Emissivity errors in the vegetation cover method caused by the lack of atmospheric correction

The influence of the lack of atmospheric correction of the optical images used to calculate land surface emissivity (LSE) was assessed. When thermal emissivity is determined by the vegetation cover method (VCM), information from the solar spectrum is required to calculate the vegetation cover fraction. The atmospheric correction was obtained in this study by using a combination of the dark dense vegetation (DDV) method and the Second Simulation of the Satellite Signal in the Solar Spectrum (6S) code. The methodology was applied to a Landsat Thematic Mapper (TM) image of Tomelloso, Spain. We determined that the emissivity between 10 and 12 µm only increases by 0.4% (which represents a systematic error of approximately +0.2 K) when atmospherically corrected reflectances are used in relation to non‐corrected Tomelloso scenes. Nevertheless, other test areas could yield larger differences.     

In situ surface temperature retrieval in a boreal forest under variable cloudiness conditions

Canopy temperature retrieval was one of the purposes during the Solar Induced FLuorescence EXperiment (SIFLEX‐2002) of the European Space Agency, carried out in a Finnish boreal forest. In this work, we describe the strategy used to determine this temperature from ground thermal infrared (TIR) data under skies with variable cloud cover. TIR radiance was measured by a CIMEL Electronique CE 312 radiometer. An analysis of the radiative transfer equation showed which terms were necessary to obtain accurate surface temperatures during the campaign. Atmospheric correction was considered negligible due to the small atmospheric path, but hemispheric downwelling sky radiance determination was needed for the emissivity correction. Since most days during the campaign the sky showed partial cloudiness, a methodology to estimate this last term was proposed, using continuous information of cloudiness amount and cloud height given by a weather station. These thermal data were used to analyse some correlations between canopy and air temperatures and plant‐activity‐related variables in the context of the SIFLEX‐2002 campaign.     

Robustness of optimal channel reservation using handover prediction in multiservice wireless networks

The aim of our study is to obtain theoretical limits for the gain that can be expected when using handover prediction and to determine the sensitivity of the system performance against different parameters. We apply an average-reward reinforcement learning approach based on afterstates to the design of optimal admission control policies in mobile multimedia cellular networks where predictive information related to the occurrence of future handovers is available. We consider a type of predictor that labels active mobile terminals in the cell neighborhood a fixed amount of time before handovers are predicted to occur, which we call the anticipation time. The admission controller exploits this information to reserve resources efficiently. We show that there exists an optimum value for the anticipation time at which the highest performance gain is obtained. Although the optimum anticipation time depends on system parameters, we find that its value changes very little when the system parameters vary within a reasonable range. We also find that, in terms of system performance, deploying prediction is always advantageous when compared to a system without prediction, even when the system parameters are estimated with poor precision.     

Relationships between memory models

There have been many proposals of shared memory systems, each one providing different types of memory coherence for interprocess communication. However, they have usually been defined using different formalisms. This makes it difficult to compare among them the different proposals put forward. In this paper we present a formal framework for specifying memory models with different coherency properties. We specify most of the known shared memory models using our framework, showing some of the relationships that hold among them.     

45S5 bioactive glass coatings by atmospheric plasma spraying obtained from feedstocks prepared by different routes

45S5 bioactive glass powders with the composition of 45 SiO₂, 6 P₂O₅, 24.5 CaO and 24.5 wt% Na₂O were melted and quenched in water to obtain a frit. The frit was milled using two different routes: dry milling followed by sieving to obtain glass particles and wet milling followed by spray drying to obtain a powder comprising porous agglomerates. All feedstocks showed adequate characteristics that make them suitable to be deposited by atmospheric plasma spraying. The powders and coatings were characterised by field-emission gun environmental scanning electron microscope and X-ray diffraction. The roughness and the contact angle of the coatings were also determined. The bioactivity of the powders and coatings was assessed by immersion in simulated body fluid. It was found that bioactive glass prepared from bioglass frit by dry milling exhibited similar bioactivity as that of a commercial bioactive glass. All coatings produced showed good adhesion to the substrate as well as suitable surface properties to ensure efficient contact with body fluid. Regardless of the characteristics of the feedstocks or plasma spray conditions used, all coatings were exclusively made up of an amorphous phase. On the other hand, micrographs revealed that the characteristics of the feedstock strongly impact on the final coating microstructure. The most homogeneous microstructure was obtained when the feedstock was prepared by fine dry grinding of the frit. For this coating, the formation of a bioactive layer was also proved by Fourier transform infrared spectroscopy and X-ray diffraction.     

