Geotechnical properties of problematic expansive subgrade stabilized with guar gum biopolymer

Clean Technologies and Environmental Policy - This article presents a comprehensive study on the geotechnical behavior of problematic expansive subgrade stabilized by guar gum (GG) biopolymer. In...     

Fracture Toughness Characteristics of Stacked Bilayer Graphene via Far-Field Displacement Measurements

Mechanical properties of graphene, e.g., strength, modulus, and fracture toughness are extremely sensitive to flaws. Here the fracture properties of stacked bilayer graphene sheets (SBLG) are reported, obtained via stacking two individually grown graphene sheets. The SBLG is presented here as a building block for flaw-resilient nanomaterials. The fracture properties of freestanding SBLG sheets, suspended on transmission electron microscope (TEM) grids, are characterized by stretching the TEM grid inside an scanning electron microscope (SEM) chamber and monitoring the local displacements in real-time. The fracture toughness is measured and expressed as a function of the critical displacement required to propagate existing cracks in the experiment via computational models. This approach decouples force and displacements measurements, and utilizes the known elastic modulus along with the known displacement boundary conditions at the onset of crack growth to estimate the far field force and stress. This strategy represents a breakthrough in nanoscale fracture mechanics for statistical analysis and high throughput experimens on multiple samples at a time. Results demonstrate that the SBLG is markedly tougher than as-grown single or multilayer graphene, with a mode I fracture toughness of ≈28.06 ± 7.5 MPa$\sqrt{m}$. The mechanisms leading to a higher toughness of SBLG are also analyzed and discussed.     

Ni3V2O8 Nanosheets Grafted on 3D Helical-shaped Carbon Nanocoils as A Binder-free Hierarchical Composite for Efficient Non-enzymatic Glucose Sensing

High fabrication cost, chemical instability, and complex immobilization of enzyme molecules are critical issues of enzyme-based glucose sensors. Designing state-of-the-art, binder-free, and non-enzymatic glucose sensing probes plays an imperative role to cope with the aforementioned issues. 3D carbonaceous nanomaterials coated with transition metal vanadates (TMVs) are a favorable biomimetic platform for glucose quantification. Peculiar hierarchical structure, enhanced conductivity, synergistic interaction, multiple oxidation states, and high catalytic activity would make such composite a potential contender for non-enzymatic glucose sensing. Herein, 3D helical-shaped carbon nanocoils (CNCs) are grown on nickel foam (NF) via chemical vapor deposition method to prepare a robust CNCs/NF scaffold. Then, a hydrothermal route is followed to grow interconnected free-standing Ni₃V₂O₈ nanosheets (NSs) on CNCs/NF scaffold. This novel and binder-free Ni₃V₂O₈ NSs/CNCs/NF hierarchical composite possesses superior electrochemical active area (ECSA) and exceptional electrochemical efficacy. Amperometric analysis exhibits extremely prompt detection time (0.1 s), elevated sensitivity (5214 µA mM⁻¹ cm⁻²), and low detection limit (0.04 µM). Developed sensor demonstrates appreciable recoveries (93.3 to 103.3%) regarding glucose concentration in human serum. The appealing analytical results show that deployment of a 3D helical-shaped hierarchical smart scaffold can be an effective strategy for developing efficient and advanced non-enzymatic glucose sensors.     

RESERVOIR CHARACTERIZATION OF THE PLIOCENE RED SERIES,LAM FIELD AND SURROUNDING AREAS,OFFSHORE WESTERN TURKMENISTAN

The sedimentology, petrography and reservoir potential of Pliocene sandstones within the Upper Red Series in the offshore LAM field, Western Turkmenistan, have been examined. Depositional settings are interpreted within the framework of the Red Series palaeoenvironments across the entire Turkmen sector of the Apsheron-Prebalkhan uplift zone, including its onshore extension to the east. Examination of 81 m of core from three separate intervals suggests that the Red Series in the LAM field is the product of a fluvial-dominated delta system with associated floodplain deposits, periodically flooded by the saline waters of the South Caspian Lake. Relatively thick sandstones, up to around 5 m thick, are interpreted as channel and point-bar deposits of a meandering river system, with thinner and finer-grained sandstones and siltstones inferred to be crevasse-splay and interdistributary floodplain deposits. Floodplain mudstones display signs of desiccation, soil formation, plant rootlets and occasional thin layers of anhydrite. Intervals with marine trace-fossil assemblages record incursions of saline-lake waters. Conglomeratic layers at the base of thicker mudstone intervals may be associated with abrupt transgressions of the lake. The best reservoir qualities are associated with the fluvial channel and point-bar sandstones. Crevasse-splay and other overbank sandstones are of poorer quality, while intercalated floodplain to lacustrine claystone/siltstone units may constitute local seals. Eighteen sandstone plug samples from the cored intervals were examined in thin-section and by XRD and SEM to assess how mineralogy, grain size and diagenesis affect reservoir quality. The samples consist predominantly of lithic arkoses and feldspathic litharenites; higher porosities, and therefore better reservoir potential, are associated with the feldspathic litharenites. Primary controls on porosity include compaction, clay-matrix content and calcite cementation. XRD data reveal the presence of illite, illite-smectite and chlorite. The presence of swelling clays has been the main cause of formation damage in the field. The interpretation of meandering fluvial channels here is thought to represent the first published account of such channels within Pliocene reservoir rocks in the north of the South Caspian Basin. Previous accounts of the Red Series sandstones deposited onshore to the east have indicated deposition within braided channels of the palaeo-Amu Darya river delta plain, and alluvial-fan deposits sourced from uplands to the north. Deposition of the equivalent Productive Series by the palaeo-Volga in the Azerbaijan sector to the west has also been interpreted as having taken place within braided systems, although mixed or suspended-load fluvial channels ascribed to the contemporary Kura delta farther south may have been associated with a meandering system. Two palaeogeographic maps are presented to illustrate depositional environments for the Red Series during relative high- and low-stands of the South Caspian Lake. The maps cover the area where the Productive Series of Azerbaijan passes into the Red Series of Western Turkmenistan.