Absolute stability of positive systems with differential constraints

We consider discrete-time systems x(k + 1) = Ax(k) + f(x(k)) where the matrix A of the linear part is known and positive, the non-linearity f is unknown but belongs to a class for which A + f(x) is positive with spectral radius < 1 for all x Rⁿ. This, with the additional property that x - Ax - f (x) is proper, is sufficient for global stability of the system. The results are applied to the continuous system x. = Ax + B phialt(C^T x) by considering the translation operator along trajectories and studying the resulting discrete system.     

Relaxation Properties of Pressure-sensitive Adhesives upon Withdrawal of Bonding Pressure

Relaxation properties of pressure-sensitive adhesives (PSA) have been studied with the squeeze-recoil tester used in the regime of parallel-plate dilatometer under conditions imitating the removal of compressive force in the course of adhesive bond formation. The relaxation properties of PSAs are compared with their adhesive behavior measured using the 180-Deg Peel Test. Two classes of PSAs are considered: 1) conventional rubbery adhesives based on the mixtures of styrene-isoprene-styrene (SIS) block copolymer with a tackifier resin and a plasticizer, and butyl rubber plasticized with low-molecular-weight polyisobutylene, and 2) hydrophilic PSAs composed of the blends of high-molecular-weight poly(N-vinyl pyrrolidone) (PVP) with oligomeric polyethylene glycol (PEG). By comparing the adhesive and relaxation behaviors of different PSAs, the relaxation criteria for pressure-sensitive adhesion have been stated. Relaxation behavior of the examined PSAs demonstrates two values of retardation time: the shorter retardation time of 10–70?sec and the longer time of 300–660?sec. These times can be associated, respectively, with small- and large-scale mechanisms of strain recovery. By comparing the relaxation and adhesive properties of PVP-PEG blend (which involves the formation of a hydrogen-bonded network through both terminal hydroxyl groups in PEG short chains) with the properties of covalently crosslinked copolymers of vinyl pyrrolidone (VP) with PEG-diacrylate and comb-like VP copolymers with PEG-monomethacrylate, the contributions of covalent crosslinking and H-bonding network have been characterized.     

Euclidean space controllability of singularly perturbed linear systems with state delay

A singularly perturbed linear time-dependent control system with small point and distributed delays in state variables is considered. Connections between the properties of controllability of the reduced-order and boundary-layer systems, associated with the original one, and such a property of the original system itself are established.     

“In‐field” cell temperature evaluation in solar modules through time‐dependent open circuit voltage measurements

A method for the evaluation of p–n junction cell temperature in PV modules operating in the maximum power point (MPP) mode has been proposed. The method does not require specialized equipment and (for the concentrator modules) the data on the open circuit (OC) voltage temperature coefficients measured under pulse illumination. It consists of measuring several open circuit voltage magnitudes together with temperature measurements on the external module surface near one of the cells. In this procedure, a fast transition from MPP to OC operational mode is carried out, during which a time‐dependent voltage measurement is carried out with the help of a memory oscilloscope. A “reference” OC voltage magnitude in a “cold” module (a condition, as if the cells are kept at ambient temperature) is obtained by calculations, so that there is no necessity in a fast mechanical shuttering of the module aperture area. In the case of the concentrator modules, the module OC voltage temperature coefficient can be measured, if heat sinking process is artificially modified during outdoor measurements. Copyright © 2015 John Wiley & Sons, Ltd.     

Synthesis of BaAl2S4:Eu2+ Electroluminescent Material by the Polymerizable Complex Method Combined with CS2 Sulfurization

Eu-activated BaAl₂S₄ (BaAl₂S₄:Eu) blue light emission phosphor has attracted considerable attention recently as a prospective material for full color electroluminescent display applications. Although BaAl₂S₄:Eu was discovered over 30 years ago, the solid-state reaction between metal sulfides in sealed quartz ampoules remains the main method for the synthesis of this material. In this work, a homogeneous single-phase Ba_0.95Eu_0.05Al₂S₄ (BaAl₂S₄:Eu) phosphor was obtained by the sulfurization–reduction of the multicomponent oxide precursor in a CS₂ atmosphere at 1050°C. The oxide precursor containing barium, aluminum, and europium for this process was prepared by the polymerizable complex method, which ensures a high degree of homogeneity in the final product. The BaAl₂S₄:Eu material thus obtained exhibited a single emission line at 475 nm and a fluorescence intensity of 35% compared with one of the best commercially available (Ba,Eu)MgAl₁₀O₁₇ phosphors.     

A Review of: “Interfacial Phenomena in Polymers,by Yuri S. Lipatov. Naukova Dumka Publ., Kiev, 1980, 259 pp. (in Russian).”

Bonding aluminum metal and its alloys with epoxy adhesives is sensitive to process variables, particularly surface contamination and moisture exposure. In the past, several surface modification schemes have been developed to improve the epoxy-bonding of aluminum. The present work describes a simple process that produces significant improvement in strength and durability of epoxy-bonded aluminum. In this process, aluminum surfaces are first rinsed with dilute sodium metasilicate solution followed by a dilute aqueous epoxysilane solution. The combination of the two materials exhibits a bond strength synergism as measured by bondline fracture toughness. The treated aluminum surface also exhibits a significant increase in bond strength tolerance to contamination and moisture exposure. The effect of epoxysilane chemical structure on bond durability was examined, as was the role of the silicate surface treatment.     

Gold nanorods with a hematoporphyrin-loaded silica shell for dual-modality photodynamic and photothermal treatment of tumors in vivo

Nanocomposites （NCs） consisting of a gold nanorod core and a mesoporous silica shell doped with hematoporphyrin （HP） have been fabricated in order to improve the efficiency of cancer treatment by combining photothermal and photodynamic therapies （PDT ＋ PTT） in vivo. In addition to the long-wavelength plasmon resonance near 810-830 nm, the fabricated NCs exhibited a 400-nm absorbance peak corresponding to bound HP, generated singlet oxygen under 633-nm excitation near the 632.5-nm Q-band, and produced heat under a 808-nm near-infrared （NIR） laser irradiation. These modalities were used for a combined PDT ＋ PTT treatment of large （about 3 cm3） solid tumors in vivo with a xenorafted tumor rat model. NCs were directly injected into tumors and irradiated simultaneously with 633-nm and 808-nm lasers to stimulate the combined photodynamic and photothermal activities of NCs. The efficiency of the combined therapy was evaluated by optical coherence tomography, histological analysis, and by measurements of the tumor volume growth during a 21-day period. The NC-mediated PDT led to weak changes in tissue histology and to a moderate 20% decrease in the tumor volume. In contrast, the combined PDT ＋ PTT treatment resulted in the large-area tumor necrosis and led to dramatic decrease in the tumor volume.     

Integration of Production Steps on a Single Equipment

The article describes a new method for integrated processing which combines high-energy heating by high frequency currents (HEH HFC) and abrasive grinding. Research clearly showed that implementation of integrated processing may lead to 2 … 2.5-fold increasing of the processing performance. It was established experimentally that the proposed integrated treatment results in increasing of the microhardness and the level of residual compressive stresses in the surface layer. This increases the contact–fatigue strength of steel parts up to 10% … 16%.