Individual and occupational factors related to fatal occupational injuries: a case-control study

This study has been designed in order to identify factors increasing the risk of a fatal outcome when occupational accidents occur. The aim is to provide further evidence for the design and implementation of preventive measures in occupational settings. The Spanish Ministry of Labour registry of occupational injuries causing absence from work includes information on individual and occupational characteristics of injured workers and events. Registered fatal occupational injuries in 2001 (n = 539) were compared to a sample of non-fatal injuries in the same year (n = 3493). Risks for a fatal result of occupational injuries, adjusted by individual and occupational factors significantly associated, were obtained through logistic regression models. Compared to non-fatal injuries, fatal occupational injuries were mostly produced by trapping or by natural causes, mostly related to elevation and transport devices and power generators, and injured parts of body more frequently affected were head, multiple parts or internal organs. Adjusted analyses showed increased risk of fatality after an occupational injury for males (adjusted odds ratio aOR = 10.92; 95%CI 4.80–24.84) and temporary workers (aOR = 5.18; 95%CI 2.63–10.18), and the risk increased with age and with advancing hour of the work shift (p for trends <0.01). Injuries taking place out of the usual occupational setting (aOR = 2.85, 95%CI 2.27–3.59), or carrying out atypical tasks (aOR = 2.08; 95%CI 1.27–3.39) showed increased risks of a fatal result too, as occupational accidents in agricultural or construction companies. These data can help to select and define priorities for programmes aimed to prevent fatal consequences of occupational injuries.     

Biodegradation of sulfamethazine by Trametes versicolor: Removal from sewage sludge and identification of intermediate products by UPLC-QqTOF-MS

Degradation of the sulfonamide sulfamethazine (SMZ) by the white-rot fungus Trametes versicolor was assessed. Elimination was achieved to nearly undetectable levels after 20 h in liquid medium when SMZ was added at 9 mg L^− 1. Experiments with purified laccase and laccase-mediators resulted in almost complete removal. On the other hand, inhibition of SMZ degradation was observed when piperonilbutoxide, a cytochrome P450-inhibitor, was added to the fungal cultures. UPLC-QqTOF-MS analysis allowed the identification and confirmation of 4 different SMZ degradation intermediates produced by fungal cultures or purified laccase: desulfo-SMZ, N⁴-formyl-SMZ, N⁴-hydroxy-SMZ and desamino-SMZ; nonetheless SMZ mineralization was not demonstrated with the isotopically labeled sulfamethazine-phenyl-¹³C₆ after 7 days. Inoculation of T. versicolor to sterilized sewage sludge in solid-phase systems showed complete elimination of SMZ and also of other sulfonamides (sulfapyridine, sulfathiazole) at real environmental concentrations, making this fungus an interesting candidate for further remediation research.     

“Key” sectors in final energy consumption: an input–output application to the Spanish case

In this paper we analyze the determination of “key” sectors in the final energy consumption. We approach this issue from an input–output perspective and we design a methodology based on the elasticities of the demands of final energy consumption. As an exercise, we apply the proposed methodology to the Spanish economy. The analysis allows us to indicate the greater or lesser relevance of the different sectors in the consumption of final energy, pointing out which sectors deserve greater attention in the Spanish case and showing the implications for energy policy.