide. In particular, the resin (RAS‐4G‐3,4‐DHBA) having two phenolic hydroxyl groups had the highest inhibition ability. The resins were found to act as radical scavengers during the generation of 1,4‐dioxane hydroperoxide by UV irradiation in the presence of oxygen. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 2097–2104, 2005     

Quantum Transition to Supersolid Phase

We study a possible coexistence of superconducting state and charge density waves which, in a broad sense, might be called a supersolid phase. We investigate the infinite dimensional (d=) attractive Hubbard model by applying a sublattice dependent Gutzwiller wave function |BCS as a variational wave function describing the ground state. One may naively expect that the BCS superconducting state evolves continuously to the Bose–Einstein condensed state of bipolarons as the attractive interaction increases, as far as the system is dilute. However, we show that our variational wave function has lower energy than the simple BCS wave function for all electron densities and the interaction strengths. Our variational parameters increase (g _A,B) as we increase the interaction strength (U). The energy gap turns out to be a mixture of s and extended-s waves. In the vicinity of half-filling, we find a quantum transition from a simple superconducting phase to a supersolid phase with increase of the electron density and/or the interaction strength.     

An absorption-based surface plasmon resonance sensor applied to sodium ion sensing based on an ion-selective optode membrane

A surface plasmon resonance (SPR) sodium ion sensor using an ion optode membrane film was experimentally and theoretically described based on an absorption-based SPR principle proposed in our previous article (Kurihara, K; Suzuki, K. AnaL Chem. 2002, 74, 696-701). The sodium ion concentrations from 10(-6) to 10(-1) have been successfully determined not only by the resonance angle diagnosis of the SPR curve but also by the minimum reflectance one. The ion optode film was plasticized poly(vinyl chloride) including a neutral sodium ionophore, a pH-sensitive cationic dye, and an anionic additive. Its optical absorption intensity changed with the sodium ion concentrations. The SPR ion sensor physically measured the complex refractive index caused by the absorption in the ion optode film. We have exhaustively investigated the experimental response behavior of the SPR curve relative to the sodium ion concentrations by comparison with numerically simulated SPR curves using a three-layer Fresnel equation including experimental values for the sodium ion optode membrane film. As predicted by the absorption-based SPR principle, the SPR curve behavior of the SPR ion sensors depended on two factors: one was the relation between the excitation frequency of the light source and the absorption maximum frequency in the ion optode film while the other was the gold metallic thickness in the Kretchmann configuration. The concept and practical theory of an absorption-based SPR sensor not only have been proved by the experimental results of the SPR sodium ion sensor but also have successfully allowed flexible ion sensing in an SPR sensor, which would be very difficult without the absorption mechanism in the ion optode film.     

Self-organization based on nonlinear nonequilibrium. Dynamics of autonomous agents

This paper discusses a study on the mechanism of self-organization. A global order is organized by the simple and locally coordinated actions of autonomous agents using only local information, so complex or globally coordinated actions which use global communication and high-level strategies are not necessary. The fundamental factors for establishing a global order using self-organization are a “dissipative structure,” an “autocatalysis mechanism,” and “intentional fluctuations.” If an environment where there are agents has a dissipative structure and those agents have some sort of autocatalysis and intentional fluctuation mechanisms within themselves, it is possible to form a global order for them using only their simple and locally coordinated actions. “The blind-hunger dilemma” is used as an example to simulate the self-organization and coordinated actions of agents. In this simulation environment, there are many ant-like agents which must get energy. However, there is only one small energy supply base, so either an efficient method or the coordinated actions of agents is needed. As a result, the agents using our approach could move and get energy more efficiently than agents using conventional coordination mechanisms involving global communication and high-level strategies. Real World Computing Partnership This work was presented, in part, at the Second International Symposium on Artificial Life and Robotics, Oita, Japan, February 18–20, 1997     

Variational Bayes via propositionalized probability computation in PRISM

We propose a logic-based approach to variational Bayes (VB) via propositionalized probability computation in a symbolic-statistical modeling language PRISM. PRISM computes probabilities of logical formulas by reducing them to AND/OR boolean formulas called explanation graphs containing probabilistic ${\tt msw/2}$ atoms. We put Dirichlet priors on parameters of ${\tt msw/2}$ atoms and derive a variational Bayes EM algorithm that learns their hyper parameters from data. It runs on explanation graphs deduced from a program and a goal and computes probabilities in a dynamic programming manner in time linear in the size of the graphs. To show the genericity and effectiveness of Bayesian modeling by the proposed approach, we conducted two learning experiments, one with a probabilistic right-corner grammar and the other with a profile-HMM. To our knowledge, no previous report has been made of VB applied to these models.     

波导全息存储器的多层读出特性

研究了多层波导全息存储器的读出特性和读出层的选择方法。通过读出光的位置重合,可读出各个记录层所记录的信息,而不受其他层的影响。而且,通过分析波导射出端的强度图形,可判断读出光和光波导的耦合状态。还研究了利用射出光强度的耦合状态判定法。