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21.
22.
Nadia Abu Samra Herbert F. Jelinek Habiba Alsafar Farah Asghar Muhieddine Seoud Shahad M. Hussein Hisham M. Mubarak Siddiq Anwar Mashal Memon Nariman Afify Ridda Manzoor Zahrah Al-Homedi Wael Osman 《International journal of molecular sciences》2022,23(7)
One of the most common complications during pregnancy is gestational diabetes mellitus (GDM), hyperglycemia that occurs for the first time during pregnancy. The condition is multifactorial, caused by an interaction between genetic, epigenetic, and environmental factors. However, the underlying mechanisms responsible for its pathogenesis remain elusive. Moreover, in contrast to several common metabolic disorders, molecular research in GDM is lagging. It is important to recognize that GDM is still commonly diagnosed during the second trimester of pregnancy using the oral glucose tolerance test (OGGT), at a time when both a fetal and maternal pathophysiology is already present, demonstrating the increased blood glucose levels associated with exacerbated insulin resistance. Therefore, early detection of metabolic changes and associated epigenetic and genetic factors that can lead to an improved prediction of adverse pregnancy outcomes and future cardio-metabolic pathologies in GDM women and their children is imperative. Several genomic and epigenetic approaches have been used to identify the genes, genetic variants, metabolic pathways, and epigenetic modifications involved in GDM to determine its etiology. In this article, we explore these factors as well as how their functional effects may contribute to immediate and future pathologies in women with GDM and their offspring from birth to adulthood. We also discuss how these approaches contribute to the changes in different molecular pathways that contribute to the GDM pathogenesis, with a special focus on the development of insulin resistance. 相似文献
23.
H.-J. Timpe S. Missal R. Manzoor E. Affi 《Advanced Synthesis \u0026amp; Catalysis》1981,323(3):459-465
Reactions of Mesoionic s-Triazolo[4,3-b] pyridazines with Electrophilic Reagents The redox-properties of zwitterionic s-triazolo [4, 3-b]pyridazines 1–3 depend on the heteroatom: products with S-atoms can easily be oxidated. O-Zwitterions 1 and 2 react with diazoniumsalts under azocoupling, while S-zwitterions 3 lead to a dediazonation. The O-zwitterions 1 and 2 can also be bromated, nitrated and hydroxylated electrophilicably. A reaction with dithioliumsalts is not possible. S-Zwitterions 3 react in a more complicated way in the electrophilic reactions mentioned. 相似文献
24.
Sadaqat Ali Bilal Anjum Ahmed Hafiz Muzammil Irshad Akolade Idris Bakare Abbas Saeed Hakeem Muhammad Qamaruddin Muhammad Ali Ehsan Sameer Ali Muhammad Umar Azam 《International Journal of Applied Ceramic Technology》2020,17(4):1948-1958
The thermomechanical behavior of micro/nano-alumina (Al2O3) ceramics reinforced with 1-5 wt.% of acid-treated oil fly ash (OFA) was investigated. Composites were sintered using spark plasma sintering (SPS) technique at a temperature of 1400°C by applying a constant uniaxial pressure of 50 MPa. It was evaluated that the fracture toughness of micro- and nanosized composites improved in contrast with the monolithic alumina. Highest fracture toughness value of 4.85 MPam1/2 was measured for the nanosized composite reinforced with 5 wt.% OFA. The thermal conductivity of the composites (nano-/microsized) decreased with the increase in temperature. However, the addition of OFA (1-5 wt.%) in nanosized alumina enhanced the thermal conductivity at an evaluated temperature. Furthermore, a minimum thermal expansion value of 6.17 ppm*K−1 was measured for nanosized Al2O3/5 wt.% OFA composite. Microstructural characterization of Al2O3-OFA composites was done by x-ray diffraction and Raman spectroscopy. Oil fly ash particles were seen to be well dispersed within the alumina matrix. Moreover, the comparative analysis of the nano-/microsized Al2O3/OFA composites shows that the mechanical and thermal properties were improved in nanosized alumina composites. 相似文献
25.
