A facile synthesis of a novel three‐phase nanocomposite: Single‐wall carbon nanotube/silver nanohybrid fibers embedded in sulfonated polyaniline

A three‐phase water‐soluble nanocomposite of single wall carbon nanotube/silver nanoparticle hybrid fibers embedded in sulfonated polyaniline has been synthesized by a simple chemical solution mixing process. The nanocomposite has been characterized by high resolution electron microscopy, X‐ray diffractometry, FTIR spectroscopy, Raman spectroscopy, and thermogravimetric analysis. Optical and electrical characteristics of the nanocomposite have been determined by UV–vis absorption spectroscopy, photoluminescence spectroscopy, and four‐probe electrical conductivity measurement. A surface plasmon absorption band obtained around 460 nm indicates the presence of silver nanoparticles in the composite. The optical band gap calculation for sulfonated polyaniline vis‐a‐vis the nanocomposite supported the conductivity measurement. Over 1300 times increase in DC electrical conductivity has been observed for the three‐phase nanocomposite, with a filler loading of 20 wt %, at 306 K. This observation could be explained by Mott's variable range hopping model considering a three‐dimensional conduction. Such a nanocomposite has immense potential for use as a cathode material in lithium‐ion batteries and supercapacitors. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41692.     

Miscibility and fracture toughness of thermoplastic polyurethane/poly(vinyl chloride)/nitrile rubber ternary blends with special reference to the blend composition

Ternary blends of thermoplastic polyurethane and a poly(vinyl chloride)/nitrile rubber blend were investigated in this work. The blends, with weight ratios of 100/0, 80/20, 40/60, 60/40, 80/20, and 0/100, were prepared via melt blending. Dynamic mechanical analysis showed that the blends with ratios of 20/80 and 80/20 were miscible, whereas the 40/60 and 60/40 blends were partially miscible. IR spectroscopy studies showed shifts in the peaks due to specific interactions in the blends. The blends showed degradation behavior between the blend components. The fracture toughness was investigated with the J‐integral by the locus method; the components and the miscible blends had good fracture toughness, whereas the other blends had lower toughness. Similar behavior was observed for the tensile properties. Scanning electron microscopy studies showed the morphological variations in the blends. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 1763–1770, 2005     

Microstructural evolution and hardness of in situ Al-4.5Cu-5TiB2 composite processed by multiple roll passes in mushy state

In situ Al-4.5Cu-5TiB₂ composite has been processed through stir casting method, in which, the TiB₂ particles have been precipitated in situ by mixed salt route involving reactions between K₂TiF₆ and KBF₄.The as-cast specimens containing 20 volume percent liquid content have been subjected to three mushy state roll passes, each leading to 5 percent reduction in thickness. The grain structure has been found to be globular in the mushy state rolled composites. Measurements along the cross-section have shown decrease in average grain size and increase in hardness, as one proceeds along the direction of rolling. On the other hand, grain size and hardness have been found to be more or less similar, when compared for sections perpendicular to the rolling direction.     

Modelling of a downdraft biomass gasifier with finite rate kinetics in the reduction zone

A model of a downdraft gasifier has been developed based on chemical equilibrium in the pyro‐oxidation zone and finite rate kinetic‐controlled chemical reactions in the reduction zone. The char reactivity factor (C_RF) in the reduction zone, representing the number of active sites on the char and its degree of burn out, has been optimized by comparing the model predictions against the experimental results from the literature. The model predictions agree well with the temperature distribution and exit gas composition obtained from the experiments at C_RF=100. A detailed parametric study has been performed at different equivalence ratios (between 2 and 3.4) and moisture content (in the range of 0–40%) in the fuel to obtain the composition of the producer gas as well as its heating value. It is observed that the heating value of the producer gas increases with the increase in the equivalence ratio and decrease in the biomass moisture content. The effect of divergence angle of the reduction zone geometry (in the range of 30–150°) on the temperature and species concentration distributions in the gasifier has been studied. An optimum divergence angle, giving the best quality of the producer gas, has been identified for a particular height of the reduction zone. Copyright © 2009 John Wiley & Sons, Ltd.     

Dielectric and Thermal Investigations on PbNb2O6 in Pure Piezoelectric Phase and Pure Non-Piezoelectric Phase

A high piezoelectric transition temperature is indicated for present orthorhombic samples of lead meta-niobate (PbNb₂O₆) by the high value of the temperature (T_m) at which the real part (?′) of electrical permittivity peaks. It is 573 to 580°C. The imaginary component (?″) increases sharply at these temperatures. Cooling run after heating to 700°C gives changed values of ?′ and ?″ and T_m. Present work reports impedance spectroscopy (up to 700°C over 20 Hz to 5.5 MHz) and Differential Scanning Calorimetry or DSC on the pure orthorhombic phase, and, for the first time, on the pure rhombohedral phase. DSC shows an endothermic dip across T_m during heating and an exothermic peak during cooling for the orthorhombic sample only.     

Applicability of time-of-flight-based ground and multispectral aerial imaging for grapevine canopy vigour monitoring under direct root-zone deficit irrigation

ABSTRACT

This study investigates the applicability of ground-based 3D time-of-flight (ToF) imaging and small unmanned aerial system (UAS) integrated multispectral imaging as a rapid grapevine canopy vigour mapping tool for decision support during crop production management. Direct root-zone deficit irrigation was applied to grapevines with continuous and pulse irrigation techniques at 15%, 30%, and 60% rates as that of standard irrigation rate (100%) established by the grower in a commercial production. The control block was irrigated continuously at 100% standard irrigation rate. Field plots were imaged using ground platform integrated with 3D ToF imaging sensor and small UAS-integrated multispectral camera at 128 and 65 days before the harvest to estimate the canopy vigour variability associated with irrigation treatments. Customized as well as standard methods (convex hull and voxel grid) were utilized to extract canopy attributes (e.g. volume) from the 3D ToF imaging sensor data. The multispectral images were processed to extract normalized and green normalized difference vegetation index images. Resulting data were used to estimate canopy area ratio i.e. the ratio between the grapevine canopy area with respect to the total area in selected region of interest. A significant correlation (r = 0.34) between canopy volume estimated by customized algorithm and aerial canopy area ratio was observed. Custom canopy volume estimates were also highly correlated (r = 0.79) with voxel grid derived canopy volume data. Overall, 60% continuous direct root zone deficit irrigation appeared to produce canopy volume/vigour comparable with those under control treatment. Results also suggest that grower can utilize either or both (ground and aerial) grapevine canopy mapping techniques for effective management.     

Design of a PLL with improved locking range and its biomedical applications

This paper describes a phase locked loop employing a low voltage VCO using modified ECL inverter cells. The VCO circuit employed, features a positive feed back scheme to improve the operating frequency. The phase detector used in the PLL also uses a positive feedback scheme to improve the locked range and to reduce supply voltage of operation of the entire circuit. An improvement of locked range of around 35% was obtained from circuit simulation (using PSPICE) as well as from practical circuit, using discrete components. The minimum supply voltage required here is 2.5 volts. Some biomedical applications of this PLL are also proposed.