Distinguishing between cis/trans isomers of monounsaturated fatty acids by FAB MS

Fast-atom bombardment (FAB) mass spectrometry in the negative ion mode can be used to unambiguously distinguish between cis and trans isomers of monounsaturated fatty acids by the relative signal strengths of an intense pair of ion signals. Under normal FAB ionization/desorption conditions, the deprotonated molecules (i.e., [M - H]-) of six fatty acids underwent charge remote fragmentation. A characteristic fragmentation pattern of two intense peak clusters of peaks with three weak intervening clusters of peaks are used in each case to identify the position of the double bond. The possibility of resonance electron capture occurring during the FAB process is discussed.     

Synthesis of Calcium Hexaboride by Electrolysis of Molten Salt

Metallurgical and Materials Transactions B - Formation of calcium hexaboride by means of electrodeposition of boron oxide in molten CaCl2 with additives of CaO and B2O3 was analyzed. It was shown...     

Peripheral noxious stimulation induces CREM expression in dorsal horn: involvement of glutamate

Thermal washout curves have been proposed as noninvasive tools for analysing lower airway dimensions and pulmonary blood flow, but how upper airway heat transfer affects these washout curves is unclear. The present study was designed to compare extrathoracic and tracheobronchial contributions to thermal washout curves. Respiratory frequency, air ambient temperature, and body core temperature (tc) were varied in six male subjects before and after immersion in cold (1.1 degrees C) water for up to 2 h under three conditions: 1) control: ambient temperature (tamb) = 25 degrees C, rectal temperature change (delta tre) = 0 degrees C; 2) pre-immersion: tamb = 4 degrees C, delta tre = 0 degrees C; and 3) post-immersion: tamb = 25 degrees C, delta tre = -0.7 degrees C. Both peak expiratory nasal (tpn) and oral (tpo) airstream temperatures were measured. Each subject was tested twice. Expiratory tpo was generally higher than tpn in all conditions. Increasing breathing rates lowered tpn and tpo in the control and cold air environments. Orifice temperatures, which are presumed to reflect upper airway blood temperatures, correlated with both tpn and tpo. Lowering tc had no effect on washout curves during quiet breathing and affected only tpn during rapid breathing. The results suggest that while tracheobronchial conditions may contribute to thermal washout curves, extrathoracic conditions predominate. Strong correlations between orifice temperatures, peak expiratory nasal temperatures and peak expiratory oral temperature demonstrate the dominant role of upper airway heat exchange in determining thermal washout curves.     

Radiation intensity from ultrarelativistic particles during axial channeling and its orientation dependence

The radiation intensity I of ultrarelativistic electrons and positrons during axial channeling in thin crystals is calculated using a realistic model for the axial potential. The approach used avoids a cumbersome analysis of radiation from concrete trajectories. A general expression for the intensity I(?_o) as a function of the incident angle ?_o of the particles, which is valid for any ax potential U(ρ), is derived. Explicit formulas for the potential [eq. (29)] are given. Intensities I(?_o) for axial and planar chann compared.     

Design and energy-efficient resource management of virtualized networked Fog architectures for the real-time support of IoT applications

With the incoming 5G access networks, it is forecasted that Fog computing (FC) and Internet of Things (IoT) will converge onto the Fog-of-IoT paradigm. Since the FC paradigm spreads, by design, networking and computing resources over the wireless access network, it would enable the support of computing-intensive and delay-sensitive streaming applications under the energy-limited wireless IoT realm. Motivated by this consideration, the goal of this paper is threefold. First, it provides a motivating study the main “killer” application areas envisioned for the considered Fog-of-IoT paradigm. Second, it presents the design of a CoNtainer-based virtualized networked computing architecture. The proposed architecture operates at the Middleware layer and exploits the native capability of the Container Engines, so as to allow the dynamic real-time scaling of the available computing-plus-networking virtualized resources. Third, the paper presents a low-complexity penalty-aware bin packing-type heuristic for the dynamic management of the resulting virtualized computing-plus-networking resources. The proposed heuristic pursues the joint minimization of the networking-plus-computing energy by adaptively scaling up/down the processing speeds of the virtual processors and transport throughputs of the instantiated TCP/IP virtual connections, while guaranteeing hard (i.e., deterministic) upper bounds on the per-task computing-plus-networking delays. Finally, the actual energy performance-versus-implementation complexity trade-off of the proposed resource manager is numerically tested under both wireless static and mobile Fog-of-IoT scenarios and comparisons against the corresponding performances of some state-of-the-art benchmark resource managers and device-to-device edge computing platforms are also carried out.     

Thermoelastic behavior of carbon fiber/polycarbonate model composites

Model composites of polycarbonate (PC) containing single, multiple and chopped carbon fibers (CF) with and without and epoxy sizing were prepared by hot pressing. The thermoelastic behavior of model CF/PC composites was characterized by stretching calorimetry at room temperature. For small strains ? (i.e., ? ≈ 0.01) the specific mechanical work, specific heat effects and specific internal energy changes ΔU were completely reversible in stretching/contraction cycles and quantitatively obeyed the standard relationships for elastic solids. Young's moduli E and ΔU were significantly higher, whereas the linear thermal expansivities α_L were lower for model CF/PC composites compared to those for the neat PC. Smaller values of the above parameters for composites reinforced with sized CF suggested weaker CF/PC interfacial interactions. Current theoretical models of thermoelastic properties of composite materials suggest the existence of unusually stiff, highly oriented PC structures in fairly thick boundary layers around CF. The onset of inelastic deformation, as well as mechanical failure in CF/PC model composites at significantly smaller strains compared to the neat PC were tentatively explained by the yield and subsequent plastic flow of the matrix polymer initiated by heat effects of fiber fragmentation processes, and by higher concentration of microvoids generated in fiber fragmentation/debonding events, respectively.     

Unique Computer Modeling Approaches for Simulation of Induction Heating and Heat-Treating Processes

In the last decade, when discussing subjects related to a computer modeling of induction heating and heat treating, the word “usefulness” has been replaced by the word “necessity.” Modern computer simulation is capable of effectively simulating electromagnetic and thermal phenomena for many processes, including those that involve electromagnetic induction. This article discusses the state-of-the-art computer simulation of induction heating and heat treating providing answers to following questions: Why finite element analysis is not always the best tool for computer modeling of some induction heating applications? What are the limitations of generalized all-purpose commercial programs? What are the crucial tips that executives must know regarding computer modeling of induction heating? Several case studies will be reviewed in this article as well.