Wun-Fui Mark-Lee Kim-Hang Ng Lorna Jeffery Minggu Akrajas Ali Umar Mohammad B. Kassim 《International Journal of Hydrogen Energy》2013
Molybdenum dithiolene complexes with the general formula [MoTp*(NO)(L)], where Tp* = tris(3,5-dimethylpyrazolyl)hydroborate and L = toluene-3,4-dithiolate (L1), 1,2-benzenedithiolate (L2), or 3,6-dichloro-1,2-benzenedithiolate (L3), were found to exhibit the chemical and physical properties required for a photosensitiser in a photoelectrochemical cell. These complexes were characterised using micro-elemental, spectroscopic (IR and UV–vis) and electrochemical analyses. Cyclic voltammetry (CV) was used to determine the oxidation/reduction potentials and to calculate the energy band gap. All of the complexes had an energy band gap in the range 1.45–1.48 eV, which extends far into the visible light region. A TiO2 thin film to be used as a photoanode for photoelectrochemical cells was prepared using the paste technique on a Fluorine-doped Tin Oxide (FTO) plate and characterised using scanning electron microscope (SEM) and X-ray diffractometer (XRD). The [MoTp*(NO)(L)]-doped TiO2 photoanodes were analysed photochemically in a 1.0 M NaOH electrolyte solution using SCE reference and platinum counterelectrodes. The [MoTp*(NO)(L3)]-doped TiO2 photoanode exhibited an increased photoinduced current compared with the undoped TiO2 photoanode. The Cl atoms on the dithiolene group offered a better interaction between the photosensitiser molecule and the TiO2 photocatalyst by providing a means for halogen atom-induced chemical bonding. Based on the band edge calculations and the subsequent photocurrent results, these complexes may be potential photosensitisers for use in the preparation of photoelectrodes for photoelectrochemical cells. 相似文献
26.
Nazrin S. N. Umar S. A. Halimah M. K. Marian M. M. Najwa Z. W. Jufa M. S. Syahirah M. T. Zuhasanah Z. Azlan M. N. Geidam I. G. Boukhris Imed Kebaili Imen 《Journal of Inorganic and Organometallic Polymers and Materials》2022,32(7):2513-2526
Journal of Inorganic and Organometallic Polymers and Materials - Copper oxide doped TeO2–B2O3 glass system with empirical formula;... 相似文献
27.
In this paper, we analyze the problem of throughput-efficient distributed coalition formation (CF) of selfish/altruistic nodes in ad hoc radio networks. We formulate the problem as a hedonic CF game with non-transferable utility and propose different preference relations (CF rules) based on individual/group rate improvement of distributed nodes. We develop a hedonic CF algorithm, through which distributed nodes may self-organize into stable throughput-efficient disjoint coalitions. We apply the concept of frequency reuse over different coalitions, such that the members of each coalition will transmit over orthogonal sub-bands with the available spectrum being optimally allocated among them. We study the computational complexity and convergence properties of the proposed hedonic CF algorithm under selfish and altruistic preferences, and present means to guarantee Nash-stability. In addition, we identify the scenarios in which a CF process might lead to instability (CF cycle), and we propose methods to avoid cycles and define different exit procedures if a CF cycle is inevitable. Performance analysis shows that the proposed algorithm with optimal bandwidth allocation provides a substantial gain, in terms of average payoff per link, over existing coalition formation algorithms for a wide SNR range. 相似文献
28.
Ahmad Umar 《Nanoscale research letters》2009,4(9):1004-1008
Dye-sensitized solar cells (DSSCs) were fabricated by using well-crystallized ZnO nanocombs directly grown onto the fluorine-doped
tin oxide (FTO) via noncatalytic thermal evaporation process. The thin films of as-grown ZnO nanocombs were used as photoanode
materials to fabricate the DSSCs, which exhibited an overall light to electricity conversion efficiency of 0.68% with a fill
factor of 34%, short-circuit current of 3.14 mA/cm2, and open-circuit voltage of 0.671 V. To the best of our knowledge, this is first report in which thin film of ZnO nanocombs
was used as photoanode materials to fabricate the DSSCs. 相似文献
29.
Afshan Shafi Umar Farooq Kashif Akram Mahgul Jaskani Farzana Siddique Amna Tanveer 《Comprehensive Reviews in Food Science and Food Safety》2014,13(2):229-239
Various Lactobacillus species possess antidiarrheal properties due to their probiotic effects and could be utilized in the form of fermented foods for the treatment of diarrheal disease. Diarrhea is the condition of having 3 or more loose or watery bowel movements per day. This disease is a global problem causing several million deaths each year, and the major victims are children. So its prevention and control is crucial. For the treatment of diarrheal disease, antibiotics and oral rehydration solutions are used, but these therapies are not always effective to reduce the duration and frequency of diarrhea and of increase consistency. Recent studies have demonstrated the effectiveness of the natural mode (fermented food) of disease management because of its easy availability, low cost, and efficacy against diarrhea. 相似文献
30.